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BY-NC-ND 3.0 license Open Access Published by De Gruyter June 2, 2014

Preparation, IR and X-Ray Crystal Structure Studies of Tl(I)-2-pyridyl-cyanoxime Complex

  • N. Nikolay Gerasimchuk , László Nagy , H.-G. Schmidt , Mathias Noltemeyer , Rakesh Bohra and Herbert W. Roesky

The thallium(I)-2-pyridyl-cyanoxime complex was prepared in a 82% yield. An X-ray crystallographic study of C7H4N3OT1 (Space group P21/c, a = 4.134(1), b = 8.875(2), c = 22.217(6) Å, β = 92.55(2)°, Ζ = 4, R = 4.36%, wR = 3.94% for 930 reflections) showed that the complex contains thallium(I) in a trigonal bipyramidal arrangement.

Received: 1992-6-5
Published Online: 2014-6-2
Published in Print: 1992-12-1

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