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BY-NC-ND 3.0 license Open Access Published by De Gruyter June 2, 2014

Hochtemperatursynthese und Kristallchemie der Oxotantalate Cr2+0,761Ta2,095O6 und FeTa2O6 / High Temperature Synthesis and Crystal Chemistry of the Oxotantalates Cr2+0,761Ta2,095O6 and FeTa2O6

E. Peters and Hk. Müller-Buschbaum

Abstract

Black single crystals of Cr0.761Ta2.095O6 have been prepared by CO2-LASER techniques. This phase crystallizes with monoclinic symmetry, space group C52h-P21/c, a = 4.748(1). b = 4.750(2), c = 10.405(3) Å, β = 117.152(13)°, Z = 2. The crystal structure is closely related to the trirutile type, although the metal positions are partly statistically occupied by Cr2+ and Ta5+ or underoccupied by Ta5+, respectively. FeTa2O6, prepared by the same m ethod does neither show any statistic occupation nor deviations from the trirutile structure, space group D144h-P42/mnm, a = 4.7595(5) Å, c = 9.201(2)A, Z = 2 .

Received: 1994-10-12
Published Online: 2014-6-2
Published in Print: 1995-5-1

© 1946 – 2014: Verlag der Zeitschrift für Naturforschung

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License.

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