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BY-NC-ND 3.0 license Open Access Published by De Gruyter June 2, 2014

Darstellung und Kristallstruktur von [Cs4(Dibenzo-18-Krone-6)3](S6)2·2CH3CN / Synthesis and Crystal Structure of [Cs4(Dibenzo-18-Krone-6)3](S6)2·2CH3CN

P. Böttcher and M. Schnock

Abstract

[Cs4(dibenzo-18-crown-6)3](S6)2·2CH3CN has been prepared from dibenzo-18-crown-6, Cs2CO3 and suifur in acetonitrile saturated with H2S. The title compound crystallizes in space group P 1̄ (lattice dimensions: a = 10,507(7) Å, b = 11,504(6) Å, c = 17,792(9) Å, α = 97,86(4)°, β = 105,86(4)°, γ = 101,48(5)°) with one formula unit. The crystallographic units are built of stacks of three crown ether molecules and two hexasulfide chains with the cations located between them. The conformation of the hexasulfide chains is all-cis.

Received: 1994-9-15
Published Online: 2014-6-2
Published in Print: 1995-5-1

© 1946 – 2014: Verlag der Zeitschrift für Naturforschung

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License.

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