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BY-NC-ND 3.0 license Open Access Published by De Gruyter June 2, 2014

Der kürzeste Weg zu C1-symmetrischen, chiralen tripod-Liganden mit Neopentan-Grundgerüst / The Shortest Way to C1-Symmetrical, Chiral Tripod Ligands with Neopentane Backbone

  • Thomas Seitz , Andreas Muth and Gottfried Huttner

Chiral tripod-ligands of the type 5 are easily accessible in four steps starting from the dibromide 1. The cleavage of the oxetane 4 b by LiPPh2 yielding the tripod-ligand 5 can be modified enantioselectively by the addition of (-)-sparteine.

Received: 1994-11-24
Published Online: 2014-6-2
Published in Print: 1995-7-1

© 1946 – 2014: Verlag der Zeitschrift für Naturforschung

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License.

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