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Kristallstruktur von Bromnitrat BrONO2 / Crystal Structure of Bromine Nitrate BrONO2

  • Rolf Minkwitz and Thomas Hertel

Abstract

The crystal structure of bromine nitrate BrONO2 has been determined on a single crystal with MoKα radiation at -83°C. The structure is orthorhombic, space group P212121, Z = 4, and the cell dimensions are a = 403.2(2), b = 684.9(4), c = 1201.4(5) pm. An intermolecular Br.....O contact leads to the formation of chains within the crystal. Attempts to synthesize a bromine(III)-nitrate by oxidizing CF3Br and CF3Br with ClONO2 were not successful.

Received: 1997-8-8
Published Online: 2014-6-2
Published in Print: 1997-11-1

© 1946 – 2014: Verlag der Zeitschrift für Naturforschung

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