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Reaction of 2,5,5-trimethyl-Δ1-pyrrolidine-N-oxide with methyl lithium yields 2,2′-bis(1-hydroxy- 2,2,5-trimethyl-pyrrolidinyl)methane which is reduced by Raney nickel/hydrogen to the corresponding amine. Both molecules are present in the meso-configuration in the solid state. While the hydroxylamine derivative shows intermolecular O-H···O bridge bonding no intermolecular N···H-N interaction is observed for the amine.
: Keywords 2,2′-Bis( 1 -hydroxy-2,2,5-trimethyl-pyrrolidinyl)methane; 2,2′-Bis(2,2,5-trimethyl-pyrroldinyl) methane; X-Ray Data
Received: 1999-7-26
Published Online: 2014-6-2
Published in Print: 1999-11-1
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