Bis(N-tnmethylsilylamino)titanium Dichlorides Bearing Two Identical or Two Different Amino Groups

Bernd Wrackmeyer; Jürgen Weidinger

doi:10.1515/znb-1999-1110

Published by De Gruyter June 2, 2014

Bis(N-tnmethylsilylamino)titanium Dichlorides Bearing Two Identical or Two Different Amino Groups

Bernd Wrackmeyer and Jürgen Weidinger

From the journal Zeitschrift für Naturforschung B

https://doi.org/10.1515/znb-1999-1110

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N-Trimethylsilylaminotitanium trichlorides, Me₃Si(R)N-TiCl₃ [R = ^tBu (2a), SiMe₃ (2b), 9-borabicyclo[3.3.1 ]nonyl (9-BBN) (2c)] react with the corresponding plumbylenes 1a - c or with the lithium amides LiN(R)SiMe₃ to give the bis(amino)titanium dichlorides 3a - c, and 4 - 6. The titanium dichlorides 4-6 are the first examples, in which the titanium atom bears two different amino groups. The compounds were characterised by a consistent set of ¹H, ¹³C, ^14/15N and ²⁹Si NMR data.

Keywords: Silylamines; Titanium; Plumbylenes; NMR Data

Received: 1999-8-17

Published Online: 2014-6-2

Published in Print: 1999-11-1

Bis(N-tnmethylsilylamino)titanium Dichlorides Bearing Two Identical or Two Different Amino Groups

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