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Licensed Unlicensed Requires Authentication Published by De Gruyter June 2, 2014

Darstellung und Strukturaufklärung von Tricäsiumundecaphosphid- Ammoniakat(1/3) Cs3P11 · 3 NH3 / Synthesis and Crystal Structure of Tricesium Undecaphosphide-Ammonia(l/3) Cs3P11 · 3 NH3

Doris Knettel, Markus Reil and Nikolaus Korber

Cs3 P11 · 3 NH3 was obtained from a solution of Cs3P11 in liquid ammonia. Its structure consists of P113--cage anions, which coordinate the cesium cations together with ammonia molecules, resulting in a three-dimensional network. The compound completes a family of structures that are derived from the binary phosphide Cs3P11, through the stepwise expanding and dismantling of the three-dimensional network of ions by ammonia molecules of coordination or through the exchange of the cesium cations for voluminous molecular cations.

Received: 2001-6-27
Published Online: 2014-6-2
Published in Print: 2001-10-1

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