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Cs3 P11 · 3 NH3 was obtained from a solution of Cs3P11 in liquid ammonia. Its structure consists of P113--cage anions, which coordinate the cesium cations together with ammonia molecules, resulting in a three-dimensional network. The compound completes a family of structures that are derived from the binary phosphide Cs3P11, through the stepwise expanding and dismantling of the three-dimensional network of ions by ammonia molecules of coordination or through the exchange of the cesium cations for voluminous molecular cations.
Received: 2001-6-27
Published Online: 2014-6-2
Published in Print: 2001-10-1
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