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Licensed Unlicensed Requires Authentication Published by De Gruyter June 5, 2018

Protic ionic liquids as catalysts for a three-component coupling/hydroarylation/dehydrogenation tandem reaction

Maren Muntzeck and René Wilhelm

Abstract

Protic ionic liquids with nitrate anions were used as solvents and catalysts for a three-component oxidative dehydrogenation tandem reaction via the coupling and hydroarylation of benzaldehyde, aniline, and phenylacetylene to a quinoline derivative. The reaction was supported by air and microwave irradiation. The presence of nitrate as counter anion in the protic ionic liquids was essential for the reaction.

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Received: 2018-05-10
Accepted: 2018-05-14
Published Online: 2018-06-05
Published in Print: 2018-07-26

©2018 Walter de Gruyter GmbH, Berlin/Boston

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