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Licensed Unlicensed Requires Authentication Published by De Gruyter September 22, 2021

Synthesis, structure, and magnetic properties of the quaternary oxysulfides Ln 5V3O7S6 (Ln = La, Ce)

Chong Zheng ORCID logo, Roald Hoffmann, Timothy S. Perkins, Frank Calvagna, Roxanna Fotovat, Crystal Ferels, Alyssa Mohr, Reinhard K. Kremer, Jürgen Köhler, Arndt Simon, Kejun Bu and Fuqiang Huang


Two rare earth oxysulfides Ln 5V3O7S6 (Ln = La, Ce) have been synthesized and their structures determined. The two isostructural compounds crystallize in the orthorhombic space group Pmmn (no. 59). The structure features one-dimensional edge-sharing VS4O2 octahedron chains parallel to the b axis. The bonding between V and S/O is covalent, and between Ln 3+ and the rest of the matrix ionic. Magnetic susceptibility measurement revealed that V is in a mixed valence state of V3+ and V4+. Its magnetic behavior follows the Curie-Weiss law.

Dedicated to: Professor Richard Dronskowski of the RWTH Aachen on the occasion of his 60th birthday.

Corresponding authors: Chong Zheng and Roald Hoffmann, Department of Chemistry and Biochemistry, Northern Illinois University, DeKalb, IL, 60115, USA; and Department of Chemistry and Chemical Biology, Cornell University, Ithaca, New York 14853, USA, E-mail: (C. Zheng), (R. Hoffmann)

  1. Author contributions: All the authors have accepted responsibility for the entire content of this submitted manuscript and approved submission.

  2. Research funding: None declared.

  3. Conflict of interest statement: The authors declare no conflicts of interest regarding this article.


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Received: 2021-08-04
Accepted: 2021-08-22
Published Online: 2021-09-22
Published in Print: 2021-11-25

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