Skip to content
Licensed Unlicensed Requires Authentication Published by De Gruyter October 19, 2021

Synthesis and structure of an asymmetrical sila[1]magnesocenophane

  • Inga-Alexandra Bischoff , Bernd Morgenstern and André Schäfer EMAIL logo

Abstract

The synthesis and structure of an asymmetrical sila[1]magnesocenophane, featuring a cyclopentadienyl and a tetramethylcyclopentadienyl group, are reported. The compound was obtained as a bis(tetrahydrofuran) adduct and exhibits a slipped sandwich structure in the solid state.


Corresponding author: André Schäfer, Department of Chemistry, Faculty of Natural Sciences and Technology, Saarland University, Campus Saarbrücken, 66123 Saarbrücken, Germany, E-mail:

Award Identifier / Grant number: Emmy Noether Program, SCHA1915/3-1

Acknowledgments

Instrumentation and technical assistance for this work were provided by the Service Center X-ray Diffraction, with financial support from Saarland University and Deutsche Forschungsgemeinschaft (INST 256/506-1).

  1. Author contributions: All the authors have accepted responsibility for the entire content of this submitted manuscript and approved submission.

  2. Research funding: This work was funded by Deutsche Forschungsgemeinschaft, DFG (Emmy Noether Program, SCHA1915/3-1).

  3. Conflict of interest statement: The authors declare no conflicts of interest regarding this article.

References

1. Herbert, D. E., Mayer, U. F. J., Manners, I. Angew. Chem. Int. Ed. 2007, 46, 5060–5081; https://doi.org/10.1002/anie.200604409.Search in Google Scholar PubMed

2. Musgrave, R. A., Russell, A. D., Manners, I. Organometallics 2013, 32, 5654–5667; https://doi.org/10.1021/om400488k.Search in Google Scholar

3. Russell, A. D., Musgrave, R. A., Stoll, L. K., Choi, P., Qiu, H., Manners, I. J. Organomet. Chem. 2015, 784, 24–30; https://doi.org/10.1016/j.jorganchem.2014.10.038.Search in Google Scholar

4. Wirtz, L., Schäfer, A. Chem. Eur. J. 2021, 27, 1219–1230; https://doi.org/10.1002/chem.202003161.Search in Google Scholar PubMed PubMed Central

5. Rider, D. A., Manners, I. Polym. Rev. 2007, 47, 165–195; https://doi.org/10.1080/15583720701271302.Search in Google Scholar

6. Bellas, V., Rehahn, M. Angew. Chem. Int. Ed. 2007, 46, 5082–5104; https://doi.org/10.1002/anie.200604420.Search in Google Scholar PubMed

7. Manners, I. J. Organomet. Chem. 2011, 696, 1146–1149; https://doi.org/10.1016/j.jorganchem.2010.11.048.Search in Google Scholar

8. Hailes, R. L. N., Oliver, A. M., Gwyther, J., Whittell, G. R., Manners, I. Chem. Soc. Rev. 2016, 45, 5358–5407; https://doi.org/10.1039/c6cs00155f.Search in Google Scholar PubMed

9. Wang, B. Coord. Chem. Rev. 2006, 250, 242–258; https://doi.org/10.1016/j.ccr.2005.05.012.Search in Google Scholar

10. Brintzinger, H. H., Fischer, D. Development of ansa-metallocene catalysts for isotactic olefin polymerization. In Polyolefins: 50 Years After Ziegler Natta II. Advances in Polymer Science; Kaminsky, W., Ed., Vol. 258. Springer: Berlin, Heidelberg, 2013; pp. 29–42.10.1007/12_2013_215Search in Google Scholar

11. Wirtz, L., Haider, W., Huch, V., Zimmer, M., Schäfer, A. Chem. Eur. J. 2020, 26, 6176–6184; https://doi.org/10.1002/chem.202000106.Search in Google Scholar

12. Wirtz, L., Lambert, J., Morgenstern, B., Schäfer, A. Organometallics 2021, 40, 2108–2117; https://doi.org/10.1021/acs.organomet.1c00245.Search in Google Scholar

13. Damrau, H.-R. H., Geyer, A., Prosenc, M.-H., Weeber, A., Schaper, F., Brintzinger, H.-H. J. Organomet. Chem. 1998, 553, 331–343; https://doi.org/10.1016/s0022-328x(97)00618-9.Search in Google Scholar

14. Schultz, M., Sofield, C. D., Walter, M. D., Andersen, R. A. New J. Chem. 2005, 29, 919–927; https://doi.org/10.1039/b418550a.Search in Google Scholar

15. Perrotin, P., Twamley, B., Shapiro, P. J. Acta Crystallogr. E 2007, 63, m1277–m1278; https://doi.org/10.1107/s1600536807015942.Search in Google Scholar

16. Perrotin, P., Shapiro, P. J., Williams, M., Twamley, B. Organometallics 2007, 26, 1823–1826; https://doi.org/10.1021/om061136u.Search in Google Scholar

17. Westerhausen, M., Makropoulos, N., Wieneke, B., Karaghiosoff, K., Nöth, H., Schwenk-Kircher, H., Knizek, J., Seifert, T. Eur. J. Inorg. Chem. 1998, 1998, 965–971; https://doi.org/10.1002/(sici)1099-0682(199807)1998:7<965::aid-ejic965>3.0.co;2-a.10.1002/(SICI)1099-0682(199807)1998:7<965::AID-EJIC965>3.0.CO;2-ASearch in Google Scholar

18. Antiñolo, A., Fernández-Galán, R., Molina, N., Otero, A., Rivilla, I., Rodríguez, A. M. J. Organomet. Chem. 2009, 694, 1959–1970; https://doi.org/10.1016/j.jorganchem.2009.01.038.Search in Google Scholar

19. Sheldrick, G. M. Acta Crystallogr. 2008, A64, 112–122; https://doi.org/10.1107/s0108767307043930.Search in Google Scholar

20. Sheldrick, G. M. Acta Crystallogr. 2015, A71, 3–8; https://doi.org/10.1107/s2053229614024218.Search in Google Scholar

21. Hübschle, C. B., Sheldrick, G. M., Dittrich, B. J. Appl. Crystallogr. 2011, 44, 1281–1284; https://doi.org/10.1107/s0021889811043202.Search in Google Scholar

22. Stern, D., Sabat, M., Marks, T. J. J. Am. Chem. Soc. 1990, 112, 9558–9575; https://doi.org/10.1021/ja00182a015.Search in Google Scholar

Received: 2021-09-30
Accepted: 2021-10-07
Published Online: 2021-10-19
Published in Print: 2022-01-27

© 2021 Walter de Gruyter GmbH, Berlin/Boston

Downloaded on 2.12.2023 from https://www.degruyter.com/document/doi/10.1515/znb-2021-0152/html
Scroll to top button