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Licensed Unlicensed Requires Authentication Published by De Gruyter (O) May 7, 2018

Plasmonic Cu/CuCl/Cu2S/Ag and Cu/CuCl/Cu2S/Au Supports with Peroxidase-Like Activity: Insights from Surface Enhanced Raman Spectroscopy

Wei Song, Peter Hildebrandt and Inez M. Weidinger

Abstract

In the present study, we present nanostructured bimetallic Cu/CuCl/Cu2S/Au(Ag) supports that exhibit plasmonic electromagnetic field enhancement and peroxidase-like catalytic activity. The Cu2S component acts as the peroxidase-like catalyst, while the Au or Ag component provides the necessary light enhancement for surface enhanced Raman spectroscopic (SERS) studies of surface bound molecular reactants. As a test reaction the catalytic oxidation of 3,3′,5,5′-tetramethylbenzidine (TMB) in presence of H2O2 was investigated. The comparison of product evolution in solution measured by UV-Vis spectroscopy and on the surface measured via SERS is able to give more insight into the different steps involved in the overall catalysis.

Acknowledgements

This work was supported by the DFG (Cluster of Excellence EXC314 UniCat) and the National Natural Science Foundation of China (21473068).

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Received: 2018-01-29
Accepted: 2018-03-05
Published Online: 2018-05-07
Published in Print: 2018-08-28

©2018 Walter de Gruyter GmbH, Berlin/Boston

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