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Licensed Unlicensed Requires Authentication Published by De Gruyter (O) July 28, 2010

The crystal structure of In7Br9

Abstract

The crystal structure of In7Br9 has been determined on the basis of single crystal data. In7Br9 is a mixed valence compound according to the crystal-chemical formulation (In+)6In3+ (Br)9, and it crystallizes isotypically with In7Cl9 in space group Pa[unk] with a = 1268.10(3) pm. While trivalent indium is octahedrally coordinated by bromine with a bond length of 268 pm, univalent indium resides in a slightly distorted bisdisphenoid, the bond lengths ranging from 307 pm to 377 pm.

Published Online: 2010-7-28
Published in Print: 1995-12-1

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