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Licensed Unlicensed Requires Authentication Published by De Gruyter (O) September 25, 2009

Interaction of Chemical Reactive Species – Investigated with Spin-Lattice Relaxation and NOE Measurements

  • A. Oßmann and S. Berger


The paper describes attempts to detect interactions or encounter complexes between reacting molecules, although the individual molecules might not succeed in forming a reaction product. As an example, the Diels-Alder reaction is chosen, and the technique employed comprises NMR T1 and NMR NOE measurements. In the case of the intermolecular Diels-Alder reaction both methods were not successful, in the intramolecular Diels-Alder reaction NOE results are able to predict the stereochemical outcome.

* Correspondence address: Universität Leipzig , Institut für Analytische Chemie , Linnéstraße 3 , 04103 Leipzig , Deutschland,

Published Online: 2009-9-25
Published in Print: 2008-8-1

© by Oldenbourg Wissenschaftsverlag, München, Germany

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