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Licensed Unlicensed Requires Authentication Published by De Gruyter January 29, 2018

Comparative compressional behavior of chabazite with Li+, Na+, Ag+, K+, Rb+, and Cs+ as extra-framework cations

  • Mihye Kong , Yongmoon Lee , G. Diego Gatta and Yongjae Lee EMAIL logo
From the journal American Mineralogist

Abstract

The high-pressure behavior of monovalent-cation-exchanged chabazites was investigated by means of in situ synchrotron X-ray powder diffraction with a diamond-anvil cell, and using water as penetrating pressure-transmitting medium, up to 5.5 GPa at room temperature. In all cases, except for Na-containing chabazites, a phase transition from the original rhombohedral (R3m) to triclinic symmetry (likely P1) was observed in the range between 3.0 GPa and 5.0 GPa. The phase transition is accompanied by an abrupt decrease of the unit-cell volume by up to 10%. Evidence of pressure-induced hydration (PIH), i.e., P-induced penetration of H2O molecules through the zeolitic cavities, was observed, as reflected by the incompressibility of the cation-exchanged chabazites, which is governed by the distribution of the extra-framework cations. The reversibility of the PIH and P-induced phase transitions in the high-pressure behavior of the cation-exchanged chabazites are discussed in the context of the role played by the chemical nature and bonding configuration of the extra-framework cations, along with that of the H2O content at room conditions.


† Special collection papers can be found online at http://www.minsocam.org/MSA/AmMin/special-collections.html.


Acknowledgments

This work was supported by the Global Research Laboratory (NRF-2009-00408) and National Research Laboratory (NRF-2015R1A2A1A01007227) programs of the Korean Ministry of Science, ICT and Planning (MSIP). We also thank the supports by NRF-2016K1A4A3914691 and NRF-2016K1A3A7A09005244 grants. Experiments using X-ray synchrotron radiation were supported by the Collaborative Access Program of SSRL. Two anonymous reviewers are thanked for their suggestions.

References Cited

Alberti, A., and Martucci, A. (2005) Phase transformations and structural modifications induced by heating in microporous materials. Studies in Surface Science and Catalysis, 155, 19–43.10.1016/S0167-2991(05)80135-1Search in Google Scholar

Angel, R.J. (2004) Equations of state of plagioclase feldspars. Contributions to Mineralogy and Petrology, 146, 506–512.10.1007/s00410-003-0515-5Search in Google Scholar

Angel, R.J., Gonzalez-Platas, J., and Alvaro, M. (2014) EosFit-7c and a fortran module (library) for equation of state calculations. Zeitschrift für Kristallographie, 229, 405–419.10.1515/zkri-2013-1711Search in Google Scholar

Barrer, R.M., Davies, J.A., and Rees, L.V.C. (1969) Thermodynamics and thermochemistry of cation exchange in chabazite. Journal of Nuclide Chemistry, 31, 219–232.10.1016/0022-1902(69)80071-0Search in Google Scholar

Bish, D.L., and Carey, J.W. (2001) Thermal behavior of natural zeolites. Reviews in Mineralogy and Geochemistry, 45, 403–452.10.2138/rmg.2001.45.13Search in Google Scholar

Birch, F. (1947) Finite elastic strain of cubic crystals. Physical Review, 71, 809–824.10.1103/PhysRev.71.809Search in Google Scholar

Breck, D.W. (1974) Zeolite molecular sieves: Structure, chemistry and use. Wiley, New York (original edition); reprinted R.E. Kriegger, F.L. Malabar, 1984 (new edition).Search in Google Scholar

Calligaris, M., Nardin, G., and Randaccio, L. (1982) Cation-site location in a natural chabazite. Acta Crystallographica, B38, 602–605.10.1107/S0567740882003483Search in Google Scholar

Cruciani, G. (2006) Zeolites upon heating: Factors governing their thermal stability and structural changes. Journal of Physics and Chemistry of Solids, 67, 1913–2240.10.1016/j.jpcs.2006.05.057Search in Google Scholar

Danisi, R.M., Armbruster, T., Arletti, R., Gatta, G.D., Vezzalini, G., Quartieri, S., and Dmitriev, V. (2015) Elastic behavior and pressure-induced structural modifications of the microporous Ca(VO)Si4O10·4H2O dimorphs cavansite and pentagonite. Microporous and Mesoporous Materials, 204, 257–268.10.1016/j.micromeso.2014.11.029Search in Google Scholar

Dent, L.S., and Smith, J.V. (1958) Crystal structure of chabazite, a molecular sieve. Nature, 181, 1794–1796.10.1038/1811794b0Search in Google Scholar

Fei, Y., and Wang, Y. (2000) High-pressure and high-temperature powder diffraction. Reviews in Mineralogy and Geochemistry, 41, 521–557.10.1515/9781501508707-019Search in Google Scholar

Fialips, C.I., Carey, J.W., and Bish, D.L. (2005) Hydration-dehydration behavior and thermodynamics of chabazite. Geochimica et Cosmochimica Acta, 69, 2293–2308.10.1016/j.gca.2004.11.007Search in Google Scholar

Gatta, G.D. (2005) A comparative study of fibrous zeolites under pressure. European Journal of Mineralogy, 17, 411–421.10.1127/0935-1221/2005/0017-0411Search in Google Scholar

Gatta, G.D. (2008) Does porous mean soft? On the elastic behavior and structural evolution of zeolites under pressure. Zeitschrift für Kristallographie, 223, 160–170.10.1524/zkri.2008.0013Search in Google Scholar

Gatta, G.D. (2010) Extreme deformation mechanisms in open-framework silicates at high-pressure: Evidence of anomalous inter-tetrahedral angles. Microporous and Mesoporous Materials, 128, 78–84.10.1016/j.micromeso.2009.08.006Search in Google Scholar

Gatta, G.D., and Lee, Y. (2014) Zeolites at high pressure: A review. Mineralogical Magazine, 78, 267–291.10.1180/minmag.2014.078.2.04Search in Google Scholar

Gatta, G.D., Boffa Ballaran, T., Comodi, P., and Zanazzi, P.F. (2004) Comparative compressibility and equation of state of orthorhombic and tetragonal edingtonite. Physics and Chemistry of Minerals, 31, 288–298.10.1007/s00269-004-0394-ySearch in Google Scholar

Gatta, G.D., Nestola, F., and Boffa Ballaran, T. (2006) Elastic behaviour and structural evolution of topaz at high pressure. Physics and Chemistry of Minerals, 33, 235–242.10.1007/s00269-006-0075-0Search in Google Scholar

Gatta, G.D., Rotiroti, N., Fisch, M., and Armbruster, T. (2010) Stability at high pressure, elastic behavior and pressure-induced structural evolution of “Al5BO9”, a mullite-type ceramic material. Physics and Chemistry of Minerals, 37, 227–236.10.1007/s00269-009-0327-xSearch in Google Scholar

Gatta, G.D., Lotti, P., Merlini, M., Liermann, H.-P., and Fisch, M. (2013) High-pressure behavior and phase stability of Al5BO9, a mullite-type ceramic material. Journal of the American Ceramic Society, 96, 2583–2592.10.1111/jace.12411Search in Google Scholar

Gatta, G.D., Morgenroth, W., Dera, P., Petitgirard, S., and Liermann, H-P. (2014) Elastic behavior and pressure-induced structure evolution of topaz up to 45 GPa. Physics and Chemistry of Minerals, 41, 569–577.10.1007/s00269-014-0670-4Search in Google Scholar

Gatta, G.D., Lotti, P., and Tabacchi, G. (2017) The effect of pressure on open-framework silicates: elastic behaviour and crystal–fluid interaction. Physics and Chemistry of Minerals, in press, 10.1007/s00269-017-0916-z.Search in Google Scholar

Hazen, R.M., Downs, R.T., Conrad, P.G., Finger, L.W., and Gasparik, T. (1994) Comparative compressibilities of majorite-type garnets. Physics and Chemistry of Minerals, 21, 344–349.10.1007/BF00202099Search in Google Scholar

Im, J., Seoung, D., Lee, S.Y., Blom, D.A., Vogt, T., Kao, C.-C., and Lee, Y. (2015) Pressure-induced metathesis reaction to sequester Cs. Environmental Science and Technology, 49, 513–519.10.1021/es504659zSearch in Google Scholar

Kong, M., Liu, Z., Vogt, T., and Lee, Y. (2016) Chabazite structures with Li+, Na+, Ag+, K+, NH4+, Rb+ and Cs+ as extra-framework cations. Microporous and Mesoporous Materials, 221, 253–263.10.1016/j.micromeso.2015.09.031Search in Google Scholar

Larson, A.C., and Von Dreele, R.B. (2004) General structure analysis system (GSAS). Los Alamos National Laboratory Report LAUR 86-748.Search in Google Scholar

Le Bail, A., Duroy, H., and Fourquet, J.L. (1988) Ab-initio structure determination of LiSbWO6 by X-ray powder diffraction. Materials Research Bulletin, 23, 447–452.10.1016/0025-5408(88)90019-0Search in Google Scholar

Leardini, L., Quartieri, S., and Vezzalini, G. (2010) Compressibility of microporous materials with CHA topology: 1. Natural chabazite and SAPO-34. Microporous and Mesoporous Materials, 127, 219–227.10.1016/j.micromeso.2009.07.017Search in Google Scholar

Leardini, L., Quartieri, S., Martucci, A., Vezzalini, M.G., and Dmitriev, V. (2012) Compressibility of microporous materials with CHA topology: 2. ALPO-34. Zeitschrift für Kristallographie, 227, 514–521.10.1524/zkri.2012.1477Search in Google Scholar

Leardini, L., Quartieri, S., Vezzalini, G., Martucci, A., and Dmitriev, V. (2013) Elastic behavior and high pressure-induced phase transition in chabazite: New data from a natural sample from Nova Scotia. Microporous and Mesoporous Materials, 170, 52–61.10.1016/j.micromeso.2012.11.024Search in Google Scholar

Lee, Y., Liu, D., Seoung, D., Liu, Z., Kao, C.-C., and Vogt, T. (2011) Pressure- and heat-induced insertion of CO2 into an auxetic small-pore zeolite. Journal of the American Chemical Society, 133, 1674–1677.10.1021/ja109765dSearch in Google Scholar PubMed

Mao, H.K., Xu, J., and Bell, P.M. (1986) Calibration of the ruby pressure gauge to 800 kbar under quasi-hydrostatic conditions. Journal of Geophysical Research, 91, 4673–4676.10.1029/JB091iB05p04673Search in Google Scholar

McCarthy, A.C., Downs, R.T., and Thompson, R.M. (2008) Compressibility trends of the clinopyroxenes, and in-situ high-pressure single-crystal X-ray diffraction study of jadeite. American Mineralogist, 93, 198–209.10.2138/am.2008.2521Search in Google Scholar

Rietveld, H.M. (1969) A profile refinement method for nuclear and magnetic structures. Journal of Applied Crystallography, 2, 65–71.10.1107/S0021889869006558Search in Google Scholar

Seoung, D., Lee, Y., Kao, C.-C., Vogt, T., and Lee, Y. (2013) Super-hydrated zeolites: pressure-induced hydration in natrolites. Chemistry—A European Journal, 19, 10876–10883.10.1002/chem.201300591Search in Google Scholar PubMed

Seoung, D., Lee, Y., Cynn, H., Park, C., Choi, K.-Y., Blom, D.A., Evans, W.J., Kao, C.-C., Vogt, T., and Lee, Y. (2014) Irreversible xenon insertion into a small pore zeolite at moderate pressures and temperatures. Nature Chemistry, 6, 835–839.10.1038/nchem.1997Search in Google Scholar PubMed

Seoung, D., Lee, Y. Kao, C.-C., Vogt, T., and Lee, Y. (2015) Two-step pressure-induced superhydration in small pore natrolite with divalent extra-framework cations. Chemistry of Materials, 27, 3874–3880.10.1021/acs.chemmater.5b00506Search in Google Scholar

Shang, J., Li, G., Singh, R., Gu, Q., Nairn, K.M., Bastow, T.J., Medhekar, N., Doherty, C.M., Hill, A.J., Liu, J.Z., and Webley, P.A. (2012) Discriminative separation of gases by a “molecular trapdoor” mechanism in Chabazite zeolites. Journal of the American Chemical Society, 134, 19,246–19,253.10.1021/ja309274ySearch in Google Scholar PubMed

Smith, L.J., Eckert, H., and Cheetham, A.K. (2001) Potassium cation effects on site preferences in the mixed cation zeolite Li, Na-chabazite. Chemistry of Materials, 13, 385–391.10.1021/cm0006392Search in Google Scholar

Smyth, J.R., Jacobsen, S.D., and Hazen, R.M. (2000) Comparative crystal chemistry of orthosilicate minerals. Reviews in Mineralogy and Geochemistry, 41, 187–209.10.1515/9781501508707-011Search in Google Scholar

Thompson, P., Cox, D.E., and Hastings, J.B. (1987) Rietveld refinement of Debye-Scherrer synchrotron X-ray data from Al2O3. Journal of Applied Crystallography, 20, 79–83.10.1107/S0021889887087090Search in Google Scholar

Toby, B.H. (2001) EXPGUI, a graphical user interface for GSAS. Journal of Applied Crystallography, 34, 210–213.10.1107/S0021889801002242Search in Google Scholar

Weidner, D.J., Wang, Y.B., Chen, G., Ando, J., and Vaughan, M.T. (1998) Rheology measurements at high pressure and temperature. In M.H. Manghnani and T. Yagi, Eds., Properties of Earth and Planetary Materials at High Pressure and Temperature. Geophysical Monograph, p. 473–480. American Geophysical Union, Washington, D.C.10.1029/GM101p0473Search in Google Scholar

Yamanaka, T., Nagai, T., and Tsuchiya, T. (1997) Mechanism of pressure-induced amorphization. Zeitschrift für Kristallographie, 212, 401–410.10.1524/zkri.1997.212.6.401Search in Google Scholar

Zema, M., Tarantino, S.C., and Montagna, G. (2008) Hydration/dehydration and cation migration processes at high temperature in zeolite chabazite. Chemistry of Materials, 20, 5876–5887.10.1021/cm800781tSearch in Google Scholar

Received: 2017-9-20
Accepted: 2017-11-3
Published Online: 2018-1-29
Published in Print: 2018-2-23

© 2018 Walter de Gruyter GmbH, Berlin/Boston

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