Accessible Requires Authentication Published by De Gruyter January 29, 2021

Experimental evaluation of a new H2O-independent thermometer based on olivine-melt Ni partitioning at crustal pressure

Xiaofei Pu ORCID logo, Gordon M. Moore, Rebecca A. Lange, Jack P. Touran and Joel E. Gagnon
From the journal American Mineralogist

Abstract

An olivine-melt thermometer based on the partitioning of Ni DNiO1/liqwas hypothesized by Pu et al. (2017) to have a negligible dependence on dissolved water in the melt (and pressure variations from 0–1 GPa), in marked contrast to thermometers based on DMgOl/liq.In this study, 15 olivine-melt equilibrium experiments were conducted on a basaltic glass starting material (9.6 wt% MgO; 353 ppm Ni) to test this hypothesis by comparing the effect of dissolved H2O in the melt on DMgOl/liqandDNiO1/liqon the same set of experiments. Results are presented for six anhydrous experiments at 1 bar, two anhydrous experiments at 0.5 GPa, and seven hydrous experiments at 0.5 GPa. Analyzed olivine and glass compositions in the quenched run products were used to calculate DMgOl/liqandDNiO1/liqvalues for each experiment, which in turn permit temperature to be calculated with the Mg- and Ni-thermometers calibrated in Pu et al. (2017) on anhydrous, 1-bar experiments from the literature. The Ni-thermometer recovers the temperatures of all 15 experiments from this study with an average deviation of –3 °C, including those with up to 4.3 wt% H2O dissolved in the melt. In contrast, the Mg-thermometer recovers the anhydrous, 1-bar experimental temperatures within +14 °C on average, but overestimates the hydrous experimental temperatures by +49 to +127 °C, with an average of +83 °C. When the Mg-thermometer of Putirka et al. (2007) is applied, which includes a correction for analyzed H2O (≤4.3 wt%) in the quenched melts of the run products, all experimental temperatures are recovered with an average (±1σ) deviation of +7 °C. The combined results show that DNiO1/liqhas a negligible dependence on dissolved water in the melt (≤4.3 wt% H2O), which is in marked contrast to the strong dependence of DMgO1/liqon water in the melt. An understanding of why DNiO1/liqis insensitive to dissolved water, unlike DMgO1/liq,is obtained from spectroscopic evidence in the literature, which shows that Ni2+ (transition metal) and Mg2+ (alkaline earth metal) have distinctly different average coordination numbers (predominantly fourfold and sixfold, respectively) in silicate melts and that fourfold-coordinated Ni2+ is unaffected by the presence of dissolved water in the melt. This difference in coordination number explains why DNiO1/liqandDMgO1/liqeach have a different dependence on pressure, anhydrous melt composition, and melt water content. Application of the Ni-thermometer of Pu et al. (2017) to five natural samples from the Mexican arc, for which H2O contents (3.6–6.7 wt%) in olivine-hosted melt inclusions are reported in the literature, leads to temperatures that match those obtained from the Putirka et al. (2007) Mg-thermometer that corrects for analyzed H2O contents. This study demonstrates that a thermometer based on DNiOl/liqcan be applied to hydrous basalts at crustal depths without the need to correct for dissolved water content or pressure.

Acknowledgments

We thank Jean-Claude Barrette at the University of Windsor for his assistance during the numerous Laser Ablation-ICP-MS analytical sessions for this study. The μ-XANES analyses of the experimental glasses was made possible through the generous support from Katherine Kelley and Elizabeth Cottrell, who also helped improve part of this manuscript. We also thank Anthony Lanzirotti and Matthew Newville for onsite support during the XANES analytical sessions. Youxue Zhang and Adam Simon shared some of their laboratory resources unsparingly, which enabled the successful experimental efforts in this study and provided constructive comments on an earlier version of this work, which enabled the successful experimental efforts in this study, and provided constructive comments. Laura Waters provided vital suggestions that resolved some of the technical challenges in this project. Jameson Jolles helped with the thermal gradient calibration of the piston-cylinder apparatus. This study was supported by National Science Foundation grant (EAR-1551344). The operational support for GeoSoilEnviroCARS, Advanced Photon Source (APS), Argonne National Laboratory (The University of Chicago, Sector 13) was supported by the National Science Foundation—Earth Sciences (EAR-1634415) and Department of Energy (DOE)—GeoSciences (DE-FG02-94ER14466). Use of the APS facilities was supported by the DOE Office of Science by Argonne National Laboratory under Contract No. DE-AC02-06CH11357. Constructive and insightful reviews by Andrew Matzen and Keith Putirka, and additional editorial comments by Charles Lesher, led to significant improvements of the manuscript.

References cited

Albarede, F., and Provost, A. (1977) Petrological and geochemical mass-balance equations: An algorithm for least-square fitting and general error analysis. Computers and Geosciences, 3, 309–326. Search in Google Scholar

Allan, J.F., Batiza, R., Perfit, M.R., Fornari, D.J., and Sack, R.O. (1989) Petrology of lavas from the Lamont Seamount Chain and adjacent East Pacific Rise, 10°N. Journal of Petrology, 30, 1245–1298. Search in Google Scholar

Almeev, R.A., Holtz, F., Koepke, J., Parat, F., and Botcharnikov, R.E. (2007) The effect of H2O on olivine crystallization in MORB: Experimental calibration at 200 MPa. American Mineralogist, 92, 670–674. Search in Google Scholar

Asimow, P.D., and Ghiorso, M.S. (1998) Algorithmic modifications extending MELTS to calculate subsolidus phase relations. American Mineralogist, 83, 1127–1131. Search in Google Scholar

Barr, J.A., and Grove, T.L. (2010) AuPdFe ternary solution model and applications to understanding the fO2 of hydrous, high-pressure experiments. Contributions to Mineralogy and Petrology, 160, 631–643. Search in Google Scholar

Beattie, P. (1993) Olivine-melt and orthopyroxene-melt equilibria. Contributions to Mineralogy and Petrology, 115, 103–111. Search in Google Scholar

Berndt, J., Koepke, J., and Holtz, F. (2005) An experimental investigation of the influence of water and oxygen fugacity on differentiation of MORB at 200 MPa. Journal of Petrology, 46, 135–167. Search in Google Scholar

Carmichael, I.S.E., Turner, F.J., and Verhoogen, J. (1974) Igneous Petrology, 739 p. McGraw-Hill, New York. Search in Google Scholar

Carmichael, I.S.E., Frey, H.M., Lange, R.A., and Hall, C.M. (2006) The Pleistocene cinder cones surrounding Volcán Colima, Mexico re-visited: eruption ages and volumes, oxidation states, and sulfur content. Bulletin of Volcanology, 68(5), 407–419. Search in Google Scholar

Cottrell, E., Kelley, K.A., Lanzirotti, A., and Fischer, R.A. (2009) High-precision determination of iron oxidation state in silicate glass using XANES. Chemical Geology, 268, 167–179. Search in Google Scholar

Cottrell, E., Lanzirotti, A., Mysen, B., Birner, S.K., Kelley, K.A., Botcharnikov, R., Davis, F.A., and Newville, M. (2018) A Mössbauer-based XANES calibration for hydrous basalt glasses reveals radiation-induced oxidation of Fe. American Mineralogist, 103, 489–501. Search in Google Scholar

Dixon, J.E., Stolper, E.M., and Holloway, J.R. (1995) An experimental study of water and carbon dioxide solubilities in mid-ocean ridge basaltic liquids. Part I: Calibration and solubility models. Journal of Petrology, 36, 1607–1631. Search in Google Scholar

Faure, F., and Schiano, P. (2005) Experimental investigation of equilibration conditions during forsterite growth and melt inclusion formation. Earth and Planetary Science Letters, 236, 882–898. Search in Google Scholar

Galoisy, L., and Calas, G. (1993) Structural environment of nickel in silicate glass/melt system: Part 1. Spectroscopic determination of coordination states. Geochimica et Cosmochimica Acta, 57, 3613–3626. Search in Google Scholar

George, A.M., and Stebbins, J.F. (1998) Structure and dynamics of magnesium in silicate melts: A high-temperature 25Mg NMR study. American Mineralogist, 83, 1022–1029. Search in Google Scholar

Ghiorso, M.S., and Sack, R.O. (1995) Chemical mass transfer in magmatic processes. IV. A revised and internally consistent thermodynamic model for the interpolation and extrapolation of liquid-solid equilibria in magmatic systems at elevated temperatures and pressures. Contributions to Mineralogy and Petrology, 119, 197–212. Search in Google Scholar

Guillong, M., Meier, D.L., Allan, M.M., Heinrich, C.A., and Yardley, B.W.D. (2008) Appendix A6: SILLS: A Matlab-based program for the reduction of laser ablation ICP-MS data of homogeneous materials and inclusions. Mineralogical Association of Canada Short Course 40, Vancouver, 328–333. Search in Google Scholar

Hall, L.J., Brodie, J., Wood, B.J., and Carroll, M.R. (2004) Iron and water losses from hydrous basalts contained in Au80Pd20 capsules at high pressure and temperature. Mineralogical Magazine, 68(1), 75–81. Search in Google Scholar

Hammer, J.E., and Rutherford, M.J. (2002) An experimental study of the kinetics of decompression-induced crystallization in silicic melt. Journal of Geophysical Research, 107, B 1, 2021. Search in Google Scholar

Herzberg, C., and O’Hara, M. J. (2002) Plume-associated ultramafic magmas off Phanerozoic age. Journal of Petrology, 43, 1857–1883. Search in Google Scholar

Hui, H., and Zhang, Y. (2007) Toward a general viscosity equation for natural anhydrous and hydrous silicate melts. Geochimica et Cosmochimica Acta, 71, 403–416. Search in Google Scholar

Jackson, W.E., Farges, F., Yeager, M., Mabrouk, P.A., Rossano, S., Waychunas, G.A., Solomon, E.I., and Brown, G.E. (2005) Multi-spectroscopic study of Fe(II) in silicate glasses: Implications for the coordination environment of Fe(II) in silicate melts. Geochimica et Cosmochimica Acta, 69, 4315–4332. Search in Google Scholar

Johnson, E.R., Wallace, P.J., Cashman, K.V., Delgado-Granados, H., and Kent, A.J.R. (2008) Magmatic volatile contents and degassing-induced crystallization at Volcán Jorullo, Mexico: Implications for melt evolution and the plumbing systems of monogenetic volcanoes. Earth and Planetary Science Letters, 269, 478–487. Search in Google Scholar

Johnson, E.R., Wallace, P.J., Granados, H.D., Manea, V.C., Kent, A.J.R., Bindeman, I.N., and Donegan, C.S. (2009) Subduction-related volatile recycling and magma generation beneath Central Mexico: Insights from melt inclusions, oxygen isotopes and geodynamic models. Journal of Petrology, 50, 1729–1764. Search in Google Scholar

Jones, J., O’Neill, H.St.C., and Berry, A. (2011) Differential changes in Ni2+ Co2+ and Fe2+ coordination in silicate melt with pressure. Goldschmidt Conference Abstract, Mineralogical Magazine, 75, 1124. Search in Google Scholar

Kress, V.C., and Carmichael, I.S.E. (1991) The compressibility of silicate liquids containing Fe2O3 and the effect of composition, temperature, oxygen fugacity and pressure on their redox states. Contributions to Mineralogy and Petrology, 108, 82–92. Search in Google Scholar

Lange, R.A. (1997) Temperature independent thermal expansivities of sodium aluminosilicate melts between 713 and 1835 K: Erratum to R.A. Lange (1996). Geochimica et Cosmochimica Acta, 60, 4989–4996. Search in Google Scholar

Lange, R.A., and Carmichael, I. S.E. (1990) Thermodynamic properties of silicate liquids with an emphasis on density, thermal expansion and compressibility. In J. Nicholls and J.K. Russell, Eds., Modern Methods of Igneous Petrology: Understanding magmatic processes, 24, 25–64. Reviews of Mineralogy, Mineralogical Society of America, Chantilly, Virginia. Search in Google Scholar

Langmuir, C.H., Bezos, A., Escrig, S., and Parman, S.W. (2006) Chemical systematics and hydrous melting of the mantle in back-arc basins. In D.M. Christie, C.R. Fischer, S-M. Lee, and S. Givens, Eds., Back-arc Spreading Systems: Geological, biological, chemical and physical interactions, 166, 87–146. Geophysical Monograph Series, American Geophysical Union, Washington, D.C. Search in Google Scholar

Lloyd, A.S., Plank, T., Ruprecht, P., Hauri, E., and Rose, W. (2013) Volatile loss from melt inclusions in pyroclasts of differing sizes. Contributions to Mineralogy and Petrology, 165, 129–153. Search in Google Scholar

Lofgren, G. (1974) An experimental study of plagioclase crystal morphology: Isothermal crystallization. American Journal of Science, 274, 243–273. Search in Google Scholar

Luhr, J.F., and Carmichael, I.S.E. (1981) The Colima volcanic complex, Mexico: Part II. Late-quaternary cinder cones. Contributions to Mineralogy and Petrology, 76, 127–147. Search in Google Scholar

Maria, A.H., and Luhr, J.F. (2008) Lamprophyres, basanites, and basalts of the western Mexican Volcanic Belt: Volatile contents and a vein–wallrock melting relationship. Journal of Petrology, 49, 2123–2156. Search in Google Scholar

Matzen, A.K., Baker, M.B., Beckett, J.R., and Stolper, E.M. (2013) The temperature and pressure dependence of nickel partitioning between olivine and silicate melt. Journal of Petrology, 54, 2521–2545. Search in Google Scholar

Matzen, A.K., Baker, M.B., Beckett, J.R., Wood, B.J., and Stolper, E.M. (2017) The effect of liquid composition on the partitioning of Ni between olivine and silicate melt. Contributions to Mineralogy and Petrology, 172, 3. Search in Google Scholar

Médard, E., and Grove, T.L. (2008) The effect of H2O on the olivine liquidus of basaltic melts: experiments and thermodynamic models. Contributions to Mineralogy and Petrology, 155, 417–432. Search in Google Scholar

Moore, G., and Carmichael, I.S.E. (1998) The hydrous phase equilibria (to 3 kbar) of an andesite and basaltic andesite from western Mexico: Constraints on water content and conditions of phenocryst growth. Contributions to Mineralogy and Petrology, 130, 304–319. Search in Google Scholar

Moore, G., Roggensack, K., and Klonowski, S. (2008) A low-pressure-high-temperature technique for the piston-cylinder. American Mineralogist, 93, 48–52. Search in Google Scholar

Muñoz, M. (2003) Comportement d’éléments formateurs et modificateurs de réseau dans des magmas hydratés. Ph.D. thesis, Université de Marne-La-Vallée, France, 247. Search in Google Scholar

Muñoz, M., Bureau, H., Malavergne, V., Menez, B., Wilke, M., Schmidt, C., Simionovici, A., Somogyi, A., and Farges, F. (2005) In-situ speciation of Nickel in hydrous melts exposed to extreme conditions. Physica Scripta, 115, 921–922. Search in Google Scholar

Ni, H., Keppler, H., Walte, N., Schiavi, F., Chen, Y., Masotta, M., and Li, Z. (2014) In situ observation of crystal growth in a basalt melt and the development of crystal size distribution in igneous rocks. Contributions to Mineralogy and Petrology, 167, 1003. Search in Google Scholar

Ochs, F.A. III, and Lange, R.A. (1999) The density of hydrous magmatic liquids. Science, 283, 1314–1317. Search in Google Scholar

Ownby, S.E., Lange, R.A., Hall, C.M., and Delgado-Granados, H. (2011) Origin of andesite in the deep crust and eruption rates in the Tancítaro-Nueva Italia region of the central Mexican arc. Geological Society of America Bulletin, 123, 274–294. Search in Google Scholar

Parman, S.W., Grove, T.L., Kelley, K.A., and Plank, T. (2011) Along-arc variations in the pre-eruptive H2O contents of Mariana Arc magma inferred from fractionation paths. Journal of Petrology, 52, 257–278. Search in Google Scholar

Patiño Douce, A.E., and Beard, J.S. (1994) H2O loss from hydrous melts during fluid-absent piston cylinder experiments. American Mineralogist, 79, 585–588. Search in Google Scholar

Pearce, N.J.G., Perkins, W.T., Westgate, J.A., Gorton, M.P., Jackson, S.E., Neal, C.R., and Chenery, S.P. (1997) A compilation of new and published major and trace element data for NIST SRM 610 and NIST SRM 612 glass reference materials. Geostandards Newsletter, 21, 115–144. Search in Google Scholar

Pu, X. (2018) New constraints on temperature, oxygen fugacity and H2O of subduction zone basalts based on olivine-melt equilibrium. Ph.D. thesis, University of Michigan. Search in Google Scholar

Pu, X., Lange, R.A., and Moore, G. (2017) A comparison of olivine-melt thermometers based on DMg and DNi The effects of melt composition, temperature, and pressure with applications to MORBs and hydrous arc basalts. American Mineralogist, 102, 750–765. Search in Google Scholar

Putirka, K.D. (2008) Thermometers and barometers for volcanic systems. In K.D. Putirka and F.J. Tepley III, Eds., Minerals, Inclusions and Volcanic Processes, 69, 61–120. Reviews in Mineralogy and Geochemistry, Mineralogical Society of America, Chantilly, Virginia. Search in Google Scholar

Putirka, K.D., Perfit, M., Ryerson, F.J., and Jackson, M.G. (2007) Ambient and excess mantle temperatures, olivine thermometry, and active vs. passive upwelling. Chemical Geology, 241, 177–206. Search in Google Scholar

Sisson, T.W., and Grove, T.L. (1993a) Experimental investigations of the role of H2O in calc-alkaline differentiation and subduction zone magmatism. Contributions to Mineralogy and Petrology, 113, 143–166. Search in Google Scholar

Sisson, T.W., and Grove, T.L. (1993b) Temperatures and H2O contents of low-MgO high-alumina basalts. Contributions to Mineralogy and Petrology, 113, 167–184. Search in Google Scholar

Tenner, T. J., Lange, R.A., and Downs, R. T. (2007) The albite fusion curve re-examined: New experiments and the high-pressure density and compressibility of high albite and NaAlSi3O8 liquid. American Mineralogist, 92, 1573–1585. Search in Google Scholar

Vigouroux, N., Wallace, P.J., and Kent, A.J.R. (2008) Volatiles in high-K magmas from the Western Trans-Mexican Volcanic Belt: Evidence for fluid fluxing and extreme enrichment of the mantle wedge by subduction processes. Journal of Petrology, 49, 1589–1618. Search in Google Scholar

Wagner, T.P., Donnelly-Nolan, J.M., and Grove, T.L. (1995) Evidence of hydrous differentiation and crystal accumulation in the low-MgO, high Al2O3 Lake Basalt from Medicine Lake volcano, California. Contributions to Mineralogy and Petrology, 121, 201–216. Search in Google Scholar

Waters, L.E., and Lange, R.A. (2017) An experimental study of between orthopyroxene and rhyolite: a strong dependence on H2O in the melt. Contributions to Mineralogy and Petrology, 172, 1–13. Search in Google Scholar

Waters, L.E., Andrews, B.J., Lange, R.A. (2015) Rapid crystallization of plagioclase phenocrysts in silicic melts during fluid-saturated ascent: Phase equilibrium and decompression experiments. Journal of Petrology, 56, 981–1006. Search in Google Scholar

Zhang, H.L., Cottrell, E., Solheid, P.A., Kelley, K.A., and Hirschmann, M.M. (2018) Determination of Fe3+/ΣFe of XANES basaltic glass standards by Mössbauer spectroscopy and its application to the oxidation state of iron in MORB. Chemical Geology, 479, 166–175. Search in Google Scholar

Zhang, Y., Belcher, R., Ihinger, P.D., Wang, L., Xu, Z., and Newman, S. (1997) New calibration of infrared measurement of dissolved water in rhyolite glass. Geochimica et Cosmochimica Acta, 61, 3089–3100. Search in Google Scholar

Received: 2019-02-20
Accepted: 2020-05-28
Published Online: 2021-01-29
Published in Print: 2021-02-23

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