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BY-NC-ND 3.0 license Open Access Published by De Gruyter Open Access April 17, 2008

Fabrication of biaxial textured NiO on Ni in a one-step process

  • Oliver Staller EMAIL logo and Gerhard Gritzner
From the journal Open Chemistry


A novel method for the preparation of biaxial textured nickel oxide on commercially available nickel via a modified surface oxidation epitaxy (SOE) process has been developed. Following studies of different heat-treatment procedures for both texturing of nickel and for the fabrication of nickel oxide the following method was found to yield the best results. Nickel was first textured under an argon — hydrogen atmosphere at 1000°C for 120 min, then the temperature was lowered to 800°C and the atmosphere was changed to argon with 3 ppm oxygen. Smooth and crack free c-axis textured and a–b aligned NiO buffer layers with an out-of-plane texture of 7.8° and an in-plane texture of 9.4° were successfully produced. Higher oxygen partial pressure and temperatures resulted in increased surface roughness and excessive grain growth.

[1] D.P. Norton et al., Science 274, 755 (1996) in Google Scholar

[2] T.G. Woodcock, J.S. Abell, T.C. Shields, M.G. Hall, Physica C 372–376 (SUPPL. 2), 863 (2002) in Google Scholar

[3] T.G. Woodcock, J.S. Abell, M.G Hall, J. Microscopy 205, 231 (2002) in Google Scholar

[4] T. Watanabe, K. Matsumoto, T. Maeda, T. Tanigawa, I. Hirabayashi, Physica C 357–360 (SUPPL. 1), 914 (2001) in Google Scholar

[5] K. Masumoto et al., IEEE Trans. Appl. Supercond. 9, 1539 (1999) in Google Scholar

[6] C.F. Liu et al., IEEE Trans. Appl. Supercond. 9, 1471 (1999) in Google Scholar

[7] A. Kursumovic et al., Physica C 385, 337 (2003) in Google Scholar

[8] R. Hühne et al., J. Phys. D Appl. Phys. 36, 1053 (2003) in Google Scholar

[9] M.J. Graham, M.J. Cohen, Electrochem. Soc. 120, 879 (1972) in Google Scholar

[10] M.J. Graham, R.J. Hussey, M.J. Cohen Electrochem. Soc. 120, 1523 (1973) in Google Scholar

[11] K. Matsumoto et al., Physica C 335, 39 (2000) in Google Scholar

[12] Z. Lockman, X. Qi, A. Berenov, R. Nast, W. Goldacker, J. MacManus-Driscoll, Physica C 351 34 (2001) in Google Scholar

[13] J. Yang et al., Physica C 412–414, 844 (2004) in Google Scholar

[14] A. Kursumovic, R. Hühne, R. Tomov, B. Holzapfel, B.A. Glowacki, J.E. Evetts, Physica C 405, 219 (2004) in Google Scholar

[15] O. Staller, D. Holzmann, G. Gritzner, P. Diko, D. Mikolaj, F. Kováč, Cent. Eur. J. Chem. (accepted) Search in Google Scholar

[16] J.-K. Chung, W.-J. Kim, J. Tal, C.J. Kim, Physica C 463–465, 619 (2007) 296 Search in Google Scholar

Published Online: 2008-4-17
Published in Print: 2008-6-1

© 2008 Versita Warsaw

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License.

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