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BY-NC-ND 3.0 license Open Access Published by De Gruyter Open Access December 23, 2008

Estimation of platinum in environmental water samples with solid phase extraction technique using inductively coupled plasma mass spectrometry

Aleksandra Dubiella-Jackowska, Żaneta Polkowska, Lech Dariusz, Piotr Pasławski, Wojciech Staszek and Jacek Namieśnik
From the journal Open Chemistry

Abstract

A solid phase extraction technique for the determination of platinum(IV) at trace levels by inductively coupled plasma mass spectromA solid phase extraction technique for the determination of platinum(IV) at trace levels by inductively coupled plasma mass spectrometry (ICP-MS) was developed. The method was based on retention of platinum in a sample on silica gel modified with aminepropyl groups. The retention of platinum(IV) from the sample solution and the recovery of platinum with 1.0 mol L−1 thiourea solution were quantitative. The relative standard deviation (RSD) was calculated as 5% (n = 7) at the 10 ng L−1 level. The enrichment factor was found to be (50-fold) for 250 mL of water sample. Under optimum conditions, the method detection limit (MDL) was found to be 1 ng L−1 for platinum in water matrices. Recoveries of Pt from spike addition to atmospheric water samples were quantitative (80–95%). The present method was used for the determination of platinum in precipitation, throughfall and runoff water samples.

[1] M. Moldovan, Anal. Bioanal. Chem. 388, 537 (2007) http://dx.doi.org/10.1007/s00216-007-1234-y10.1007/s00216-007-1234-ySearch in Google Scholar

[2] K. Ravindra, L. Bencs, R. Van Grieken, Sci. Total Environ. 318, 1 (2004) http://dx.doi.org/10.1016/S0048-9697(03)00372-310.1016/S0048-9697(03)00372-3Search in Google Scholar

[3] K.H. Ek, G.M. Morrison, S. Rauch, Sci. Total Environ. 334, 21 (2004) http://dx.doi.org/10.1016/j.scitotenv.2004.04.02710.1016/j.scitotenv.2004.04.027Search in Google Scholar

[4] C.H. Bartholomew, Catalyst deactivation and regeneration. In: Kirk-Othmer Encyclopedia of Chemical Technology (John Wiley & Sons, Inc, 2004) 10.1002/0471238961.1415021218150209.a01.pub2Search in Google Scholar

[5] C.H. Bartholomew, Appl. Catal. A 212, 17 (2001) 10.1016/S0926-860X(00)00843-7Search in Google Scholar

[6] M. Bojanowska, Acta Agrophys. 5, 535 (2005) (in Polish) Search in Google Scholar

[7] M. Kolodziej, I. Baranowska, A. Matyja, Electroanal. 19, 1585 (2007) http://dx.doi.org/10.1002/elan.20070387610.1002/elan.200703876Search in Google Scholar

[8] N. Haus, S. Zimmermann, J. Wiegand, B. Sures, Chemosphere 66, 619 (2007) http://dx.doi.org/10.1016/j.chemosphere.2006.07.09710.1016/j.chemosphere.2006.07.097Search in Google Scholar

[9] A. Limbeck, C. Puls, M. Handler, Environ. Sci. Technol. 41, 4938 (2007) http://dx.doi.org/10.1021/es062675t10.1021/es062675tSearch in Google Scholar

[10] F. Petrucci, N. Violante, O. Senofonte, M. De Gregorio, A. Alimonti, S. Caroli, G. Forte, A. Cristaudo, Microchem. J. 76, 131 (2004) http://dx.doi.org/10.1016/j.microc.2003.11.00510.1016/j.microc.2003.11.005Search in Google Scholar

[11] E.H. Ivanova, G.D. Gentscheva, Bulg. Chem. Commun. 32, 191 (2000) Search in Google Scholar

[12] L. Bencs, K. Ravindra, R. Van Grieken, Spectrochim. Acta B 58, 1723 (2003) http://dx.doi.org/10.1016/S0584-8547(03)00162-910.1016/S0584-8547(03)00162-9Search in Google Scholar

[13] M. Hallberg, G. Renman, T. Lundbom, Wat. Air Soil Pollut. 181, 183 (2007) http://dx.doi.org/10.1007/s11270-006-9289-510.1007/s11270-006-9289-5Search in Google Scholar

[14] B. Godlewska-Żyłkiewicz, Mikrochim. Acta 147, 189 (2004) 10.1007/s00604-004-0234-2Search in Google Scholar

[15] D. Laschka, T. Striebel, J. Daub, M. Nachtwey, UWSF- Z Umweltchem. Ökotox. 8, 124 (1996) (in German) http://dx.doi.org/10.1007/BF0293929510.1007/BF02939295Search in Google Scholar

[16] C.R.M. Rao, G.S. Reddi, Trends Anal. Chem. 19, 565 (2000) http://dx.doi.org/10.1016/S0165-9936(00)00031-510.1016/S0165-9936(00)00031-5Search in Google Scholar

[17] M. Moldovan, M.M. Gómez, M.A. Palacios, Anal. Chim. Acta 478, 209 (2003) http://dx.doi.org/10.1016/S0003-2670(02)01522-210.1016/S0003-2670(02)01522-2Search in Google Scholar

[18] H. Obata, T. Yoshida, H. Ogawa, Anal. Chim. Acta 580, 32 (2006) http://dx.doi.org/10.1016/j.aca.2006.07.04410.1016/j.aca.2006.07.044Search in Google Scholar

[19] G.V. Myasoedova, O.B. Mokhodoeva, I.V. Kubrakova, Anal. Sci. 23, 1031 (2007) http://dx.doi.org/10.2116/analsci.23.103110.2116/analsci.23.1031Search in Google Scholar

[20] M. Brzezicka, I. Baranowska, Spectrochim. Acta B 56, 2513 (2001) http://dx.doi.org/10.1016/S0584-8547(01)00326-310.1016/S0584-8547(01)00326-3Search in Google Scholar

[21] B.L. Gong, Y. Wang, Anal. Bioanal. Chem. 372, 597 (2002) http://dx.doi.org/10.1007/s00216-001-1207-510.1007/s00216-001-1207-5Search in Google Scholar

[22] X. Chang, Z. Su, D. Yang, B. Gong, Q. Pu, S. Li, Anal. Chim. Acta 354, 143 (1997) http://dx.doi.org/10.1016/S0003-2670(97)00437-610.1016/S0003-2670(97)00437-6Search in Google Scholar

[23] A.G. Coedo, M.T. Dorado, I. Padilla, F. Alguacil, Anal. Chim. Acta 340, 31 (1997) http://dx.doi.org/10.1016/S0003-2670(96)00549-110.1016/S0003-2670(96)00549-1Search in Google Scholar

[24] M. Muzikar, C. Fontas, M. Hidalgo, T. Havel, V. Salvadó, Talanta 70, 1081 (2006) http://dx.doi.org/10.1016/j.talanta.2006.02.02110.1016/j.talanta.2006.02.021Search in Google Scholar

[25] A. Tunceli, Anal. Sci. 16, 81 (2000) http://dx.doi.org/10.2116/analsci.16.8110.2116/analsci.16.81Search in Google Scholar

[26] L. Elci, M. Soylak, E.B. Buyuksekerci, Anal. Sci. 19, 1621 (2003) http://dx.doi.org/10.2116/analsci.19.162110.2116/analsci.19.1621Search in Google Scholar

[27] P. Kovacheva, R. Djingova, Anal. Chim. Acta 464, 7 (2002) http://dx.doi.org/10.1016/S0003-2670(02)00428-210.1016/S0003-2670(02)00428-2Search in Google Scholar

[28] G.V. Myasoedova, E.A. Zaharchenko, O.B. Mokhodoeva, I.V. Kubrakova, V.A. Nikashina, Russ. J. Anal. Chem. 59, 536 (2004) 10.1023/B:JANC.0000030873.88087.f0Search in Google Scholar

[29] L. Chunsheng, C. Chifang, Y. Xuefeng, H. Xiaolin, M. Xueying, Talanta 44, 1313 (1997) http://dx.doi.org/10.1016/S0039-9140(97)00027-110.1016/S0039-9140(97)00027-1Search in Google Scholar

[30] A. Cantarero, M. M. Gomez, C. Camara, M. A. Palacios, Anal. Chim. Acta 296, 205 (1994) http://dx.doi.org/10.1016/0003-2670(94)80264-510.1016/0003-2670(94)80264-5Search in Google Scholar

[31] F.S. Rojas, C.B. Ojeda, J.M.C. Pavon, J. Flow Inject. Anal. 21, 128 (2004) Search in Google Scholar

[32] R. Vlasankova, V. Otruba, J. Bendl, M. Fisera, V. Kanicky, Talanta 48, 839 (1999) http://dx.doi.org/10.1016/S0039-9140(98)00100-310.1016/S0039-9140(98)00100-3Search in Google Scholar

[33] Q. Pu, Z. Su, Z. Hu, X. Chang, M. Yang, J. Anal. At. Spectrom. 13, 249 (1998) http://dx.doi.org/10.1039/a705786e10.1039/a705786eSearch in Google Scholar

[34] V. Camel, Spectrochim. Acta B 58, 1177 (2003) http://dx.doi.org/10.1016/S0584-8547(03)00072-710.1016/S0584-8547(03)00072-7Search in Google Scholar

[35] F. E. Beamish, The Analytical Chemistry of the Noble Metals (Pergamon Press, Oxford, 1966) Search in Google Scholar

[36] J. Korkisch, Handbook of Ion Exchange Resins: Their Application to Inorganic Analytical Chemistry (CRC Press, Boca Raton, 1989) 10.1016/S0003-2670(00)83364-4Search in Google Scholar

[37] P. Kovacheva, R. Djingova, Anal. Chim. Acta 464, 7 (2002) http://dx.doi.org/10.1016/S0003-2670(02)00428-210.1016/S0003-2670(02)00428-2Search in Google Scholar

[38] T. Meisel, J. Moser, N. Fellner, W. Wegscheider, Analyst 126, 322 (2001) http://dx.doi.org/10.1039/b007575m10.1039/b007575mSearch in Google Scholar PubMed

[39] U. Dziwulska, A. Bajguz, B. Godlewska-Żyłkiewicz, Anal. Lett. 37, 2189 (2004) http://dx.doi.org/10.1081/AL-20002669610.1081/AL-200026696Search in Google Scholar

[40] Z. Fan, Chem. J. Internet 6 (2004), http://www.chemistrymag.org/cji/2004/064023pe.htm Search in Google Scholar

[41] T. Schilling, P. Schramel, B. Michalke, G. Knapp, Microchim. Acta 124, 235 (1996) http://dx.doi.org/10.1007/BF0124282110.1007/BF01242821Search in Google Scholar

[42] J. Kowalska, M. Asztemborska, B. GodlewskaŻyłkiewicz, J. Golimowski, Microchim. Acta 150, 55 (2005) http://dx.doi.org/10.1007/s00604-005-0332-910.1007/s00604-005-0332-9Search in Google Scholar

[43] B. Godlewska-Żyłkiewicz, Anal. Bioanal. Chem. 372, 593 (2002) http://dx.doi.org/10.1007/s00216-001-1206-610.1007/s00216-001-1206-6Search in Google Scholar PubMed

Published Online: 2008-12-23
Published in Print: 2009-3-1

© 2009 Versita Warsaw

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License.

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