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BY-NC-ND 3.0 license Open Access Published by De Gruyter Open Access February 17, 2011

Synthesis and characterization of coordination polymers prepared from CuII and NiII cyclam perchlorate and carmosine

Mihaela Vlassa, George Borodi, Gabriela Blăniţa, Ileana Cojocaru, Mircea Vlassa and Cristian Silvestru
From the journal Open Chemistry

Abstract

Reaction of [CuII(cyclam)](ClO4)2 or [NiII(cyclam)](ClO4)2 in DMF with aqueous 4-hydroxy-3-(4-sulfonato-1-naphthylazo)naphthalen-1-sulfonate disodium salt (carmoisine) yielded coordination polymers {[CuII(cyclam)](carmoisine dianion)(H2O)5}n and powder {[NiII(cyclam)](carmoisine dianion)}n, respectively (cyclam = 1,4,8,11-tetrazacyclotetradecane). They were characterized by powder X-ray diffraction, IR, Raman spectrometry and TGA.

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Published Online: 2011-2-17
Published in Print: 2011-4-1

© 2011 Versita Warsaw

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License.

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