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BY-NC-ND 3.0 license Open Access Published by De Gruyter Open Access February 17, 2011

Influence of land development on heavy metal forms in the Bobrza River ecosystem (Świętokrzyskie Province, Poland)

Anna Rabajczyk
From the journal Open Chemistry

Abstract

Metals are perceived as pollutants but they are also natural substances found in the environment. The surface water environment is under the influence of continuing industrial pollution/effluents. Therefore it is necessary to determine various metal forms present in each component of the water ecosystem. The study presents analysis for Cd, Cu, Cr, Fe, Mn, Ni, Zn and Pb content in the Bobrza River bottom deposits and water. The analysis of water and sediment samples from the Bobrza River taken from the littoral zone at three sampling points: the riverhead, i.e. the natural environment; Białogon — the acidic environment; and Sitkówka-Nowiny — the alkaline environment, were analyzed. Sample quality indicators were defined with pH value, conductivity, heavy metal content for water and suspended matter samples. The metal forms in river sediment were also analyzed. The sediment samples were subjected to Tessier’s five-stage sequential extraction procedure assisted by microwave radiation. Analyte concentration in water samples and in the extracts was determined with the use of F-AAS and GF-AAS techniques. The results obtained reveal a relationship between land development, the degree of metal bonding with suspended matter and metal forms found in river sediments.

[1] A. Rabajczyk, E. Sykała, Humic Substances in Ecosystems 8, 134 (2009) Search in Google Scholar

[2] J.D. Luck, S.R. Workman, M.S. Coyne, S.F. Higgins, Biosystem Engineering 100(3), 401 (2008) http://dx.doi.org/10.1016/j.biosystemseng.2008.03.01110.1016/j.biosystemseng.2008.03.011Search in Google Scholar

[3] M. Saeedi, S.H. Daneshvar, A.R. Karbassi, International Journal of Environmental Science & Technology 1(2), 135 (2004) 10.1007/BF03325826Search in Google Scholar

[4] Y. Ding, R. Dresnack, P. C. Chan, Internal Report: Assessment of High-Rate Sedimentation Processes: Microcarrier Weighted Coagulation Jar Tests (EPA/600/X-99/033), New Jersey (1999) Search in Google Scholar

[5] G. Blo, C. Contado, C. Conato, F. Dondi, Separation and Elemental Characterization of water born particles. In: J. Namieśnik, W. Chrzanowski, P. Szpinek (Eds.), New Horizons and Challenges in Environmental Analysis and Monitoring (Centre of Excellence in Environmental Analysis and Monitoring, Gdańsk, 2003) Search in Google Scholar

[6] R.M. Cenci, J.-M. Martin, Science of the Total Environment 332, 167 (2004) http://dx.doi.org/10.1016/j.scitotenv.2004.01.01810.1016/j.scitotenv.2004.01.018Search in Google Scholar

[7] Ch. Horng, Sh. Wang, I. Cheng, J. of Experimental Marine Biology and Ecology 371, 68 (2009) http://dx.doi.org/10.1016/j.jembe.2009.01.00810.1016/j.jembe.2009.01.008Search in Google Scholar

[8] J.J. Vicente-Martorell, M.D. Galindo-Riano, M. Garcia-Vargas, M.D. Granado-Castro, J. Hazard. Mat. 162, 823 (2009) http://dx.doi.org/10.1016/j.jhazmat.2008.05.10610.1016/j.jhazmat.2008.05.106Search in Google Scholar

[9] V.K. Gaur, S.K. Gupta, S.D. Pandey, K. Gopal, V. Misra, Environ. Monit. Assess. 102, 419 (2005) http://dx.doi.org/10.1007/s10661-005-6395-610.1007/s10661-005-6395-6Search in Google Scholar

[10] A. Tessier, P. Campbell, M. Bisson, Anal. Chem. 51(7), 844 (1979) http://dx.doi.org/10.1021/ac50043a01710.1021/ac50043a017Search in Google Scholar

[11] H. Irving, R.J.P. Williams, Nature 162, 746 (1948) http://dx.doi.org/10.1038/162746a010.1038/162746a0Search in Google Scholar

[12] F.H. Frimmel, Vom Wasser, 53, 243 (1979) Search in Google Scholar

[13] B. Żukowska, J. Pacyna, J. Namieśnik, Ecol. Chem. Eng., 14(S4), 199 (2007) Search in Google Scholar

[14] S.E. Manahan, Toxicological chemistry and biochemistry (Lewis Publishers, CRC Press Company, Boca Raton-London-New York-Washington, 2003) Search in Google Scholar

[15] M.G. Macklin, In: M.G. Anderson, D.E. Walling, P. Bates (Eds.), Floodplain Processes (Chichester, Wiley, 1996) Search in Google Scholar

[16] J. Lewin, M.G. Macklin, In: V. Gardiner (Ed.), Metal mining and floodplain sedimentation in Britain. First International Conference on Geomorphology, Manchester, United Kingdom, 1985 (Wiley, Chichester, 1986) 1009-1027 Search in Google Scholar

[17] P.A. Brewer, M.P. Taylor, Catena 30, 229 (1997) http://dx.doi.org/10.1016/S0341-8162(97)00017-910.1016/S0341-8162(97)00017-9Search in Google Scholar

Published Online: 2011-2-17
Published in Print: 2011-4-1

© 2011 Versita Warsaw

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License.

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