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BY-NC-ND 3.0 license Open Access Published by De Gruyter Open Access March 22, 2011

Competitive adsorption of toxic metals on activated carbon

Marek Šváb, Kateřina Sukdolová and Martina Švábová
From the journal Open Chemistry


Competitive adsorption of zinc and copper on activated carbon is studied in this article. Main aim was to suggest an advanced model for competitive adsorption of both metals considering pH influence and precipitation. A surface-complexation approach was employed for the modeling. Two models were considered: simple adsorption and ion exchange. System “The Geochemists Workbench” was used for calculation of both static and dynamic adsorption tasks. From the batch experiments, concentration of four types of sorbing sites on the carbon surface and its protonation and sorption constants were deduced. Then, batch competitive adsorption experiments were compared with the models’ results. Finally, a column experiment (fixed bed adsorption) was carried out. It was observed that the model of ion exchange can satisfyingly predict both chromatographic effect and increase of zinc concentration in effluent over its initial value, although a quantitative agreement between the model and the experiment was not totally precise.

[1] A.P. Sincero, G.A. Sincero, Physical-Chemical Treatment of Water and Wastewater (CRC Press, Boca Raton, 2002) in Google Scholar

[2] P.Y. Kumar et al., J. Hazard. Mater. B137, 1246 (2006) in Google Scholar PubMed

[3] Ch. Yan, J. Hazard. Mater., in press Search in Google Scholar

[4] A.E. Ofomaja et al., Bioresour. Technol. 101, 3844 (2010) in Google Scholar PubMed

[5] H.Ch. Khim, J. Hazard. Mater. 177, 1006 (2010) in Google Scholar PubMed

[6] B. Salamatinia, Chem. Eng. J. 145, 259 (2008) in Google Scholar

[7] M. Svab, L. Wimmerova, Groundwater: Modelling, Management And Contamination (Nova Science Publishers Inc., New York, 2008) 133–147 Search in Google Scholar

[8] E. Eriksson, Principles and applications of hydrochemistry (Chapman and Hall, London, 1985) 10.1007/978-94-009-4836-5Search in Google Scholar

[9] C.M. Bethke, Geochemical Reaction Modelling (Oxford University Press, New York, 1996) 10.1093/oso/9780195094756.003.0018Search in Google Scholar

[10] D.A. Dzombak, F.M.M. Morel, Surface Complexation Modelling (J.Wiley&Sons, Hoboken, 1990) Search in Google Scholar

[11] R.T. Yang, Adsorbents: Fundaments and Application (J. Wiley&Sons, Hoboken, 2003) in Google Scholar

[12] X. Guo et al., J. Hazard. Mater. 151, 134 (2008) in Google Scholar PubMed

Published Online: 2011-3-22
Published in Print: 2011-6-1

© 2011 Versita Warsaw

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License.

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