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BY-NC-ND 3.0 license Open Access Published by De Gruyter Open Access July 24, 2011

Partition coefficients of ketones, phenols, aliphatic and aromatic acids, and esters in n-hexane/nitromethane

Urszula Kotowska and Valery Isidorov
From the journal Open Chemistry

Abstract

Liquid-liquid partition is used in sample preparation and in countercurrent and liquid-liquid chromatographic separations. Partition coefficients are widely used in toxicology, environmental, and analytical chemistry. The K hn determination procedure for the n-hexane/nitromethane system was optimized and partition coefficients for 99 ketones, esters and trimethylsilyl derivatives of phenols, aliphatic and aromatic acids were determined. For 130 compounds, K hn values were predicted using mathematical relationships between K hn and other physicochemical and structural parameters.

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Published Online: 2011-7-24
Published in Print: 2011-10-1

© 2011 Versita Warsaw

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License.

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