Skip to content
BY-NC-ND 3.0 license Open Access Published by De Gruyter Open Access July 24, 2011

Analysis of crystallographic and structural data of polymeric FeM (M = transition metals, lanthanides) complexes

Milan Melnik and Ján Garaj
From the journal Open Chemistry

Abstract

This review covers crystallographic and structural data for almost fifty polymeric FeM complexes (M = transition Cu, Ag, Au, Mo, W, Mn, Co, Ni and Pt and lanthanide elements Sm, Er and Yb) where iron is involved in polymeric chains. The complexes are for the most part yellow or black, but there are complexes of brown, orange, red, purple, blue and green colour. The complexes crystallized in the monoclinic (by far prevails), triclinic, tetragonal, orthorhombic, trigonal, hexagonal and rhombohedral crystal classes. The iron atoms are found in oxidation states 0, +2 and +3, of which +3 by far prevails. The inner coordination spheres about the Fe(0) atom are tetrahedral (FeC4) or sandwiched (FeC10), Fe(II) atoms are six-coordinated, and Fe(III) are six or even seven-coordinated. The inner coordination about M atoms range from four- through six- to eight-coordinated. The shortest Fe-Fe, Fe-M (transition) and Fe-M (lanthanide) and M-M separations are: 8.08 Å, 3.033 Å for Fe-Cu, 3.010 Å for Fe-Yb and 2.505 Å for Mo-Mo.

[1] M. Melník, Z. Baloghová, I. Ondrejkovičová, V. Vančová, C.E. Holloway, Rev. Inorg. Chem. 26, 1 (2006) http://dx.doi.org/10.1515/REVIC.2006.26.1-2-3.110.1515/REVIC.2006.26.1-2-3.1Search in Google Scholar

[2] M. Melník, I. Ondrejkovičová, D. Mikloš, P. Segl’a, C.E. Holloway, Rev. Inorg. Chem. 27, 67 (2007) http://dx.doi.org/10.1515/REVIC.2007.27.2-3-4.6710.1515/REVIC.2007.27.2-3-4.67Search in Google Scholar

[3] M. Melník, I. Ondrejkovičová, M. Sundberg, C.E. Holloway, Rev. Inorg. Chem. 28, 237 (2008) http://dx.doi.org/10.1515/REVIC.2008.28.4-5-6.23710.1515/REVIC.2008.28.4-5-6.237Search in Google Scholar

[4] M. Melník, I. Ondrejkovičová, M. Koman, C.E. Holloway, Rev. Inorg. Chem. 30, 1 (2010) http://dx.doi.org/10.1515/REVIC.2010.30.1-2.110.1515/REVIC.2010.30.1-2.1Search in Google Scholar

[5] M. Melnik, C.E. Holloway, Rev. Inorg. Chem. (in press) Search in Google Scholar

[6] M. Melník, J. Garaj, C.E. Holloway, In: A.G. Mirsky (Ed.), Thermochemistry and Advances in Chemistry Research (Nova Sc. Publ. Inc., New York, 2009) chapter 8, pp. 217–250 Search in Google Scholar

[7] M. Melník, M. Sundberg, R. Uggla, Main Group Met. Chem. (in press) Search in Google Scholar

[8] M. Melník, M. Sundberg, R. Uggla, Main Group Met. Chem. (in press) Search in Google Scholar

[9] G.O. Morpurgo, V. Morini, P. Porta, G. Dessy, V. Faras, J. Chem. Soc., Dalton Trans. 1272 (1980) 10.1039/dt9800001272Search in Google Scholar

[10] G.O. Morpugo, V. Morini, P. Porta, G. Bessy, V. Faras, J. Chem. Soc., Dalton Trans. 111 (1981) 10.1039/dt9810000111Search in Google Scholar

[11] H. Zhong, D.-Zh. Liao, P. Cheng, Z.-H. Jiong, S.-P. Yan, G.-L. Wang, X.-K. Yao, H.-G. Wang, J. Chem. Soc., Dalton Trans. 1503 (1997) Search in Google Scholar

[12] T. Kaufmann, B. Shamsai, R.S. Lee, R. Ban, G.M. Miskelly, Inorg. Chem. 34, 5073 (1995) http://dx.doi.org/10.1021/ic00124a02510.1021/ic00124a025Search in Google Scholar

[13] Morgenstan-Baradau, D. Laroque, E. Bill, H. Winkler, A.X. Trautwein, F. Robert, Y. Jannin, Inorg. Chem. 30, 3180 (1991) http://dx.doi.org/10.1021/ic00016a01510.1021/ic00016a015Search in Google Scholar

[14] P. Gomez-Romero, G.B. Jameson, J.J. Bornas-Almenar, E. Escriva, E. Coronado, D. Belron, J. Chem. Soc., Dalton Trans. 2747 (1988) 10.1039/DT9880002747Search in Google Scholar

[15] L.R. Masinboni, M.M. Thacheray, Acta Crystallog., Sec. B 30, 1072 (1974) http://dx.doi.org/10.1107/S056774087400428610.1107/S0567740874004286Search in Google Scholar

[16] X. Solans, M.F. Abtaba, J. Garcia-Oricain, Acta Crystallogr., Sec. C40, 635 (1984) http://dx.doi.org/10.1107/S010827018400515110.1107/S0108270184005151Search in Google Scholar

[17] O. Crespo, M.C. Gimeno, D.G. Jones, A. Laguna, C. Sarroca, J. Chem. Soc., Chem. Commun. 1481 (1998) 10.1039/a803087aSearch in Google Scholar

[18] M.C. Gimeno, P.G. Jones, A. Laguna, G. Sarroca, J. Chem. Soc., Dalton Trans. 1277 (1998) Search in Google Scholar

[19] A. Houlton, D.M.P. Mingos, D.M. Murphy, D.J. Wiliams, L.-T. Phang, T.S.A. Hor, J. Chem. Soc. Dalton Trans. 3629 (1993) 10.1039/DT9930003629Search in Google Scholar

[20] L.-T. Phang, T.S. Andy Hor, Zh.-Y. Zhou, T.C.V. Mak, J. Organomet. Chem. 469, 253 (1994) http://dx.doi.org/10.1016/0022-328X(94)88080-810.1016/0022-328X(94)88080-8Search in Google Scholar

[21] H. Liu, L. Xu, J. Huang, W. Chen, Q. Zhang, Acta Crystallogr., Sect. C 52, 69 (1996) http://dx.doi.org/10.1107/S010827019500292710.1107/S0108270195002927Search in Google Scholar

[22] L. Xu, Zh. Li, Huang, H. Liu, J. Huang, Q. Zhang, Chem. Eur. J. 3, 226 (1997) http://dx.doi.org/10.1002/chem.1997003021010.1002/chem.19970030210Search in Google Scholar

[23] L.A. Meyer, R. Haushalter, Inorg. Chem. 32, 1579 (1993) http://dx.doi.org/10.1021/ic00061a01110.1021/ic00061a011Search in Google Scholar

[24] D.I. Mulica, D.B. Tippin, E.L. Sapenfield, Inorg. Chim. Acta. 174, 129 (1990) http://dx.doi.org/10.1016/S0020-1693(00)80287-X10.1016/S0020-1693(00)80287-XSearch in Google Scholar

[25] H. Henkel, D. Babel, Z. Naturforsch. 39B, 880 (1984) Search in Google Scholar

[26] N. Re, E. Gallo, C. Floriani, H. Miyasaka, N. Matsumoto, Inorg. Chem. 35, 6004 (1996) http://dx.doi.org/10.1021/ic960556g10.1021/ic960556gSearch in Google Scholar

[27] H. Miyasaka, N. Matsumoto, H. Okawa, N. Ra, E. Galld, C. Floriani, J. Amer. Chem. Soc. 118, 981 (1996) http://dx.doi.org/10.1021/ja952706c10.1021/ja952706cSearch in Google Scholar

[28] R. Peleux, H.W. Schmalc, R. Huber, P. Fischer, T. Hauss, B Ouladdiaf, S. Decurtins, Inorg. Chem. 36, 2301 (1997) http://dx.doi.org/10.1021/ic960838g10.1021/ic960838gSearch in Google Scholar PubMed

[29] S.G. Carling, C. Mathoniere, P. Day, K.M Abdul Malik, S.J. Coles, M.B. Hursthouse, J. Chem. Soc., Dalton Trans. 1839 (1996) Search in Google Scholar

[30] M. Clemente-León, E. Coronado, J.R. Galán-Mascarós, C.J. Gómer-Garciá, Chem. Commun. 1727 (1997) 10.1039/a703712kSearch in Google Scholar

[31] H. Furutachi, H. Okawa, Inorg. Chem. 36, 3911 (1997) http://dx.doi.org/10.1021/ic970056310.1021/ic9700563Search in Google Scholar

[32] M. Ohba, N. Usuki, N. Fukita, H. Okawa, Inorg. Chem. 37, 3349 (1998) http://dx.doi.org/10.1021/ic970474810.1021/ic9704748Search in Google Scholar

[33] T. Kitazawa, N. Furunaga, M. Takahashi, M. Takeda, Mol. Cryst. Sci. Technol., Sect A 244, 331 (1994) http://dx.doi.org/10.1080/1058725940805012610.1080/10587259408050126Search in Google Scholar

[34] H. Yuge, C.H. Kim, T. Iwamoto, T. Kitazawa, Inorg. Chim. Acta 257, 217 (1997) http://dx.doi.org/10.1016/S0020-1693(96)05484-910.1016/S0020-1693(96)05484-9Search in Google Scholar

[35] T. Nakano, T. Miyoshi, T. Iwamoto, Y. Sasaki, Bull. Chem. Soc. Japan 40, 1297 (1967) http://dx.doi.org/10.1246/bcsj.40.129710.1246/bcsj.40.1297Search in Google Scholar

[36] T. Kitazawa, Y. Gomi, M. Takahashi, M. Takeda, M. Enomoto, A. Miyzaki, T. Enoki, J. Mater. Chem. 6, 119 (1996) http://dx.doi.org/10.1039/jm996060011910.1039/jm9960600119Search in Google Scholar

[37] M. Ohba, H. Okawa, N. Fukita, Y. Hashimoto, J. Amer. Chem. Soc. 119, 1011 (1997) http://dx.doi.org/10.1021/ja962198m10.1021/ja962198mSearch in Google Scholar

[38] N. Fukita, M. Ohba, H. Okawa, K. Matsuda, H. Iwamura, Inorg. Chem. 37, 842 (1998) http://dx.doi.org/10.1021/ic971116810.1021/ic9711168Search in Google Scholar

[39] J.S. Miller, J.C. Calabrese, A.J. Epstain, Inorg. Chem. 28, 4230 (1989) http://dx.doi.org/10.1021/ic00322a01210.1021/ic00322a012Search in Google Scholar

[40] V. Krasnikov, M. Vaivada, Z. Konstants, J. Solid State Chem. 74, 9 (1988) http://dx.doi.org/10.1016/0022-4596(88)90323-410.1016/0022-4596(88)90323-4Search in Google Scholar

[41] S. Dommann, H. Vetsch, F. Hulliger, W. Petter, Acta Crystalogr., Sect. C 46, 1992 (1990) http://dx.doi.org/10.1107/S010827019000268210.1107/S0108270190002682Search in Google Scholar

[42] H. Deng, S.G. Shore, J. Amer. Chem. Soc. 113, 8538 (1991) http://dx.doi.org/10.1021/ja00022a06110.1021/ja00022a061Search in Google Scholar

[43] H. Deng, S.-H. Chum, P. Florian, P.J. Grandinetti, S.G. Shore, Inorg. Chem. 35, 3891 (1996) http://dx.doi.org/10.1021/ic951511310.1021/ic9515113Search in Google Scholar PubMed

Published Online: 2011-7-24
Published in Print: 2011-10-1

© 2011 Versita Warsaw

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License.

Scroll Up Arrow