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BY-NC-ND 3.0 license Open Access Published by De Gruyter Open Access July 19, 2013

Development of a screening method for the determination of xenobiotic organic pollutants in municipal landfill leachate using solvent extraction and comprehensive GCxGC-qMS analysis

  • Mihail Beldean-Galea EMAIL logo , Jerome Vial and Didier Thiebaut
From the journal Open Chemistry


In the present study, we propose a method for the evaluation of different classes of xenobiotic organic compounds enclosed in the municipal landfill leachate using comprehensive two-dimensional gas chromatography coupled with quadrupole mass spectrometry (GCxGC-qMS). Here we show that, due to high peak capacity of comprehensive two-dimensional gas chromatography, in a single run it is possible to separate compounds with different physical-chemical properties (such as aliphatic and aromatic compounds, polyaromatic hydrocarbons, phenols, phthalates, aldehydes, ketones, nitrogen containing compounds, organo-phosphoric flame retardants etc.), compounds which have proved to be endocrine disruptors, compounds that are persistent, bioaccumulative and toxic, carcinogenic, mutagenic, teratogenic, reprotoxic or harmful for the environment. Even though a solvent extraction method has been optimised, the extraction step still remains the main problem for a comprehensive characterization of all classes of organic toxicants enclosed in the municipal landfill leachate.

[1] A.A. Bakare, A.A. Mosuro, O. Osibanjo, Mutant Res-Gen Tox. En. 582(1–2), 28 (2005) in Google Scholar

[2] P. Moy, N. Krishnan, P. Ulloa, S. Cohen, P.W. Brandt-Rauf, J. Environ. Manag. 87, 73 (2008) in Google Scholar

[3] L. Morselli, C. De Robertis, J. Luzi, F. Passarini, I. Vassura, J. Hazard. Mat. 159, 505 (2008) in Google Scholar

[4] R.J. Slack, J.R. Gronowb, N. Voulvoulis, Sci. Total Environ. 337, 119 (2005) in Google Scholar

[5] D. Baderna, S. Maggioni, E. Boriani, S. Gemmab, M. Molteni, A. Lombardo, A. Colombo, S. Bordonali, G. Rotella, M. Lodi, E. Benfenati, Environ Res. 111, 603 (2011) in Google Scholar

[6] T.H. Christensen, P. Kjeldsen, H.J. Albrechtsen, H.J. Heron, P.H. Nielsen, P.L. Bjerg, P.E. Holm, Crit. Rev. Environ. Sci. Technol. 24, 119 (1994) in Google Scholar

[7] Search in Google Scholar

[8] R. Li, D. Yue, J. Liu, and Y. Nie, Waste Manage. 29, 2527 (2009) in Google Scholar

[9] E. Benfenati, P. Pierucci, R. Fanelli, A. Preiss, M. Godejohann, M. Astratov, K. Levsen, D. Barceló, J. Chromatogr. A 831(2), 243 (1999) in Google Scholar

[10] J. Schwarzbauer, S. Heim, S. Brinker, R. Littke, Water Res. 36(9), 2275 (2002) in Google Scholar

[11] J. Schwarzbauer, S. Heim, B. Krooss, R. Littke, Organic Geochem. 37(12), 2026 (2006) in Google Scholar

[12] T. Eggen, M. Moeder, A. Arukwe, Sci. Total Environ. 408, 5147 (2010) in Google Scholar

[13] Y. Xu, Y. Zhou, D. Wang, S. Chen, J. Liu, Z. Wang, J. Environ. Sci. 20, 1281 (2008) in Google Scholar

[14] C. Zhang, R.P. Eganhouse, J. Pontolillo, I.M. Cozzarelli, Y. Wang, J. Chromatogr. A 1230, 110 (2012) in Google Scholar PubMed

[15] A. Preiss, E. Berger-Preiss, M. Elend, S. Gerling, S. Kühn, S. Schuchardt, Anal. Bioanal. Chem. 403(9), 2553 (2012) in Google Scholar PubMed

[16] C. Zhang, Y. Wang, S. Qi, J. Chromatogr. B 874, 1 (2008) in Google Scholar PubMed

[17] J. Busch, L. Ahrens, R. Sturm, R. Ebinghaus, Environ. Pollut. 158, 1467 (2010) in Google Scholar PubMed

[18] S. Liyan, Z. Youcai, S. Weimin, L. Ziyang, J. Hazard. Mat. 163, 1084 (2009) in Google Scholar PubMed

[19] B. Ozkaya. J. Hazard. Mat. B124, 107 (2005) in Google Scholar PubMed

Published Online: 2013-7-19
Published in Print: 2013-10-1

© 2013 Versita Warsaw

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License.

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