Skip to content
BY-NC-ND 3.0 license Open Access Published by De Gruyter Open Access February 9, 2013

Structural properties of transparent Ti-V oxide semiconductor thin films

  • Karolina Sieradzka EMAIL logo , Danuta Kaczmarek , Jerzy Morgiel , Jaroslaw Domaradzki , Eugeniusz Prociow and Bogdan Adamiak
From the journal Open Physics

Abstract

Transparent oxide semiconducting thin films based on mixed Ti-V oxides were prepared using a modified reactive magnetron sputtering method. Based on structural investigations performed with the help of x-ray diffraction and transmission electron microscopy analysis, two distinct regions in the prepared thin film have been observed: a nanocrystalline TiO2-V2O3-V2O5 mixed composition, and a thin layer consisting of amorphous phase and nanocystalline TiO2 phase deposited directly at the substrate. Optical measurements show excellent transmission in the visible spectral range of 73%, on average. Resistivity of the thin film was found at the order of 105 Ω cm at room temperature. The preparation of mixed Ti-V oxides provides a combination of high transparency and semiconducting properties.

[1] S. M. Islam, J. V. Longeeswaran, IEEE Commun. Mag. 48, 112 (2010) http://dx.doi.org/10.1109/MCOM.2010.547387210.1109/MCOM.2010.5473872Search in Google Scholar

[2] Y. D. Tretyakov, E. A. Goodilin, Russ. Chem. Rev. 78, 801 (2009) http://dx.doi.org/10.1070/RC2009v078n09ABEH00402910.1070/RC2009v078n09ABEH004029Search in Google Scholar

[3] A. Facchetti, T. J. Marks, Transparent Electronics — From Synthesis to Applications (John Wiley and Sons Ltd., United Kingdom, 2010) http://dx.doi.org/10.1002/978047071060910.1002/9780470710609Search in Google Scholar

[4] J. F. Wager, Thin Solid Films 516, 1755 (2008) http://dx.doi.org/10.1016/j.tsf.2007.06.16410.1016/j.tsf.2007.06.164Search in Google Scholar

[5] M. G. Blamire, J. L. MacManus-Driscoll, N. D. Mathur, Z. H. Barber, Adv. Mater. 21, 3827 (2009) http://dx.doi.org/10.1002/adma.20090094710.1002/adma.200900947Search in Google Scholar

[6] T. Kamiya, H. Hosono, Int. J. Appl. Ceram. Tec. 2, 285 (2005) http://dx.doi.org/10.1111/j.1744-7402.2005.02033.x10.1111/j.1744-7402.2005.02033.xSearch in Google Scholar

[7] T. Minami, Thin Solid Films 516, 5822 (2006) http://dx.doi.org/10.1016/j.tsf.2007.10.06310.1016/j.tsf.2007.10.063Search in Google Scholar

[8] A. N. Banerjee, Nanotechnol. Sci. Appl. 4, 35 (2011) http://dx.doi.org/10.2147/NSA.S904010.2147/NSA.S9040Search in Google Scholar PubMed PubMed Central

[9] H. Natsuhara et al., Sol. Energ. Mat. Sol. C. 90, 2867 (2006) http://dx.doi.org/10.1016/j.solmat.2006.05.00110.1016/j.solmat.2006.05.001Search in Google Scholar

[10] E. Szalkowska, J. Gluszek, J. Masalski, W. Tylus, J. Mater. Sci. Lett. 20, 495 (2001) http://dx.doi.org/10.1023/A:101095581187110.1023/A:1010955811871Search in Google Scholar

[11] B. S. Richards, Sol. Energ. Mat. Sol. C. 79, 369 (2003) http://dx.doi.org/10.1016/S0927-0248(02)00473-710.1016/S0927-0248(02)00473-7Search in Google Scholar

[12] M. A. Gillispie, M. F. A. M. van Hest, M. S. Dabney, J. D. Perkins, D. S. Ginley, J. Mater. Res. 22, 2832 (2007) http://dx.doi.org/10.1557/JMR.2007.035310.1557/JMR.2007.0353Search in Google Scholar

[13] Y. Sato, H. Akizuki, T. Kamiyama, Y. Shigesato, Thin Solid Films 516, 5758 (2008) http://dx.doi.org/10.1016/j.tsf.2007.10.04710.1016/j.tsf.2007.10.047Search in Google Scholar

[14] T. Hitosugi et al., Appl. Phys. Express 1, 111203/1 (2008) http://dx.doi.org/10.1143/APEX.1.11120310.1143/APEX.1.111203Search in Google Scholar

[15] J. Domaradzki, Thin Solid Films 497, 243 (2006) http://dx.doi.org/10.1016/j.tsf.2005.10.08710.1016/j.tsf.2005.10.087Search in Google Scholar

[16] K. Sieradzka et al., Cent. Eur. J. Phys. 9, 313 (2011) http://dx.doi.org/10.2478/s11534-010-0094-910.2478/s11534-010-0094-9Search in Google Scholar

[17] K. Sieradzka, E. L. Prociow, J. Domaradzki, M. Mazur, D. Kaczmarek, In: J. Domaradzki (Ed.), International Students and Young Scientists Workshop ‘Photonics and Microsystems’, 25–27 Jun. 2009, Wernigerode, Germany (GS Media, Wroclaw, 2009) 72 http://dx.doi.org/10.1109/STYSW.2009.547029910.1109/STYSW.2009.5470299Search in Google Scholar

[18] K. Sieradzka et al., Thin Solid Films 520, 3472 (2012) http://dx.doi.org/10.1016/j.tsf.2011.12.05010.1016/j.tsf.2011.12.050Search in Google Scholar

[19] R. Akbarzadeh, S. B. Umbarkar, R. S. Sonawane, S. Takle, M. K. Dongare, Appl. Catal. A-Gen. 374, 103 (2010) http://dx.doi.org/10.1016/j.apcata.2009.11.03510.1016/j.apcata.2009.11.035Search in Google Scholar

[20] I. Tsuyumoto, K. Nawa, Solid State Ionics 179, 1227 (2008) http://dx.doi.org/10.1016/j.ssi.2008.01.06110.1016/j.ssi.2008.01.061Search in Google Scholar

[21] R. Fajgar, J. Kupcik, J. Subrt, F. Novotny, In: R. Zboril (Ed.), 2nd International Conference on Nanotechnology, Oct 12–14, 2010, Olomouc, Czech Republic (Tanger Ltd., Ostrava, Czech Republic) 398 Search in Google Scholar

[22] K. Sieradzka, J. Domaradzki, E. L. Prociow, M. Mazur, M. Lapinski, Acta Phys. Pol. A 116, 33 (2009) 10.12693/APhysPolA.116.S-33Search in Google Scholar

[23] D. Habel, O. Goerke, M. Tovar, E. Kondratenko, H. Schubert, J. Phase Equilib. Diff. 29, 482 (2008) http://dx.doi.org/10.1007/s11669-008-9391-z10.1007/s11669-008-9391-zSearch in Google Scholar

[24] F. Beteille. R. Morineau, J. Livage, M. Nagano, Mater. Res. Bull. 32, 1109 (1997) http://dx.doi.org/10.1016/S0025-5408(97)00084-610.1016/S0025-5408(97)00084-6Search in Google Scholar

[25] E. L. Prociow, J. Domaradzki, D. Kaczmarek, T. Berlicki, Polish patent No P382163 (2007) Search in Google Scholar

[26] J. Domaradzki et al., Mat. Sci. Eng. B-Solid 109, 249 (2004) http://dx.doi.org/10.1016/j.mseb.2003.10.07310.1016/j.mseb.2003.10.073Search in Google Scholar

[27] Card 21-1272:1967, Powder Diffraction File, Joint Committee on Powder Diffraction Standards Search in Google Scholar

[28] Card 39-0774:1990, Powder Diffraction File, Joint Committee on Powder Diffraction Standards Search in Google Scholar

[29] Card 45-1074:2000, Powder Diffraction File, Joint Committee on Powder Diffraction Standards Search in Google Scholar

[30] J. L. Labar, Microsc. Microanal. 14, 287 (2008) http://dx.doi.org/10.1017/S143192760808038010.1017/S1431927608080380Search in Google Scholar

[31] J. L. Labar, Microsc. Microanal. 15, 20 (2008) http://dx.doi.org/10.1017/S143192760909002310.1017/S1431927609090023Search in Google Scholar

[32] P. Nagels, In: M. H. Brodsky (Ed.), Electronic Transport in Amorphous Semiconductors (Spinger-Verlag, New York, 1979) 113 http://dx.doi.org/10.1007/3-540-16008-6_15910.1007/3-540-16008-6_159Search in Google Scholar

[33] A. Szabo, A. Urda, M. Alifanti, Ann. Univ. Buc. Chim. 15, 85 (2006) Search in Google Scholar

[34] M. Muhibbullah, O. M. Hakim, M. G. M. Choudhury, Thin Solid Films 423, 103 (2003) http://dx.doi.org/10.1016/S0040-6090(02)00970-710.1016/S0040-6090(02)00970-7Search in Google Scholar

[35] M. G. Ambia, M. N. Islam, O. M. Hakim, J. Mater. Sci. 27, 5169 (1992) http://dx.doi.org/10.1007/BF0240381210.1007/BF02403812Search in Google Scholar

[36] S. N. Phatthalung et al., Phys. Rev. B 73, 125205 (2006) http://dx.doi.org/10.1103/PhysRevB.73.12520510.1103/PhysRevB.73.125205Search in Google Scholar

Published Online: 2013-2-9
Published in Print: 2013-2-1

© 2013 Versita Warsaw

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License.

Downloaded on 6.12.2023 from https://www.degruyter.com/document/doi/10.2478/s11534-012-0150-8/html
Scroll to top button