Accessible Requires Authentication Published by De Gruyter April 5, 2013

The Quantitative Characterization of Chemical Modification of Sodium Dodecyl Sulphate Micellar Solutions and Retention Model in Micellar Liquid Chromatography

Quantitative Charakterisierung der chemischen Modifikation mizellarer Lösungen von Natriumdodecylsulfat und Retentionsmodell in mizellarer Flüssigkeitschromatographie
L. Samokhina, L. Loginova and D. Stepanko

Abstract

The micelle solutions of sodium dodecyl sulphate (NaDS) modified by simultaneously presence of different aliphatic alcohols and an inorganic salt have been quantitatively characterized by the values of critical micelle concentrations, the degrees of counter-ion binding and electrostatic potentials of surface. The obtained characteristics of hybrid micelles and the coefficients of modifier distribution between aqueous solution and micellar pseudophase were used to develop a conceptual retention model in micellar liquid chromatography (MLC). The new retention model takes into account the microenvironment changes of an analyte when it goes from the hybrid micellar eluent to a modified surface of alkyl-bounded sorbent.

Kurzfassung

Die mizellare Lösungen von Natriumdodecylsulfat (NaDS), modifiziert durch gleichzeitige Anwesenheit verschiedener aliphatischer Alkohole und eines anorganischen Salzes, wurden durch die Werte der kritischen Mizellbildungskonzentrationen, Grade der Gegenionenbindungen sowie der elektrostatischen Oberflächenpotentiale quantitativ charakterisiert. Die erhaltenen Charakteristika hybrider Mizellen und Koeffizienten der Modifikatorverteilung zwischen wäßriger Lösung und mizellarer Pseudophase wurden verwendet, um ein konzeptionelles Retentionsmodell in mizellarer Flüssigkeitschromatographie (MLC) zu entwickeln. Das neue Retentionsmodell berücksichtigt die Änderungen der Mikroumgebung eines Analyten beim Übergang vom hybrid mizellaren Eluenten zu einer modifizierten Oberfläche eines alkylgebundenen Sorbenten.


Dr. Larysa Samokhina, Department of Chemical Metrology, Chemical Faculty, V.N. Karazin Kharkov National University, Svoboda Square 4, Kharkov, 61077 Ukraine. E-mail: ,

Dr. Larysa V. Samokhina graduated Kharkov State University (1998). Up to 2003 she was a post-graduate student in the V.N. Karazin Kharkov National University (former Kharkov State University) and took her PhD degree in a speciality of analytical chemistry. Since 2003 she has taken up her posts as a superior teacher and a research officer in the department of Chemical Metrology, V.N. Karazin Kharkov National University. In 2005 she has a post-doc position in Bayreuth University in the scientific group of Prof. Matthias Ballauff.

Prof. Lidia P. Loginova graduated Kharkov State University (1967). In 1971 she took her PhD degree in the Kharkov State University and in 2001 her Science Doctor degree in a speciality of analytical chemistry. From 2003 up to now she has academic status of professor and is a head of the Chemical Metrology department of V.N. Karazin Kharkov National University.

Daria V. Stepanko graduated V.N. Karazin Kharkov National University (2004). Up to now she is a post-graduate student in the V.N. Karazin Kharkov National University.


References

1. Mukerjee, P. and Mysels, K. J.: J. Amer. Chem. Soc.77 (1955) 2937. 10.1021/ja01616a003 Search in Google Scholar

2. Bossev, D. P., Matsumoto, M. and Nakahara, M.: J. Phys. Chem. B.103 (1999) 8251. 10.1021/jp991827m Search in Google Scholar

3. Khaledi, M. G.: J. Chromatography A.780 (1997) 3. 10.1016/S0021-9673(97)00610-9 Search in Google Scholar

4. Shtykov, S. N.: Zh. Anal. Khimii (Russia)55 (2000) 79. Search in Google Scholar

5. Berthod, A. and Garcia-Alvarez-Coque, C.: Micellar Liquid Chromatography, Marcel Dekker Inc, New York–Bazel, 2000. Search in Google Scholar

6. Loginova, L. P., Samokhina, L. V., Mchedlov-Petrossyan, N. O., Alekseeva, V. I. and Savvina, L. P.: Coll. Surf. A.193 (2001) 207. 10.1016/S0927-7757(01)00741-5 Search in Google Scholar

7. Kulikov, A. U., Loginova, L. P. and Samokhina, L. V.: Chromatographia.157 (2003) 463. 10.1007/BF02492542 Search in Google Scholar

8. Loginova, L., Samokhina, L., Boichenko, A. and Kulikov, A.: J. Chromatogr. A, to be published Search in Google Scholar

9. McGreevy, R. J. and Schechter, R. S.: J. Colloid Interface Sci.127 (1989) 209. 10.1016/0021-9797(89)90021-0 Search in Google Scholar

10. Attwood, D., Mosquera, V. and Perez-Villar, V.: J. Colloid Interface Sci.127 (1989) 532. 10.1016/0021-9797(89)90057-X Search in Google Scholar

11. Boström, G., Backlund, S., Blokhus, A. M. and Høiland, H.: J. Colloid Interface Sci.128 (1989) 169. 10.1016/0021-9797(89)90395-0 Search in Google Scholar

12. Rubio, D., Zanette, D., Nome, F. and Bunton, C. A.: Langmuir10, (1994) 1151. 10.1021/la00016a030 Search in Google Scholar

13. Rao, I. V. and Ruckenstein, E.: J. Colloid Interface Sci.113 (1986) 484. 10.1016/0021-9797(86)90173-6 Search in Google Scholar

14. Stilbs, P.: J. Colloid Interface Sci.89 (1982) 547. 10.1016/0021-9797(82)90206-5 Search in Google Scholar

15. Førland, G. M., Samseth, J., Høiland, H. and Mortensen, K.: J. Colloid Interface Sci.164 (1994) 163. 10.1006/jcis.1994.1154 Search in Google Scholar

16. Førland, G. M., Samseth, J., Gjerde, M. I., Høiland, H., Jensen, A. and Mortensen, K.: J. Colloid Interface Sci.203 (1998) 328334. 10.1006/jcis.1998.5539 Search in Google Scholar

17. Leung, R. and Shah, D. O.: J. Colloid Interface Sci.113 (1986) 484. 10.1016/0021-9797(86)90183-9 Search in Google Scholar

18. Zana, R., Yiv, S., Strazielle, C. and Lianos, P.: J. Colloid Interface Sci.80 (1981) 280. 10.1016/0021-9797(81)90177-6 Search in Google Scholar

19. Candau, S. and Zana, R.: J. Colloid Interface Sci.84 (1981) 206. 10.1016/0021-9797(81)90277-0 Search in Google Scholar

20. Yiv, S., Zana, R., Ulbricht, W. and Hoffmann, H.: J. Colloid Interface Sci.80 (1981) 224. 10.1016/0021-9797(81)90178-8 Search in Google Scholar

21. Zana, R., Picot, C. and Duplessix, R.: J. Colloid Interface Sci.93 (1983) 43. 10.1016/0021-9797(83)90382-X Search in Google Scholar

22. Guveli, D. E., Kayes, J. B. and Davis, S. S.: J. Colloid Interface Sci.72 (1979) 130. 10.1016/0021-9797(79)90189-9 Search in Google Scholar

23. Loginova, L. P., Masliy, O. G., Reshetnyak, E. A., Yevsyukova, L. V., Kotsyur, I. N., Dementyeva, T. A., Shumakher, A. S. and Mchedlov-Petrossyan, N. O.: Kharkov University Bulletin, Chem. Ser.2 (1998) 223. Search in Google Scholar

24. Rafati, A. A., Gharibi, H. and Rezaie-Sameti, M.: J. Molecular Liquids111 (2004) 109. 10.1016/j.molliq.2003.12.006 Search in Google Scholar

25. Serdyuk, A. I. and Kucher, R. B.: Micelle transitions in the surfactant solutions (in Russian), Naukova Dumka, Kyiv, 1987. Search in Google Scholar

26. Gunaseelan, K. and Ismail, K.: J. Coll. Interface Sci.258 (2003) 11010.1016/S0021-9797(02)00065-6 Search in Google Scholar

27. Lopez-Grio, S. J., Baeza-Baeza, J. J. and Garcia-Alvarez-Coque, M. C.: Chromatographia.48 (1998) 655. 10.1007/BF02467595 Search in Google Scholar

28. Singh, H. N. and Swarup, S.: Bull. Chem. Soc. Jpn.15 (1978) 1534. 10.1246/bcsj.51.1534 Search in Google Scholar

29. Almgren, M. and Swarup, S.: J. Colloid Interface Sci.91 (1983) 256. 10.1016/0021-9797(83)90330-2 Search in Google Scholar

30. Backlund, S., Bakken, J., Blokhus, A. M., Høiland, H. and Vikholm, I.: Acta Chem. Scand. A40 (1986) 241. 10.3891/acta.chem.scand.40a-0241 Search in Google Scholar

31. Lawrence, A. S. C. and Pearson, J. T.: Trans. Faraday Soc.63 (1967) 495. 10.1039/tf9676300495 Search in Google Scholar

32. Belskiy, V. E.: Izvestia Akademii Nauk, Seriya Khimicheskaya (Russian)5 (1999) 873. Search in Google Scholar

33. Mchedlov-Petrossyan, N. O., Plichko, A. V. and Shumaher, A. S.: Khimicheskaya Phizika (Russian)15 (1996) 105. Search in Google Scholar

34. Mukerjee, P. and Banerjee, K.: J. Phys. Chem.68 (1964) 3567. 10.1021/j100794a022 Search in Google Scholar

35. Fernandez, M. S. and Fromherz, P.: J. Phys. Chem.81 (1977) 1755. 10.1021/j100533a009 Search in Google Scholar

36. Hartland, G. V., Grieser, F. and White, L. R.: J. Chem. Soc., Faraday Trans. 1.83 (1987) 591. 10.1039/f19878300591 Search in Google Scholar

37. Ruhadze, M. D., Sebiskveradze, M. V., Okudzhava, V. M. and Tkesheliadze, N. B.: Zhurnal Phizicheskoy Khimii (Russian)72 (1998) 111. Search in Google Scholar

38. Monferrer-Pons, L., Capella-Peiro, E., Gil-Agustí, M. and Estevo-Romero, J.: J. Chromatogr.984 (2003) 223. 10.1016/S0021-9673(02)01845-9 Search in Google Scholar

39. Gil-Agustí, M., Garcia-Alvarez-Coque, M. C. and Estevo-Romero, J.: Anal. Chim. Acta.421 (2000) 45. 10.1016/S0003-2670(00)01033-3 Search in Google Scholar

40. Gil-Agustí, M., Garcia-Alvarez-Coque, M. C. and Estevo-Romero, J.: Talanta.54 (2001) 621. 10.1016/S0039-9140(01)00315-0 Search in Google Scholar

41. European Pharmacopoeia, 4, Council of Europe, Strasbourg (France), 2002. Search in Google Scholar

42. Garcia-Alvarez-Coque, M. C., Torres-Lapasio, J. R. and Baeza-Baeza, J. J.: Anal. Chim. Acta.324 (1996) 163. 10.1016/0003-2670(96)00028-1 Search in Google Scholar

Received: 2005-11-07
Published Online: 2013-04-05
Published in Print: 2006-03-01

© 2006, Carl Hanser Publisher, Munich