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The Quantitative Characterization of Chemical Modification of Sodium Dodecyl Sulphate Micellar Solutions and Retention Model in Micellar Liquid Chromatography

Quantitative Charakterisierung der chemischen Modifikation mizellarer Lösungen von Natriumdodecylsulfat und Retentionsmodell in mizellarer Flüssigkeitschromatographie
L. Samokhina, L. Loginova and D. Stepanko


The micelle solutions of sodium dodecyl sulphate (NaDS) modified by simultaneously presence of different aliphatic alcohols and an inorganic salt have been quantitatively characterized by the values of critical micelle concentrations, the degrees of counter-ion binding and electrostatic potentials of surface. The obtained characteristics of hybrid micelles and the coefficients of modifier distribution between aqueous solution and micellar pseudophase were used to develop a conceptual retention model in micellar liquid chromatography (MLC). The new retention model takes into account the microenvironment changes of an analyte when it goes from the hybrid micellar eluent to a modified surface of alkyl-bounded sorbent.


Die mizellare Lösungen von Natriumdodecylsulfat (NaDS), modifiziert durch gleichzeitige Anwesenheit verschiedener aliphatischer Alkohole und eines anorganischen Salzes, wurden durch die Werte der kritischen Mizellbildungskonzentrationen, Grade der Gegenionenbindungen sowie der elektrostatischen Oberflächenpotentiale quantitativ charakterisiert. Die erhaltenen Charakteristika hybrider Mizellen und Koeffizienten der Modifikatorverteilung zwischen wäßriger Lösung und mizellarer Pseudophase wurden verwendet, um ein konzeptionelles Retentionsmodell in mizellarer Flüssigkeitschromatographie (MLC) zu entwickeln. Das neue Retentionsmodell berücksichtigt die Änderungen der Mikroumgebung eines Analyten beim Übergang vom hybrid mizellaren Eluenten zu einer modifizierten Oberfläche eines alkylgebundenen Sorbenten.

Dr. Larysa Samokhina, Department of Chemical Metrology, Chemical Faculty, V.N. Karazin Kharkov National University, Svoboda Square 4, Kharkov, 61077 Ukraine. E-mail: ,

Dr. Larysa V. Samokhina graduated Kharkov State University (1998). Up to 2003 she was a post-graduate student in the V.N. Karazin Kharkov National University (former Kharkov State University) and took her PhD degree in a speciality of analytical chemistry. Since 2003 she has taken up her posts as a superior teacher and a research officer in the department of Chemical Metrology, V.N. Karazin Kharkov National University. In 2005 she has a post-doc position in Bayreuth University in the scientific group of Prof. Matthias Ballauff.

Prof. Lidia P. Loginova graduated Kharkov State University (1967). In 1971 she took her PhD degree in the Kharkov State University and in 2001 her Science Doctor degree in a speciality of analytical chemistry. From 2003 up to now she has academic status of professor and is a head of the Chemical Metrology department of V.N. Karazin Kharkov National University.

Daria V. Stepanko graduated V.N. Karazin Kharkov National University (2004). Up to now she is a post-graduate student in the V.N. Karazin Kharkov National University.


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Received: 2005-11-07
Published Online: 2013-04-05
Published in Print: 2006-03-01

© 2006, Carl Hanser Publisher, Munich