Skip to content
Licensed Unlicensed Requires Authentication Published by De Gruyter April 5, 2013

Micellization of Gemini Surfactants in Polymer Solutions

Mizellbildung von Gemini-Tensiden in Polymerlösungen
D. Tikariha , K. K. Ghosh and P. Quagliotto

Abstract

The micellization behavior of three cationic gemini surfactants, C16H33N+(CH3)2(CH2)SN+(CH3)2C16H33, 2Br (s = 4, 6, 10) have been studied in the presence of 1% (w/v) and 5% (w/v) polyethylene glycol-600 (PEG-600) by conductivity measurements at 300–320 K. From the conductivity data the critical micelle concentration, the degree of counterion ionization (α) and the thermodynamics of micellization ΔGom, ΔHom, ΔSom, of the gemini surfactants have been determined. The micellar parameters show a significant dependence on the spacer length and as well as amount of polymer.

Kurzfassung

Die Bildung von Mizellen der drei kationischen Gemini-Tenside C16H33N+(CH3)2(CH2)SN+(CH3)2C16H33, 2Br (s = 4, 6, 10) in 1% (w/v)- und 5% (w/v)-Lösungen aus Polyethylenglycol-600 (PEG-600) wurde mittels Messung der Leitfähigkeit im Bereich von 300–320 K untersucht. Aus den Leitfähigkeitsmessungen wurde die kritische Mizellkonzentration (CMC), der Ionisierungsgrad (α) und die thermodynamischen Parameter der Mizellisierung ΔGom, ΔHom, ΔSom der Gemini-Tenside ermittelt. Die Parameter zeigen eine signifikante Anhängigkeit von der Länge des Spacers und von der Polymerkonzentration.


Dr. Kallol K. Ghosh, School of Studies in Chemistry, Pt. Ravishankar Shukla University, Raipur (C.G.), 492010, India, Tel.: +91-771-2263146 (O), 2262249 (R), Fax: +91-771-2262583. E-Mail:

Dr. Kallol K. Ghosh is presently a Professor of Physical Chemistry at School of Studies in Chemistry, Pt. Ravishankar Shukla University, Raipur, India since 1998. He had been INSA/JSPS fellow at Seikei University, Tokyo, Japan and James Chair visiting fellow at St. Francis Xavier University, Antigonish, Canada. He has published 90 research papers. His research is focused on micellar catalysis, reaction mechanisms, hydroxamic acids and detoxifications.

Deepti Tikariha has completed M. Phil degree and is presently working as a Research Scholar in School of Studies in Chemistry, Pt. Ravishankar Shukla University, Raipur. India. Her research interest is to study the Physico-chemical properties of Gemini and monomeric surfactants.

Pierluigi Quagliotto is a Assosiate professor of Dipartimento di Chimica Generale ed Organica Applicata e Centro di Eccellenza NIS, Università degli Studi di Torino, Corso Massimo D'Azeglio 48, 10125, Torino, Italy.


References

1. Sesta, B., Aprano, A. D., Segre, A. L. and Proietti, N.: Langmuir13 (1997) 6612. 10.1021/la970253eSearch in Google Scholar

2. Cao, M. and Hai, M.: J. Eng. Data51 (2006) 1576. 10.1021/je060067nSearch in Google Scholar

3. Maltesh, C. and Somasundara, P.: Langmuir8 (1992) 1926. 10.1021/la00044a008Search in Google Scholar

4. Nikas, Y. J. and Blankschtein, D.: Langmuir10 (1994) 3512. 10.1021/la00022a026Search in Google Scholar

5. Norwood, D. P., Minatti, E. and Reed, W. F.: Macromolecules31 (1998) 2957. 10.1021/ma971318nSearch in Google Scholar

6. Borse, M. S. and Devi, S.: Adv. Colloid Interface Sci.123 (2006) 387. 10.1016/j.cis.2006.05.017Search in Google Scholar PubMed

7. Sultana, S. B., Bhatt, S. G. T. and Rakshit, A. K.: Bull. Chem. Soc. Jpn.73 (2000) 281. 10.1246/bcsj.73.281Search in Google Scholar

8. Kumar, S., Sharma, D. and Kabir-ud-din: Langmuir1 (2000) 6821. 10.1021/la9913607Search in Google Scholar

9. Dai, S. and Tan, K. C.: Langmuir20 (2004) 2177. 10.1021/la0357559Search in Google Scholar PubMed

10. Roscigno, P., Asaro, F., Pellizer, G., Ortona, O. and Paduano, L.: Langmuir19 (2003) 9638. 10.1021/la034928rSearch in Google Scholar

11. Muzzalupo, R., Infante, M. R., Perez, L., Pinazo, A., Marques, E. F., Antonelli, M. L., Strinati, C. and Mesa, C. la.: Langmuir23 (2007) 5963. 10.1021/la063244rSearch in Google Scholar

12. Mszros, R., Thompson, L., Bos, M., Varga, I. and Gilnyi, T.: Langmuir19 (2003) 609. 10.1021/la026616eSearch in Google Scholar

13. Li, Y., Li, P., Dong, C., Wang, X., Wang, Y., Yan, H. and Thomas, R. K.: Langmuir22 (2006) 42. 10.1021/la051544nSearch in Google Scholar

14. Sharma, P., Sachar, S., Kaur, G., Thakur, P., Bakshi, M. S. and Banipal, T. S.: J. Surface Sci. Technol.23 (2007) 131.Search in Google Scholar

15. Borse, M., Sharma, V., Aswal, V. K., Goyal, P. S. and Devi, S.: J. Colloid Interface Sci.284 (2005) 282. 10.1016/j.jcis.2004.10.008Search in Google Scholar

16. Berned, T.: J. Colloid. Polym. Sci.283 (2005) 421. 10.1007/s00396-004-1168-2Search in Google Scholar

17. Murguia, M. C., Vaillard, V. A., Sanchez, V. G., Conza, J. D. and Grau, R. J.: J. Oleo. Sci.57 (2008) 301. 10.5650/jos.57.301Search in Google Scholar

18. In, M. and Zana, R.: J. Disp. Sci. Technol.28 (2007) 143. 10.1080/01932690600991888Search in Google Scholar

19. Kabir-ud-din, Siddiqi U. S., Kumar, S. and Dar, A. A.: J. Colloid Polym. Sci.284 (2006) 807. 10.1007/s00396-005-1449-4Search in Google Scholar

20. Acharya, D. P., Guitierrez, J. M., Aramati, K., Aratani, K. and Kunieda, H.: J. Colloid Interface Sci.16 (2005) 291.Search in Google Scholar

21. Quaglioto, P., Viscardi, G., Borolo, C., Barni, E., Bellinvia, S., Fiscaro, E. and Compari, C.: J. Org. Chem.68 (2003) 7651. 10.1021/jo034602nSearch in Google Scholar

22. Menger, F. M. and Keiper, J. S.: Angew. Chem. Int. Ed.39 (2000) 1906. 10.1002/1521-3773(20000602)39:11<1906::AID-ANIE1906>3.0.CO;2-QSearch in Google Scholar

23. Zana, R., Benrraou, M. and Rueff, R.: Langmuir7 (1996) 1072. 10.1021/la00054a008Search in Google Scholar

24. Zana, R.: Langmuir12 (1996) 1208. 10.1021/la950691qSearch in Google Scholar

25. Zana, R.: J. Colloid Interface Sci.248 (2002) 203. 10.1006/jcis.2001.8104Search in Google Scholar PubMed

Received: 2009-09-22
Published Online: 2013-04-05
Published in Print: 2010-05-01

© 2010, Carl Hanser Publisher, Munich

Downloaded on 1.12.2022 from frontend.live.degruyter.dgbricks.com/document/doi/10.3139/113.110065/html
Scroll Up Arrow