Accessible Requires Authentication Published by De Gruyter January 23, 2020

Preparation and Application of Modified Imidazole with MPEG (Polyethylene Glycol Monomethyl Ether) as Carbon Steel Inhibitor

Herstellung von mit MPEG (Polyethylenglykolmonomethylether) modifiziertem Imidazol und Anwendung als Kohlenstoffstahlinhibitor
Qiuli Nan, Li Song, Yuming Zhou, Qingzhao Yao, Xiaoli Sheng, Xiaoyong Xi, Yiyi Chen, Shengqiu Lin, Guiyu Guan and Wei Sun

Abstract

The inhibition effect of three inhibitors with different chain lengths of their ether groups on Q235 steel in 0.5 M HCl solution at 318 K was determined by means of weight loss measureme nt, electrochemical methods (Tafel and EIS) and surface analysis (SEM). Moreover, the further study of corrosion inhibition mechanism was also conducted by computational methods (Quantum chemical calculations and Molecular dynamics simulations). Results reveal that the three inhibitors exhibit an excellent inhibition performance for carbon steel, and the corrosion inhibition efficiency of the three inhibitors increases with the increase of the chain length, which favors the formation of a protection film adsorbed on the surface. Analysis of polarization data informs that the adsorption type of three inhibitors basically obeys the Langmuir monolaye r adsorption, which is mainly of chemisorptive nature. Computational methods also tell that the three inhibitors possess a high reactivity and strong interaction with the iron surface, furthermore, the interaction is increased with the increase of the chain length of three inhibitors. The conclusion is in good agreement with the experimental results.

Kurzfassung

Die inhibierende Wirkung von drei Inhibitoren mit unterschiedlichen Kettenlängen ihrer Ethergruppen auf Q235-Stahl in 0,5 M HCl-Lösung bei 318 K wurde mittels Gewichtsverlustmessung, elektrochemischen Methoden (Tafel und EIS) und Oberflächenanalyse (SEM) bestimmt. Darüber hinaus wurde die weitere Untersuchung des Korrosionsinhibitionsmechanismus mit Computerverfahren (quantenchemischen Berechnungen und Molekulardynamiksimulationen) durchgeführt. Die Ergebnisse zeigen, dass drei Inhibitoren eine hervorragende Inhibierungsleistung für Kohlenstoffstahl zeigen, und die Korrosionsinhibierungseffizienz der drei Inhibitoren steigt mit der Zunahme der Kettenlänge, was die Bildung eines an der Oberfläche adsorbierten Schutzfilms begünstigt. Die Analyse der Polarisationsdaten zeigt, dass die Adsorptionsart für die drei Inhibitoren im Wesentlichen der Langmuir-Monoschichtadsorption entspricht, die hauptsächlich chemiosorptiv ist. Berechnungsmethoden zeigen auch, dass die drei Inhibitoren eine hohe Reaktivität und starke Wechselwirkun g an der Eisenoberfläche besitzen. Darüber hinaus wird die Wechselw irkung mit der Zunahme der Kettenlänge für die drei Inhibitoren erhöht. Die Schlussfolgerung stimmt gut mit den experimentellen Ergebnis sen überein.


Prof. Yuming Zhou, School of Chemistry and Chemical Engineering, Southeast University, Nanjing 211189, P.R. China, E-Mail:
Prof. Qingzhao Yao, Southeast University, Nanjing 211189, P.R. China, E-Mail:

Qiuli Nan was born in 1980. She is graduated from southeast University in 2007, and she is a teacher at Cheng Xian College, Southeast University. Her main field of research is applications of water soluble polymers in industrial water systems and green chemical.

Li Song was born in 1993. He is a postgraduate at Southeast University. His main field of research is applications of water soluble polymers in industrial water systems and green chemical.

Prof. Yuming Zhou was born in 1964. He graduated from Nanjing University in 1986. He obtained his PhD in Department of Biomedical Southeast University. His research interests lie in organic material, fine chemicals and environmental protectio n. At the moment is associate dean of the School of Chemistry and Chemical Engineering Southeast University

Qingzhao Yao was born in 1973. She is an associate professor at Southeast University. Her main field of research is applications of water soluble polymers in industrial water systems and green chemical.

Xiaoli Shen was born in 1973. She is an associate professor at Southeast University. Her main field of research is applications of water soluble polymers in industrial water systems and green chemical.

Xiaoyong Xi was born in 1992. He is a postgraduate at Southeast University. His main scientific interest has been the synthesis and properties of environment friendly materials.

Yiyi Chen was born in 1990. She is a doctoral student at Southeast University. Her main field of research is applications of water soluble polymers in industrial water systems and green chemical. Xiangnan Chen was born in 1992. She is an undergraduate at Cheng Xian College, Southeast University.

Shengqiu Lin and Guiyu Guan were born in 1998. They are undergraduate college students at Southeast University, majoring in pharmaceutical engineering.

Wei Sun was born in 1979. He received his bachelor degree in applied chemical from Nanjing University in 2004. He is now working at Jiangsu Jianghai Chemical Co., Ltd., Changzhou China. His main field of research is synthesis and application of surfactants.


References

1 Arthur D. E. , Jonathan, A., Ameh, P. O., and Anya, C.: A review on the assessment of polymeric materials used as corrosion inhibitor of metals and alloys, Journal of Industrial and Engineering Chemistry4 (2013):19. 10.1186/2228-5547-4-2 Search in Google Scholar

2 Amjad, Z. and KweikA.: The Influence of Natural and Synthetic Additives in Mitigating Calcium Phosphate Scale in Industrial Water Systems, Tenside Surfactants Detergents, 54 (2017): 460466. 10.3139/113.110525 Search in Google Scholar

3 Arora, P., Singh, R., Seshadri, G. and Tyagi, A. K.: Synthesis, Properties and Applications of Anionic Phosphate Ester Surfactants: A Review, Tenside Surfactants Detergents, 55 (2018) 266272. 10.3139/113.110570 Search in Google Scholar

4 Shah, A., Shah, A. H., Mahmood, S., Ullah, I. and Rehman, Z.: Cost Effective Procedures for Extremely Efficient Synthesis of Environmental Friendly Surfactants, Tenside Surfactants Detergents, 50 (2013) 160168. 10.3139/113.110243 Search in Google Scholar

5 Gupta, N. K., Verma, C., Quraishi, M. A. and Mukherjee, A. K.: Schiff's bases derived from l-lysine and aromatic aldehydes as green corrosion inhibitors for mild steel: Experimental and theoretical studies, Journal of Molecular Liquids, 215 (2016) 4757. 10.1016/j.molliq.2015.12.027 Search in Google Scholar

6 Xu, B., Yang, W., Liu, Y., Yin, X., Gong, W. and Chen, Y.: Experimental and theoretical evaluation of two pyridinecarboxaldehyde thiosemicarbazone compounds as corrosion inhibitors for mild steel in hydrochloric acid solution, Corrosion Science, 78 (2014) 260268; j.corsci.2013.10.007. 10.1016/ Search in Google Scholar

7 Amjad, Z.: Influence of Surfactants on the Performance of Calcium Phosphate Scale Inhibitors, Tenside Surfactants Detergent48 (2011) 5359. 10.3139/113.110104 Search in Google Scholar

8 Moschona, A., Plesu, N., Mezei, G., Thomas, A. G. and Demadis, K. D.: Corrosion protection of carbon steel by tetraphosphonates of systematically different molecular size, Corrosion Science, 145 (2018) 135150. 10.1016/j.corsci.2018.09.021 Search in Google Scholar

9 Wang, H., Zhou, Y., Liu, G., Huang, J., Yao, Q., Ma, S. H., Cao, K., Liu, Y., Wu, W. and Sun, W.: Preparation and Application of Fluorescent-tagged Inhibitor for Calcium Phosphate and Iron(III) Hydroxide Scales in Industrial Cooling Water Systems, Tenside Surfactants Detergents51 (2014) 257266. 10.3139/113.110306 Search in Google Scholar

10 Mobin, M. and Noori, S.: Adsorption and Corrosion Inhibition Behaviour of Zwitterionic Gemini Surfactant for Mild Steel in 0.5 M HCl, Tenside Surfactants Detergents53 (2016) 357367. 10.3139/113.110442 Search in Google Scholar

11 Qiang, Y., Zhang, S., Guo, L., Zheng, X., Xiang, B. and Chen, S.: Experimental and theoretical studies of four allyl imidazolium-based ionic liquids as green inhibitors for copper corrosion in sulfuric acid, Corrosion Science, 119 (2017) 6878. 10.1016/j.corsci.2017.02.021 Search in Google Scholar

12 Verma, C., Ebenso, E. E. and Quraishi, M.A.: Ionic liquids as green and sustainable corrosion inhibitors for metals and alloys: An overview, Journal of Molecular Liquids, 233 (2017) 403414. 10.1016/j.molliq.2017.02.111 Search in Google Scholar

13 He, Y., Zhou, Y., Yang, R., Ma, L. and Chen, Z.: Imidazoline derivative with four imidazole reaction centers as an efficient corrosion inhibitor for anti-CO2 corrosion, Russian Journal of Applied Chemistry, 88 (2015) 11921200. 10.1134/S1070427215070149 Search in Google Scholar

14 Babić-Samardzija, K., Lupu, C., Hackerman, N., Barron, A. R. and Luttge, A.: Inhibitive Properties and Surface Morphology of a Groupof Heterocyclic Diazoles as Inhibitors for Acidic Iron Corrosion, Langmuir, 21 (2005) 1218712196. PMid:16342991; 10.1021/la051766l Search in Google Scholar

15 El-Haddad, M. N. and Fouda, A. S.: Electroanalytical, quantum and surface characterization studies on imidazole derivatives as corrosion inhibitors for aluminum in acidic media, Journal of Molecular Liquids, 209 (2015) 480486. 10.1016/j.molliq.2015.06.005 Search in Google Scholar

16 Nouri, P. M and AttarM. M.: An Imidazole-Based Antifungal Drug as a Corrosion Inhibitor for Steel in Hydrochloric Acid, Chemical Engineering Communications, 203 (2015) 505515. 10.1080/00986445.2015.1039122 Search in Google Scholar

17 Wahdan, M. H., Gomma, G. K., Mostafa, G. K. G. b. and Wahdan, H. A.: Effect of copper cation on electrochemical behaviour of steel in presence of imidazole in acid medium, MaterialsChemistry and Physics, 47 (1997) 176183. 10.1016/s0254–0584(97)80048-x Search in Google Scholar

18 Mobin, M. and Masroor, S. H.: Experimental and Theoretical Study on Corrosion Inhibition of Mild steel in 20% Formic Acid Solution Using Schiff Base-Based Cationic Gemini Surfactant, Tenside Surfactants Detergents53 (2016) 157167. 10.3139/113.110421 Search in Google Scholar

19 Salimi, S., Nasr-Esfahani, M., Umoren and Saebnoori, S. A.: Complexes of Imidazole with Poly(ethylene glycol) as a Corrosion Inhibitor for Carbon Steel in Sulphuric Acid, Journal of Materials Engineering and Performance, 24 (2015) 46964709. 10.1007/s11665-015-1788-3 Search in Google Scholar

20 Ashassi-Sorkhabi, H. and Ghalebsaz-Jeddi, N.: Inhibition effect of polyethylene glycol on the corrosion of carbon steel in sulphuric acid, Materials Chemistry and Physics, 92 (2005) 480486. 10.1016/j.matchemphys.2005.01.059 Search in Google Scholar

21 Ashassi-Sorkhabi, H., Ghalebsaz-Jeddi, N., Hashemzadeh, F. and Jahani, H.: Corrosion inhibition of carbon steel in hydrochloric acid by some polyethylene glycols, Electrochimica Acta, 51 (2006) 38483854. 10.1016/j.electacta.2005.11.002 Search in Google Scholar

22 A. EI.-S. and Khairou, K. S.: Inhibition Effect of Some Polymers on the Corrosion of Cadmium in a Hydrochloric Acid Solution, Applied Polymer Science, 88 (2003) 866871. 10.1002/app.11663 Search in Google Scholar

23 Umoren, S. A.: Polymers as Corrosion Inhibitors for Metals in Different Media – A Review, The Open Corrosion Journal, 2 (2009) 175188. 10.2174/1876503300902010175 Search in Google Scholar

24 Hong, S., Chen, W., Luo, H. Q. and Li, N. B.: Inhibition effect of 4-amino-antipyrine on the corrosion of copper in 3 wt.% NaCl solution, Corrosion Science. 10.1016/j.corsci.2011.12.009 Search in Google Scholar

25 Katritzky, A. R., Lan, X., Yang, J. Z. and Denisko, O. V.: Properties and synthetic utility of N-Substituted benzotriazoles, Chemical Review, 98 (1998) 409548. PMid:11848906; 10.1021/cr941170v Search in Google Scholar

26 El-Lateef, Abd H. M., Abo-Riya, M. A. and Tantawy, A. H.: Empirical and quantum chemical studies on the corrosion inhibition performance of some novel synthesized cationic gemini surfactants on carbon steel pipelines in acid pickling processes, Corrosion Science, 108 (2016) 94110. 10.1016/j.corsci.2016.03.004 Search in Google Scholar

27 Hu, K., Zhuang, J., Zheng, C., Ma, Z., Yan, L., Gu, H., Zeng, X. and Ding, J.: Effect of novel cytosine-l-alanine derivative based corrosion inhibitor on steel surface in acidic solution, Journal of Molecular Liquids, 222 (2016) 109117. 10.1016/j.molliq.2016.07.008 Search in Google Scholar

28 Nuha, A., Wazzan, I. B. O. and Savaş, K.: Theoretical modeling and molecular level insights into the corrosion inhibition activity of 2-amino-1,3,4-thiadiazole and its 5-alkyl derivatives, Journal of Molecular Liquids, 221 (2016) 579602. 10.1016/j.molliq.2016.06.011 Search in Google Scholar

29 Kaya, S., Guo, L., Kaya, C., Tüzün, B., Obot, I. B., Touir, R. and Islam, N.: Quantum chemical and molecular dynamic simulation studies for the prediction of inhibition efficiencies of some piperidine derivatives on the corrosion of iron, Journal of the Taiwan Institute of Chemical Engineers, 65 (2016) 522529. 10.1016/j.jtice.2016.05.034 Search in Google Scholar

30 Guo, L., Zhang, S. T., Lv, T. M. and Feng, W. J.: Comparative theoretical study on the corrosion inhibition properties of benzoxazole and benzothiazole, Research on Chemical Intermediates, 41 (2013) 37293742. 10.1007/s11164-013-1485-5 Search in Google Scholar

31 Zeng, J., Shi, W., Sun, G., and Chen, S.: Molecular dynamics simulation of the interaction between benzotriazole and its derivatives and Cu2O crystal, Journal of Molecular Liquids, 223 (2016) 150155. 10.1016/j.molliq.2016.07.073 Search in Google Scholar

32 Amin, M. A., Abd El-Rehim, S. S., El-Sherbini, E. E. F. and Bayoumi, R. S.: The inhibition of low carbon steel corrosion in hydrochloric acid solutions by succinic acid, Electrochimica Acta, 52 (2007) 35883600. 10.1016/j.electacta.2006.10.019 Search in Google Scholar

33 Hmamou, D. B., Salghi, R., Zarrouk, A., Aouad, M. R., Benali, O., Zarrok, H., Messali, M., Hammouti, B.Kabanda, M. M., Bouachrine, M. and Ebenso, E. E.: Weight Loss, Electrochemical, Quantum Chemical Calculation, and Molecular Dynamics Simulation Studies on 2-(Benzylthio)-1,4,5- triphenyl-1H-imidazole as an Inhibitor for Carbon Steel Corrosion in Hydrochloric Acid, Industrial & Engineering Chemistry Research, 52 (2013) 1431514327. 10.1021/ie401034 Search in Google Scholar

34 Zhang, K., Xu, B., Yang, W., Yin, X., Liu, Y. and Chen, Y.: Halogen-substituted imidazoline derivatives as corrosion inhibitors for mild steel in hydrochloric acid solution, Corrosion Science, 90 (2015) 284295. 10.1016/j.corsci.2014.10.032 Search in Google Scholar

35 Hari Kumar, S. and Karthikeyan, S.: Torsemide and Furosemide as Green Inhibitors for the Corrosion of Mild Steel in Hydrochloric Acid Medium, Industrial & Engineering Chemistry Research, 52 (2013) 74577469. 10.1021/ie400815w Search in Google Scholar

36 Yadav, D. K. and Quraishi, M. A.: Electrochemical investigation of Substituted Pyranopyrazoles Adsorption on Mild Steel in Acid Solution, Industrial & Engineering Chemistry Research, 51 (2012) 81948210. 10.1021/ie3002155 Search in Google Scholar

37 Yadav, D. K., Quraishi, M. A. and Maiti, B.: Inhibition effect of some benzylidenes on mild steel in 1 M HCl: An experimental and theoretical correlation, Corrosion Science, 55 (2012) 254266. 10.1016/j.corsci.2011.10.030 Search in Google Scholar

38 Liao, L. L., Mo, S., Luo, H. Q. and Li, N. B.: Longan seed and peel as environmentally friendly corrosion inhibitor for mild steel in acid solution: Experimental and theoretical studies, Journal of Colloid and Interface Science, 499 (2017) 110119. PMid:28365436; 10.1016/j.jcis.2017.03.091 Search in Google Scholar

39 Zheng, X., Zhang, S., Gong, M. and Li, W.: Experimental and Theoretical Study on the Corrosion Inhibition of Mild Steel by 1-Octyl-3-methylimidazoliuml-Prolinate in Sulfuric Acid Solution, Industrial & Engineering Chemistry Research, 53 (2014) 1634916358. 10.1021/ie502578q Search in Google Scholar

40 Hegazy, M. A., El-Etre, A. Y., El-Shafaie, M. and Berry, K. M.: Novel cationic surfactants for corrosion inhibition of carbon steel pipelines in oil and gas wells applications, Journal of Molecular Liquids, 214 (2016) 347356. 10.1016/j.molliq.2015.11.047 Search in Google Scholar

41 Rochdi, A., Touir, R., Bakri, M. E., Ebn Touhami, M., Bakkali, S. and Mernari, B.: Protection of low carbon steel by oxadiazole derivatives and biocide against corrosion in simulated cooling water system, Journal of Environmental Chemical Engineering, 3 (2015) 233242. 10.1016/j.jece.2014.11.020 Search in Google Scholar

42 L. S. F., Hosseini, M. M., Ghorbani, M. and Arshadi, M. R.: Asymmetrical Schiff bases as inhibitors of mild steel corrosion in sulphuric acid media, Materials Chemistry and Physics, 78 (2003) 800808. 10.1016/S0254-0584(02)00390-5 Search in Google Scholar

43 Lv, T. M., Zhu, S. H., Guo, L. and Zhang, S. T.: Experimental and theoretical investigation of indole as a corrosion inhibitor for mild steel in sulfuric acid solution, Research on Chemical Intermediates, 41 (2014) 70737093. 10.1007/s11164-014-1799-y Search in Google Scholar

44 John, S. and Joseph, A.: Electroanalytical studies of the corrosion-protection properties of 4-amino-4H-1,2,4-triazole-3,5-dimethanol (ATD) on mild steel in 0.5 N sulfuric acid, Research on Chemical Intermediates, 38 (2011) 13591373. 10.1007/s11164-011-0468-7 Search in Google Scholar

45 Kowsari, E., Payami, M., Amini, R., Ramezanzadeh, B. and Javanbakht, M.: Task-specific ionic liquid as a new green inhibitor of mild steel corrosion, Applied Surface Science, 289 (2014) 478486. 10.1016/j.apsusc.2013.11.017 Search in Google Scholar

46 Mert, B. D., Yüce, A. O., Kardaş, G. and Yazıcı, B.: Inhibition effect of 2-amino-4-methylpyridine on mild steel corrosion: Experimental and theoretical investigation, Corrosion Science, 85 (2014) 287295. 10.1016/j.corsci.2014.04.032 Search in Google Scholar

47 de Souza, F. S. and Spinelli, A.: Caffeic acid as a green corrosion inhibitor for mild steel, Corrosion Science, 51 (2009) 642649. 10.1016/j.corsci.2008.12.013 Search in Google Scholar

48 Lj, M, Vračar, D. and Dražić, M.: Adsorption and corrosion inhibitive properties of some organic molecules on iron electrode in sulfuric acid, Corros. Sci., 44 (2002) 16691680. 10.1016/S0010-938X(01)00166-4 Search in Google Scholar

49 Kaya, S., Kaya, C., Guo, L., Kandemirli, F., Tüzün, B., Uğurlu, İ., Madkour, L. H. and Saraçoğlu, M.: Quantum chemical and molecular dynamics simulation studies on inhibition performances of some thiazole and thiadiazole derivatives against corrosion of iron, Journal of Molecular Liquids, 219 (2016) 497504. 10.1016/j.molliq.2016.03.042 Search in Google Scholar

50 Erdoğan, Ş., Safi, Z. S., Kaya, S., Işın, D. Ö., Guo, L. and Kaya, C.: A computational study on corrosion inhibition performances of novel quinoline derivatives against the corrosion of iron, Journal of Molecular Structure, 1134 (2017) 751761. 10.1016/j.molstruc.2017.01.037 Search in Google Scholar

51 Wazzan, N. A., Obot, I. B. and Kaya, S.: Theoretical modeling and molecular level insights into the corrosion inhibition activity of 2-amino-1,3,4-thiadiazole and its 5-alkyl derivatives, Journal of Molecular Liquids, 221 (2016) 579602. 10.1016/j.molliq.2016.06.011 Search in Google Scholar

52 Lgaz, H., Salghi, R., Jodeh, S. and Hammouti, B.: Effect of clozapine on inhibition of mild steel corrosion in 1.0 M HCl medium, Journal of Molecular Liquids, 225 (2017) 271280. 10.1016/j.molliq.2016.11.039 Search in Google Scholar

53 Singh, A., Ansari, K. R., Kumar, A., Liu, W., Song song, C. and Lin, Y.: Electrochemical, surface and quantum chemical studies of novel imidazole derivatives as corrosion inhibitors for J55 steel in sweet corrosive environment, Journal of Alloys and Compounds, 712 (2017) 121133. 10.1016/j.jallcom.2017.04.072 Search in Google Scholar

54 Dehdab, M., Shahraki, M. and Habibi-Khorassani, S. M.: Theoretical study of inhibition efficiencies of some amino acids on corrosion of carbon steel in acidic media: green corrosion inhibitors, Amino acids, 48 (2016) 291306. PMid:26347374; 10.1007/s00726-015-2090-2 Search in Google Scholar

55 Kaya, S., Banerjee, P., Saha, S. K., Tüzün, B. and Kaya, C.: Theoretical evaluation of some benzotriazole and phospono derivatives as aluminum corrosion inhibitors: DFT and molecular dynamics simulation approaches, RSC Adv., 6 (2016) 7455074559. 10.1039/C6RA14548E Search in Google Scholar

56 Martinez, S.: Inhibitory mechanism of mimosa tannin using molecular modeling and substitutional adsorption isotherms, Materials Chemistry and Physics, 77 (2002) 97102. 10.1016/s0254-0584(01)00569-7 Search in Google Scholar

57 Khaled, K. F.: Corrosion control of copper in nitric acid solutions using some amino acids – A combined experimental and theoretical study, Corrosion Science, 52 (2010) 32253234. 10.1016/j.corsci.2010.05.039 Search in Google Scholar

58 Awad, M. K., Mustafa, M. R. and Elnga, M. M. A.: Computational simulation of the molecular structure of some triazoles as inhibitors for the corrosion of metal surface, Journal of Molecular Structure: THEOCHEM, 959 (2010) 6674. 10.1016/j.theochem.2010.08.008 Search in Google Scholar

59 Yadav, M., Sarkar, T. K. and Obot, I. B.: Carbohydrate compounds as green corrosion inhibitors: electrochemical, XPS, DFT and molecular dynamics simulation studies, RSC Adv., 6 (2016) 110053110069. 10.1039/C6RA24026G Search in Google Scholar

Received: 2018-12-13
Accepted: 2019-04-17
Published Online: 2020-01-23
Published in Print: 2020-01-21

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