Abstract
Sulfuric acid dew point corrosion is still a matter of concern with respect to early failure of heating elements used for air preheating in thermal power plants. Therefore, corrosion protection by means of porcelain enamel coatings is widely used. However, insufficient protective properties of the coating can result in a drastic decrease in service life. In the present study, failure analysis was comparatively performed on damaged heating elements showing different degrees of damage after approximately 1.5 years in service in a thermal power plant. The analytical results indicated that a lower degree of damage was observed for the heating element having higher content of silica. The protective properties of coatings decreased with the increasing pore density formed in the coating layer. The heating element coated with a harder porcelain layer was less severely attacked.
Kurzfassung
Die Schwefelsäure-Taupunktskorrosion ist immer noch bedenklich einzustufen, hinsichtlich des vorzeitigen Versagens von Wärmeelementen, die für Luft-Vorerhitzer in Wärmekraftwerken verwendet werden. Daher wird häufig ein Korrosionsschutz unter Verwendung von Porzellan-Email-Beschichtungen angewendet. Doch unzureichende Schutzeigenschaften der Beschichtungen können sich in Form einer drastischen Reduktion der Lebensdauer auswirken. In der diesem Beitrag zugrunde liegenden Studie, wurde eine vergleichende Schadensanalyse an geschädigten Heizelementen durchgeführt, die verschiedene Schädigungsgrade nach einer Nutzungsdauer von 1,5 Jahren in einem Kraftwerk aufwiesen. Die analytischen Ergebnisse zeigen auf, dass sich ein geringerer Schädigungsgrad bei Elementen mit einem höheren Siliziumanteil einstellt. Die Schutzeigenschaften der Beschichtungen nehmen mit zunehmender Porendichte in der Schicht ab. Das Heizelement, das mit einer härteren Porzellanschicht versehen war, wurde weniger stark angegriffen.
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