Accessible Requires Authentication Published by De Gruyter November 30, 2013

XPS measurements of LDX 2101 duplex steel surface after magnetoelectropolishing

Krzysztof Rokosz and Tadeusz Hryniewicz

Abstract

The work presents the X-ray photoelectron spectroscopy measurement results of LDX 2101 duplex steel surface after magnetoelectropolishing in comparison with the results obtained after a standard electropolishing in still electrolyte and in the electrolyte with moderate mixing. A considerable improvement of the steel surface was found to appear after the magnetoelectropolishing treatment concerning the general composition. The calculated ratio of chromium compounds to iron compounds Cr-X/FeX equals 2 after magnetoelectropolishing and only 0.5 after a standard electropolishing. On the other hand, the ionic Cr6+ content after magnetoelectropolishing was the lowest (2.77 at.%), and after a standard electropolishing it was the highest (30.3 at.%). Such results are expected to influence the corrosion behavior of the steel and increase the corrosion resistance greatly.


* Correspondence address, Prof. Tadeusz Hryniewicz, DSc PhD, Koszalin University of Technology, Raclawicka 15 – 17, 75-620 Koszalin, Poland, Tel.: +48 94 3478244, Fax: +48 94 3426753, E-mail:

References

[1] Metals Handbook, 10th Edition, Properties and Selection. Irons, Steels and High-Performance Alloys. ASM International, Materials Park, OH 44073, Vol. 1 (1990). Search in Google Scholar

[2] X.Li, L.Guo, D.Han, J.Li, Y.Jiang: Steel Res. Intern.84 (2013) 155. 10.1002/srin.201200131 Search in Google Scholar

[3] J.O.Nilsson: Materials Sci. Technol.8 (9) (1992) 685. Search in Google Scholar

[4] J.O.Nilsson: Materials Sci. Technol.9 (7) (1993) 545. 10.1179/026708393790172222 Search in Google Scholar

[5] http://www.rolledalloys.com/products/duplex-stainless-steels/ldx-2101. Search in Google Scholar

[6] http://www.sandmeyersteel.com/LDX2101.html. Search in Google Scholar

[7] http://www.outokumpu.com/stainless/naLDXduplexsteel.pdf. Search in Google Scholar

[8] T.Hryniewicz, R.Rokicki, K.Rokosz: Met. Finish.104 (12) (2006) 26. 10.1016/S0026-0576(06)80361-2 Search in Google Scholar

[9] T.Hryniewicz, R.Rokicki, K.Rokosz: Trans. Inst. Met. Finish.85 (6) (2007) 325. 10.1179/174591907X246537 Search in Google Scholar

[10] R.Rokicki, T.Hryniewicz, K.Rokosz: Medical Device & Diagnostic Industry30 (1) (2008) 102. Search in Google Scholar

[11] R.Rokicki: US Patent7632390 (2009). Search in Google Scholar

[12] T.Hryniewicz, K.Rokosz, M.Filippi: Materials2 (1) (2009) 129. 10.3390/ma2010129 Search in Google Scholar

[13] T.Hryniewicz, K.Rokosz: Mat. Chem. Phys.122 (2010) 169,. 10.1016/j.matchemphys.2010.02.055 Search in Google Scholar

[14] T.Hryniewicz, R.Rokicki, K.Rokosz: Corrosion64 (8) (2008) 660. 10.5006/1.3279927 Search in Google Scholar

[15] K.Rokosz, T.Hryniewicz: Corrosion66 (3) (2010) 035004-1.11 (11 pages). 10.5006/1.3360910 Search in Google Scholar

[16] T.Hryniewicz, R.Rokicki, K.Rokosz: Surf. Coat. Technol.202 (9) (2008) 1668. 10.1016/j.surfcoat.2007.07.067 Search in Google Scholar

[17] T.Hryniewicz, K.Rokosz, R.Rokicki: Corr. Sci.50 (9) (2008) 2676. 10.1016/j.corsci.2008.06.048 Search in Google Scholar

[18] T.Hryniewicz, K.Rokosz: Mat. Chem. Phys.123 (2010) 47. 10.1016/j.matchemphys.2010.03.060 Search in Google Scholar

[19] T.Hryniewicz, K.Rokosz: Surf. Coat. Technol.204 (2010) 2583. 10.1016/j.surfcoat.2010.02.005 Search in Google Scholar

[20] K.Rokosz, T.Hryniewicz, W.Malorny, J.Valíček, L.Cepova: Transactions VSB, TU Ostrava56(1) (2010) 301, (ISSN 1210-0471, ISBN 978-80-248-2302-7). Search in Google Scholar

[21] K.Rokosz, T.Hryniewicz, S.Raaen: Steel Res. Intern.83 (2012). 10.1002/srin.201200046 Search in Google Scholar

[22] C.C.Shih, C.M.Shih, Y.Y.Su, L.H.J.Su, M.S.Chang, S.J.Lin: Corr. Sci.46 (2) (2004) 427. 10.1016/S0010-938X(03)00148-3 Search in Google Scholar

[23] G.Selvaduray, S.Trigwell in: Proc. Mater. and Processes for Medical Devices Conference, Boston MA, (2005), http://www.sjsu.edu/faculty/selvaduray/page/recent/316LStainlessSteel.pdf. Search in Google Scholar

[24] S.Trigwell, G.Selvaduray: NASA Technical Report, Kennedy Space Center, Rep. No. KSC-2005-182 (2005), http://naca.larc.nasa.gov/search.jsp?R=20120003602&qs=N%3D4294966819%26Nn%3D4294966526%257CAvailability%2BType%257CAcquire%2Bfrom%2BCASI. Search in Google Scholar

[25] X.Y.Wang, Y.S.Wu, L.Zhang, Z.Y.Yu: Corrosion57 (6) (2001) 540. 10.5006/1.3290380 Search in Google Scholar

[26] CasaXPS Version 2.3.16http://www.casaxps.com. Search in Google Scholar

[27] V.Crist: Handbook of monochromatic XPS spectra, The elements and native oxides, John Wiley & Sons, Ltd. (2000). Search in Google Scholar

[28] C.D.Wagner, W.M.Riggs, L.E.Davis, J.E.Moulder, G.E.Muilenberg (Eds.): Handbook of X-Ray Photoelectron Spectroscopy. Perkin-Elmer Corporation, Eden Prairie, MN (2000). Search in Google Scholar

[29] A.Grosvenor, B.A.Kobe, M.C.Biesinger, N.S.McIntyre: Surf. Interface Analysis36 (12) (2004) 1564. 10.1002/sia.1984 Search in Google Scholar

[30] M.Fantauzzi, A.Pacella, D.Atzei, A.Gianfagna, G.B.Andreozzi, A.Rossi: Analyt. Bioanalyt. Chem.396 (8) (2013) 2889. PMid: 20217397; 10.1007/s00216-010-3576-0 Search in Google Scholar

[31] S.G.Wang, G.Han, G.H.Yu, Y.Jiang, C.Wang, A.Kohn, R.C.C.Ward: J. Magn. Magn. Mater.310 (2007) 1935. 10.1016/j.jmmm.2006.10.767 Search in Google Scholar

[32] L.Pramatarova, E.Pecheva, V.Krastev, F.Riesz: J. Mater. Sci: Materials in Medicine: 18 (2007) 435. PMid: 17334694; 10.1007/s10854-007-9254-0 Search in Google Scholar

[33] J.R.Kish, M.B.Ives, J.R.Rodda: Corr. Sci.45 (7) (2003) 1571. 10.1016/S0010-938X(02)00232-9 Search in Google Scholar

[34] C.DWagner, W.M.Riggs, L.E.Davis, J.F.Moulder: Handbook of X-Ray Photoelectron Spectroscopy Perkin Elmer Corp., Physics and Electronics Division, Eden Prairie, MN (1979). Search in Google Scholar

[35] X.Zhang, G.Zhuang, J.Chen, H.Xue: Chinese Sci. Bullet.50 (8) (2005) 738. 10.1007/BF03183671 Search in Google Scholar

[36] K.N.Barquist: Synthesis and environmental adsorption applications of functionalized zeolites and iron oxide/zeolite composites, Doctoral Dissertation, The University of Iowa (2009). Search in Google Scholar

[37] S.Tang, N.Lu, S.-W.Myung, H-S.Cho: Surf. Coat. Technol.200(18–19) (2006) 5220. Search in Google Scholar

[38] V.L.Tauson, D.N.Babkin, E.E.Lustenberg, S.V.Lipko, I. Yu.Parkhomenko: Geochem. Intern.46 (6) (2008) 565. 10.1134/S0016702908060037 Search in Google Scholar

[39] K.W.Vogt, L.A.Naugher, P.A.Kohl: Thin Solid Films256 (1995) 106. 10.1016/0040-6090(94)06308-7 Search in Google Scholar

[40] M.C.Biesinger, C.Brown, J.R.Mycroft, R.D.Davidson, N.C.McIntyre: Surf. Interface Analysis36 (2004) 1550. 10.1002/sia.1983 Search in Google Scholar

[41] B.Stypuła, J.Banaś, M.Starowicz in: Proc. 33rd Sci. Confer., AGH, Kraków, (2009). PMid: 19919967; Search in Google Scholar

[42] T.L.Daulton, B.J.Little: Ultramicroscopy106 (2006) 561. http://srdata.nist.gov/xps/. 10.1016/j.ultramic.2006.02.005 Search in Google Scholar

[43] M.Descostes, F.Mercier, N.Thromat, C.Beaucaire, M.Gautier-Soyer: Appl. Surf. Sci.165 (2000) 288. 10.1016/S0169-4332(00)00443-8 Search in Google Scholar

[44] H.Konno, K.Sasaki, M.Tsunekawa, T.Takamori, R.Furuichi: Bunseki Kagaku40 (1991) 609. 10.2116/bunsekikagaku.40.11_609 Search in Google Scholar

[45] C.M.Eggleston, J.J.Ehrhardt, W.Stumm: Amer. Mineral.81 (1996) 1036. Search in Google Scholar

[46] D.Brion, Appl. Surf. Sci.5 (1980) 133. 10.1016/0378-5963(80)90148-8 Search in Google Scholar

[47] H.W.Nesbitt, I.J.Muir: Geochim. Cosmochim. Acta58 (1994) 4667. 10.1016/0016-7037(94)90199-6 Search in Google Scholar

[48] P.Mills, J.L.Sullivan: J. Phys. D: Appl. Phys. London16 (1983) 723. 10.1088/0022-3727/16/5/005 Search in Google Scholar

[49] T.Hryniewicz, K.Rokosz, J.Valíček, R.Rokicki: Mater. Lett.83 (2012) 69. 10.1016/j.matlet.2012.06.010 Search in Google Scholar

[50] T.Hryniewicz, P.Konarski, K.Rokosz, R.Rokicki: Surf. Coat. Technol.205 (2011) 4228,. 10.1016/j.surfcoat.2011.03.024 Search in Google Scholar

[51] T.Hryniewicz, P.Konarski, R.Rokicki, J.Valíček: Surf. Coat. Technol.206 (2012) 4027. 10.1016/j.surfcoat.2012.03.083 Search in Google Scholar

[52] K.Rokosz, T.Hryniewicz, J.Valíček, M.Harničárová, M.Vyležík: PAK (Measurement Automation and Monitoring)58 (5) (2012) 460. Search in Google Scholar

Received: 2013-3-19
Accepted: 2013-7-16
Published Online: 2013-11-30
Published in Print: 2013-12-12

© 2013, Carl Hanser Verlag, München