Accessible Unlicensed Requires Authentication Published by De Gruyter November 30, 2013

XPS measurements of LDX 2101 duplex steel surface after magnetoelectropolishing

Krzysztof Rokosz and Tadeusz Hryniewicz

Abstract

The work presents the X-ray photoelectron spectroscopy measurement results of LDX 2101 duplex steel surface after magnetoelectropolishing in comparison with the results obtained after a standard electropolishing in still electrolyte and in the electrolyte with moderate mixing. A considerable improvement of the steel surface was found to appear after the magnetoelectropolishing treatment concerning the general composition. The calculated ratio of chromium compounds to iron compounds Cr-X/FeX equals 2 after magnetoelectropolishing and only 0.5 after a standard electropolishing. On the other hand, the ionic Cr6+ content after magnetoelectropolishing was the lowest (2.77 at.%), and after a standard electropolishing it was the highest (30.3 at.%). Such results are expected to influence the corrosion behavior of the steel and increase the corrosion resistance greatly.


* Correspondence address, Prof. Tadeusz Hryniewicz, DSc PhD, Koszalin University of Technology, Raclawicka 15 – 17, 75-620 Koszalin, Poland, Tel.: +48 94 3478244, Fax: +48 94 3426753, E-mail:

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Received: 2013-3-19
Accepted: 2013-7-16
Published Online: 2013-11-30
Published in Print: 2013-12-12

© 2013, Carl Hanser Verlag, München