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Licensed Unlicensed Requires Authentication Published by De Gruyter November 30, 2013

XPS measurements of LDX 2101 duplex steel surface after magnetoelectropolishing

  • Krzysztof Rokosz and Tadeusz Hryniewicz

Abstract

The work presents the X-ray photoelectron spectroscopy measurement results of LDX 2101 duplex steel surface after magnetoelectropolishing in comparison with the results obtained after a standard electropolishing in still electrolyte and in the electrolyte with moderate mixing. A considerable improvement of the steel surface was found to appear after the magnetoelectropolishing treatment concerning the general composition. The calculated ratio of chromium compounds to iron compounds Cr-X/FeX equals 2 after magnetoelectropolishing and only 0.5 after a standard electropolishing. On the other hand, the ionic Cr6+ content after magnetoelectropolishing was the lowest (2.77 at.%), and after a standard electropolishing it was the highest (30.3 at.%). Such results are expected to influence the corrosion behavior of the steel and increase the corrosion resistance greatly.


* Correspondence address, Prof. Tadeusz Hryniewicz, DSc PhD, Koszalin University of Technology, Raclawicka 15 – 17, 75-620 Koszalin, Poland, Tel.: +48 94 3478244, Fax: +48 94 3426753, E-mail:

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Received: 2013-3-19
Accepted: 2013-7-16
Published Online: 2013-11-30
Published in Print: 2013-12-12

© 2013, Carl Hanser Verlag, München

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