Abstract
Powder injection moulding (PIM) is an important and accepted industrial technique for net shaping of precision components which can have a rather complex geometry. In order to meet the imposed, often rather strict, requirements with regard to dimensional accuracy, it is important to have an adequate knowledge and control of the rheological behaviour and the related processing properties of the powder/polymer melt (feedstock). Such a knowledge is furthermore of crucial importance in numerical simulations of the PIM-process. In the present work, a model system, consisting of steel powder, poly(ethylene glycol) and wax, is used in order to illustrate how the viscometric properties as well as thermal properties, such as the conductivity and the specific heat, of the system can be related to the corresponding properties of the polymeric binder system. In a similar way, the pvT (pressure-volume-temperature)-behaviour of the model system is analysed and discussed. The pvT-behaviour, which has not been extensively reported on for PIM-feedstocks, is considered to be of significant relevance for controlling the outcome of the injection moulding process.
References
Araujo, F. F. T., Rosenberg, H. M., “The Thermal Conductivity of Epoxy-resin/Metal-powder Composite Materials from 1.7 to 300 K”, J. Phys. D: Appl. Phys., 9, 665–675(1976)10.1088/0022-3727/9/4/017Search in Google Scholar
Barnes, H. A., Hutton, J. F., Walters, K.: An Introduction to Rheology, Elsevier, Amserdam(1989)Search in Google Scholar
Boyer, H. E., Gall, T. L.: Metal Handbook, Desk Edition, Amer. Soc. Metals, Ohio(1985)Search in Google Scholar
Dhami, A. K., et al., “Thermal Conductivity Of 2223 BSCCO Superconductor-Polyethylene Glycol Composites between 20 and 300 K”, J. Supercond., 13, 417–422(2000)10.1023/A:1007755125840Search in Google Scholar
Fu, G., et al., “The demolding of Powder Injection Molded Micro-Structures: Analysis, Simulation And Experiments”, J. Micromech. Microeng., 18, 075024(2008). 10.1088/0960-1317/18/7/075024Search in Google Scholar
German, R. M., Bose, A.: Injection Moulding of Metals and Ceramics, Metal Powder Industries Federation, Princeton N. J.(1997)Search in Google Scholar
German, R. M.: Powder Injection Molding, Metal Powder Industries Federation, Princeton N. J.(1990)Search in Google Scholar
JMatPro version 4.0.5, Sente Software, Guildford, UK(2005)Search in Google Scholar
Johansson, E.: “Surface Interactions in Powder Injection Moulding”, PhD Thesis, Chalmers University of Technology, Göteborg, Sweden (2002)Search in Google Scholar
Johansson, E., Nyborg, L., “XPS Study of Surface-active Organic Compounds on Fine Ferrous Powder”, Surf. Interface Anal., 30, 333–336(2000)10.1002/1096-9918(200008)30:1<333::AID-SIA843>3.0.CO;2-HSearch in Google Scholar
Johansson, E., et al., “Assessment of Rheology and Related Properties of OIM Feedstock Material”, Europ. Symp. Powder Injection Moulding, 67–74 (2000)Search in Google Scholar
Kowalski, L., Duszczyk, J., “Specific Heat of Metal powder-polymer Feedstock for Powder Injection Molding”, J. Mater. Sci. Letters, 18, 1417–1420(1999)10.1023/A:1006623507854Search in Google Scholar
Kowalski, L., et al., “Thermal Conductivity of Metal Powder-polymer Feedstock for Powder Injection Moulding”, J. Mater. Sci., 34, 1–5(1999)10.1023/A:1004424401427Search in Google Scholar
Meredith, R. E., Tobias, C. W., “Resistance to Potential Flow through Cubical Array of Spheres”, J. Appl. Phys., 31, 1270–1273(1960)10.1063/1.1735816Search in Google Scholar
Nyborg, L., et al., “Reaction Products on Metal Powder Surfaces and Interfaces”, Colloq. Controlling the Properties of PM Parts through their Microstructure, Paris (1990)Search in Google Scholar
Nyborg, L., et al., “Guide to Injection Moulding of Ceramics and Hardmetals: Special Consideration of Fine Powder”, Powder Metal, 41, 41–45(1998)Search in Google Scholar
Parker, W. J., et al., “Flash Method of Determining Thermal Diffusivity, Heat Capacity and Thermal Conductivity”, J. Appl. Phys., 32, 1679–1684(1961)10.1063/1.1728417Search in Google Scholar
Van Krevelen, D. W.: Properties of Polymers, 3rd Edition, Elsevier, Amsterdam(1990)Search in Google Scholar
Zoller, P., Walsh, D. J.: Standard Pressure-Volume-Temperature Data for Polymers, Technomic Publishing, Lancaster(1995)Search in Google Scholar
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