Abstract
Nowadays there is a widespread phenomenon of dairy residue, which causes a great deal of waste. To solve this problem, the copolymer of fluorinated acrylate resin was synthesized and the resisting fluid film was prepared. The proprieties of the fluorinated acrylate resin coatings were characterized by scanning electron microscope (SEM), measuring the contact angle of the droplet liquid on the surface of the coating, the influence of acidic environment, the adhesion to substrate material, and analyzing thermogravimetry (TG) and Gas Chromatography (GC). It was found that the fluorinated acrylate resin film is a kind of resisting fluid film with excellent property and it is safe, nontoxic and readily biodegradable. So it was said a very potential dairy packaging material.
References
Bae, G. Y., Min, B. G., Jeong, Y. G., Lee, S. C., Jang, J. H. and Koo, G. H., “Superhydrophobicity of Cotton Fabrics Treated with Silica Nanoparticles and Water-Repellent Agent”, J. Colloid Interface Sci., 337, 170–175 (2009) 10.1016/j.jcis.2009.04.066Search in Google Scholar PubMed
Chang, C. J., Kuo, E. H., “Roughness-Enhanced Thermal-Responsive Surfaces by Surface-Initiated Polymerization of Polymer on Ordered ZnO Pore-Array Films”, Thin Solid Films, 519, 1755–1760 (2010) 10.1016/j.tsf.2010.08.156Search in Google Scholar
Chen, L., Shi, H., Wu, H. and Xiang, J., “Preparation and Characterization of a Novel Fluorinated Acrylate Resin”, J. Fluorine Chem., 131, 731–737 (2010) 10.1016/j.jfluchem.2010.03.009Search in Google Scholar
Feng, L., “Super-Hydrophobic Surfaces: From Natural to Artificial”, Adv. Mater., 14, 1857–1860 (2002) 10.1002/adma.200290020Search in Google Scholar
Hansson, K., Andersson, T. and Skepö, M., “Adhesion of Fermented Diary Products to Packaging Materials. Effect of Material Functionality, Storage Time, and Fat Content of the Product. An Empirical Study”, J. Food Eng., 111, 318–325 (2012) 10.1016/j.jfoodeng.2012.02.017Search in Google Scholar
Huang, Y., Hu, M., Yi, S., Liu, X., Li, H., Huang, C., Luo, Y. and Li, Y., “Preparation and Characterization of Silica/Fluorinated Acrylate Copolymers Hybrid Films and the Investigation of their Icephobicity”, Thin Solid Films, 520, 5644–5651 (2012) 10.1016/j.tsf.2012.04.067Search in Google Scholar
Keles, O., Dundar, M., “Aluminum Foil: Its Typical Quality Problems and their Causes”, J. Mater. Process. Technol., 186, 125–137 (2007) 10.1016/j.jmatprotec.2006.12.027Search in Google Scholar
Kumar, P., Mishra, H., “Storage Stability of Mango Soy Fortified Yoghurt Powder in Two Different Packaging Materials: HDPP and ALP”, J. Food Eng., 65, 569–576 (2004) 10.1016/j.jfoodeng.2004.02.022Search in Google Scholar
Li, J., Yang, Y., Zha, F. and Lei, Z., “Facile Fabrication of Superhydrophobic ZnO Surfaces From High to Low Water Adhesion”, Mater. Lett., 75, 71–73 (2012) 10.1016/j.matlet.2012.01.139Search in Google Scholar
Li, Q., Li, R., Jiang, S., Li, W. and ChengW., “The Structure, Properties, and Nature of C-Br Halogen Bond Involving Harf: Substitution, Hybridization, and Nonadditivity”, J. Fluor. Chem., 135, 207–212 (2012) 10.1016/j.jfluchem.2011.11.004Search in Google Scholar
Li, Y., Liu, F. and Sun, J., “A Facile Layer-by-Layer Deposition Process for the Fabrication of Highly Transparent Superhydrophobic Coatings”, Chem. Commun., 19, 2730–2732 (2009) 10.1039/b900804gSearch in Google Scholar PubMed
Ma, M., Hill, R. M., “Superhydrophobic Surfaces”, Curr. Opin. Colloid In., 11, 193–202 (2006) 10.1016/j.cocis.2006.06.002Search in Google Scholar
Miwa, M., Nakajima, A., Fujishima, A., Hashimoto, K. and Watanabe, T., “Effects of the Surface Roughness on Sliding Angles of Water Droplets on Superhydrophobic Surfaces”, Langmuir, 16, 5754–5760 (2000) 10.1021/la991660oSearch in Google Scholar
Nystrom, D., Lindqvist, J., Ostmark, E., Hult, A. and Malmstrom, E., “Superhydrophobic Bio-Fibre Surfaces via Tailored Grafting Architecture”, Chem. Commun., 34, 3594–3596 (2006)Search in Google Scholar
Patankar, N., “Mimicking the Lotus Effect: Influence of Double Roughness Structures and Slender Pillars”, Langmuir, 20, 8209–8213 (2004) 10.1021/la048629tSearch in Google Scholar PubMed
Phani, A. R., Haefke, H., “Effect of Annealing Temperature on Antireflection Property and Watercontact Angle of Fluorine-Based Hydrophobic Films by a Sol-Gel Technique”, Mater. Lett., 58, 3555–3558 (2004) 10.1016/j.matlet.2004.06.066Search in Google Scholar
Seay, C. W., Baird, D. G., “Sparse Long-Chain Branching's Effect on the Film-Casting Behavior of PE”, Int. Polym. Proc., 24, 41–49 (2009) 10.3139/217.2184Search in Google Scholar
Singh, A., Steely, L. and Allcock, H. R., “Poly[bis(2,2,2-trifluoroethoxy)phosphazene] Superhydrophobic Nanofibers”, Langmuir, 21, 11604–11607 (2005) 10.1021/la052110vSearch in Google Scholar PubMed
Steele, A., Bayer, I., Moran, S., Cannon, A., King, W. P. and Loth, E., “Conformal ZnO Nanocomposite Coatings on Micro-Patterned Surfaces for Superhydrophobicity”, Thin Solid Films, 518, 5426–5431 (2010) 10.1016/j.tsf.2010.03.084Search in Google Scholar
Su, C., “Facile Fabrication of a Lotus-Effect Composite Coating via Wrapping Silica with Polyurethane”, Appl. Surf. Sci., 256, 2122–2127 (2010) 10.1016/j.apsusc.2009.09.058Search in Google Scholar
Su, C. C., Chang, S. H., “Effective Growth of Vertically Aligned Carbon Nanotube Turfs on Flexible AL Foil.” Mater. Lett., 65, 2700–2702 (2011) 10.1016/j.matlet.2011.05.012Search in Google Scholar
Sun, C., Gu, Z. and Xu, H., “Packing the Silica Colloidal Crystal Beads: A Facile Route to Superhydrophobic Surfaces”, Langmuir, 25, 12439–12443 (2009) 10.1021/la902785kSearch in Google Scholar
Trigueros, L., Pérez-Alvarez, J. A., Viuda-Martos, M. and Sendra, E., “Production of Low-Fat Yogurt with Quince (Cydonia Oblonga Mill.) Scalding Water”, LWT-Food Sci. Technol., 44, 1388–1395 (2011) 10.1016/j.lwt.2011.01.012Search in Google Scholar
Uhlmann, P., Schneider, S., “Acid-Base and Surface Energy Characterization of Grafted Polyethylene Using Inverse Gas Chromatography”, J. Chromatogr. A., 969, 73–80 (2002) 10.1016/S0021-9673(02)00900-7Search in Google Scholar
Wang, H., Fang, J., Cheng, T., Ding, J., Qu, L., Dai, L., Wang, X. and Lin, T., “One-Step Coating of Fluoro-Containing Silica Nanoparticles for Universal Generation of Surface Superhydrophobicity”, Chem. Commun., 7, 877–879 (2008) 10.1039/B714352DSearch in Google Scholar PubMed
Wenzel, R. N., “Surface Roughness and Contact Angle” J. Phys. Chem., 53, 1466–1467 (1949) 10.1021/j150474a015Search in Google Scholar
Xiong, J., Das, S. N., Shin, B., Kar, J. P., Choi, J. H. and Myoung, J. M., “Biomimetic Hierarchical ZnO Structure with Superhydrophobic and Antireflective Properties”, J. Colloid Interface Sci., 350, 344–347 (2010) 10.1016/j.jcis.2010.06.053Search in Google Scholar PubMed
Xiu, Y., Hess, D. W. and Wong, C. P., “UV and Thermally Stable Superhydrophobic Coatings from Sol-Gel Processing”, J. Colloid Interface Sci., 326, 465–470 (2008) 10.1016/j.jcis.2008.06.042Search in Google Scholar PubMed
Xu, Q. F., Wang, J. N. and Sanderson, K. D., “A General Approach for Superhydrophobic Coating with Strong Adhesion Strength”, J. Mater. Chem., 20, 5961–5966 (2010) 10.1039/c0jm00001aSearch in Google Scholar
Yang, X., Zhu, L., Zhang, Y., Chen, Y., Bao, B., Xu, J. and Zhou, W., “Surface Properties and Self-Cleaning Ability of the Fluorinated Acrylate Coatings Modified with Dodecafluoroheptyl Methacrylate through Two Adding Ways”, Appl. Surf. Sci., 295, 44–49 (2014) 10.1016/j.apsusc.2013.12.177Search in Google Scholar
Zhang, H., Lamb, R. and Lewis, J., “Engineering Nanoscale Roughness on Hydrophobic Surface-Preliminary Assessment of Fouling Behaviour”, Sci. Technol. Adv. Mat., 6, 236–239 (2005) 10.1016/j.stam.2005.03.003Search in Google Scholar
Zhang, J., Li, J. and Han, Y., “Superhydrophobic PTFE Surfaces by Extension”, Macromol. Rapid Comm., 25, 1105–1108 (2004) 10.1002/marc.200400065Search in Google Scholar
© 2014, Carl Hanser Verlag, Munich
