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Licensed Unlicensed Requires Authentication Published by De Gruyter November 3, 2015

Synthesis and Evaluation of Amides as Slip Additives in Polypropylene

F. Coelho, L. F. Vieira, R. Benavides, M. Marques da Silva Paula, A. M. Bernardin, R. F. Magnago and L. da Silva

Abstract

In this study, we describe the synthesis of amides and evaluate their use as slip additive agents in polypropylene films. The additives N-isopropyl-stearamide and N,N-diisopropyl-stearamide were synthesized and characterized and then used to prepare masterbatches. Erucamide, a commercial masterbatch, was used as the reference standard. A 32 factorial experimental design was used to create the different compositions of slip additives in polymer films. The films were processed via flat-die extrusion and stored in an oven at a constant temperature of 40 °C for seven days. The following are the properties evaluated in the study: thermal decomposition temperature, fusion temperature, fusion enthalpy, coefficient of friction, surface energy, contact angle, and seal initiation temperature. The results were evaluated by analysis of variance (ANOVA) at a 90 % confidence interval. The analysis of the results showed that N-isopropyl stearamide and N,N-diisopropyl stearamide do not provide an adequate surface slip for polypropylene films at the conditions used in the study. In turn, at the same conditions, erucamide, the commercial amide, also does not provide the required surface energy for printing and lamination processes required for polypropylene films.


* Mail address: Luciano da Silva, Laboratório de Pesquisa em Materiais LAPEM – Universidade do Extremo Sul Catarinense, 88806 – 000, Criciúma, Brazil, E-mail:

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Received: 2015-03-09
Accepted: 2015-08-25
Published Online: 2015-11-03
Published in Print: 2015-11-30

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