Skip to content
Publicly Available Published by De Gruyter July 29, 2013

Terminology of metal–organic frameworks and coordination polymers (IUPAC Recommendations 2013)

  • Stuart R. Batten , Neil R. Champness , Xiao-Ming Chen , Javier Garcia-Martinez , Susumu Kitagawa , Lars Öhrström , Michael O’Keeffe , Myunghyun Paik Suh and Jan Reedijk

A set of terms, definitions, and recommendations is provided for use in the classification of coordination polymers, networks, and metal–organic frameworks (MOFs). A hierarchical terminology is recommended in which the most general term is coordination polymer. Coordination networks are a subset of coordination polymers and MOFs a further subset of coordination networks. One of the criteria an MOF needs to fulfill is that it contains potential voids, but no physical measurements of porosity or other properties are demanded per se. The use of topology and topology descriptors to enhance the description of crystal structures of MOFs and 3D-coordination polymers is furthermore strongly recommended.


Project Year: 2009, Project Code: 2009-012-2-200


References

1 S. R. Batten, S. M. Neville, D. R. Turner. Coordination Polymers: Design, Analysis and Application, RSC, Cambridge (2009).Search in Google Scholar

2 10.1016/j.micromeso.2004.03.034, J. L. C. Rowsell, O. M. Yaghi. Microporous Mesoporous Mater.73, 3 (2004).Search in Google Scholar

3 10.1039/b903811f, J. R. Long, O. M. Yaghi. Chem. Soc. Rev.38, 1213 (2009).Search in Google Scholar PubMed

4 M. Jacoby. In Chem. Eng. News86, 13 (2008).10.1021/cen-v086n038.p013aSearch in Google Scholar

5 10.1039/b804680h, A. U. Czaja, N. Trukhan, U. Muller. Chem. Soc. Rev.38, 1284 (2009).Search in Google Scholar PubMed

6 IUPAC. Nomenclature of Inorganic Chemistry, IUPAC Recommendations 2005 (the “Red Book”). Prepared for publication by N. Connelly, T. Damhus, R. M. Harshorn, RSC Publishing, Cambridge, UK (2005).Search in Google Scholar

7 10.1351/pac199668122287, A. D. Jenkins, P. Kratochvil, R. F. T. Stepto, U. W. Suter. Pure Appl. Chem.68, 2287 (1996).Search in Google Scholar

8 10.1039/c2ce06488j, S. R. Batten, N. R. Champness, X. M. Chen, J. Garcia-Martinez, S. Kitagawa, L. Öhrström, M. O’Keeffe, M. P. Suh, J. Reedijk. CrystEngComm14, 3001 (2012).Search in Google Scholar

9 F. Kubel, J. Strahle. Z. Naturforsch., B: Chem. Sci.37, 272 (1982).Search in Google Scholar

10 10.1021/cm950594i, D. Venkataraman, S. Lee, J. S. Moore, P. Zhang, K. A. Hirsch, G. B. Gardner, A. C. Covey, C. L. Prentice. Chem. Mater.8, 2030 (1996).Search in Google Scholar

11 10.1021/cg800896k, J.-X. Chen, X.-Y. Tang, Y. Chen, W.-H. Zhang, L.-L. Li, R.-X. Yuan, Y. Zhang, J.-P. Lang. Cryst. Growth Des.9, 1461 (2009).Search in Google Scholar

12 10.1107/S1600536801005931, K. Larsson. Acta Crystallogr., Sect. E: Struct. Rep. Online57, m195 (2001).Search in Google Scholar

13 B. F. Abrahams, M. J. Hardie, B. F. Hoskins, R. Robson, E. E. Sutherland. Chem. Commun. 1049 (1994).10.1039/c39940001049Search in Google Scholar

14 10.1021/ic00035a036, S. Kitagawa, M. Munakata, T. Tanimura. Inorg. Chem.31, 1714 (1992).Search in Google Scholar

15 H. Li, M. Eddaoudi, M. O’Keeffe, O. M. Yaghi. Nature402, 276 (1999).10.1038/46248Search in Google Scholar

16 10.1126/science.283.5405.1148, S. S. Y. Chui, S. M. F. Lo, J. P. H. Charmant, A. G. Orpen, I. D. Williams. Science283, 1148 (1999).Search in Google Scholar PubMed

17 10.1021/ar800124u, M. O’Keeffe, M. A. Peskov, S. Ramsden, O. M. Yaghi. Acc. Chem. Res.41, 1782 (2008).Search in Google Scholar PubMed

18 10.1039/b910671e, V. A. Blatov, M. O’Keeffe, D. M. Proserpio. CrystEngComm12, 44 (2010).Search in Google Scholar

19 10.1351/pac200779101801, J. Aleman, A. V. Chadwick, J. He, M. Hess, K. Horie, R. G. Jones, P. Kratochvil, I. Meisel, I. Mita, G. Moad, S. Penczek, R. F. T. Stepto. Pure Appl. Chem.79, 1801 (2007).Search in Google Scholar

20 L. G. Donaruma, B. P. Block, K. L. Loening, N. Plate, T. Tsuruta, K. C. Buschbeck, W. H. Powell, J. Reedijk. Pure Appl. Chem.57, 149 (1985).Search in Google Scholar

21 L. Öhrström. Chem. Int., p. 32, No. 1, January–February (2010).Search in Google Scholar

Online erschienen: 2013-7-29
Erschienen im Druck: 2013-7-31

© 2013 Walter de Gruyter GmbH, Berlin/Boston

Downloaded on 19.3.2024 from https://www.degruyter.com/document/doi/10.1351/PAC-REC-12-11-20/html
Scroll to top button