Abstract
Some new mixed valence compounds of the type [M(L-L)2M(L-L)2X2]Y4 (where M = Pt or Pd, L-L = 2NH3 or ethylenediamine, X = Cl, Br or I and Y = HSO4, 1/2 SO4, ClO4 or 1/2 PtCl4) have been synthesized. The polarized Raman spectra of single crystals show the anisotropic character and the presence of ---M(II)---X-M(IV)-X chains. The method of preparation and the chemical behaviour correspond to the mechanism of the formation of Magnus green salt oxidized product.
Keywords: Metal-Halide Chain; Raman Spectra
Received: 1980-7-28
Published Online: 2014-6-2
Published in Print: 1981-1-1
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