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International Polymer Processing

International Polymer Processing

Volume 25 Issue 5

  • Contents
  • Journal Overview

Contents

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Contents

April 6, 2013 Page range: 321-321
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Review Article

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Perspectives on the Transition from Batch to Continuous Mixing Technologies in the Compounding Industry

J. L. White, S. H. Bumm April 6, 2013 Page range: 322-326
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Abstract

During the last quarter of the 20 th century, there was a transition from batch to continuous mixing in the polymer and food industries. We present and summarize experimental studies of flows in both internal and continuous mixers. Simulation of flow in these machines is also described. It is argued that the primary reason for this transition was that continuous mixers produce more uniform and better quality mixes, and that this is inherent in their different fluid mechanics. Batch mixers are always starved and largely unpressurized. Their complex fluid mechanics produce non-uniform mixing in the various portions of the compound material. Continuous mixers set up a steady state hydrodynamic flow field generally consisting of alternating regions of pressurized fully filled flow and starved flow. All of the compounds must pass through these regions to reach the die exit and thus possess uniform mixing histories. This uniform deformation history which includes pressurized mixing regions produces superior uniform products.

Regular Contributed Articles

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Reactive Blending of Thermoplastic Polyurethane and Polypropylene

R. Jaruttrakool, S. Tanpichai, D. Pentrakoon, P. Potiyaraj April 6, 2013 Page range: 327-333
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Abstract

In this research, reactive blending of thermoplastic polyurethane (TPU) and polypropylene (PP) was studied. Grafting of maleic anhydride (MAH) onto TPU/PP blends was performed by a twin-screw extruder in the presence of dicumyl peroxide (DCP). Mechanical properties and morphology of the blends were investigated by tensile testing and scanning electron microscopy (SEM), respectively. Thermal properties of the blends were characterized by differential scanning calorimetry (DSC) and thermogravimetric analysis (TGA). The obtained results were compared with those of the uncompatibilized blends and the blends compatibilized with a commercial maleic anhydride grafted polypropylene (PP-g-MA). The results from the uncompatibilized blends clearly indicate that the TPU and PP are immiscible resulting in undesirable properties of the blends. These properties were improved significantly when TPU and PP were reactive-blended in the presence of MAH and DCP. When comparing with the blends compatibilized with PP-g-MA, the blends prepared by the reactive blending technique possessed better mechanical properties.
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Effect of Malonic Acid/Calcium Stearate Bicomponent Nucleator on the β-Crystalline Formation in Isotactic Poly(propylene)

Q. Dou April 6, 2013 Page range: 334-340
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Abstract

The effect of a new bicomponent β-nucleator composed of malonic acid (MA) and calcium stearate (CaSt) on the formation of the β-crystalline form in isotactic polypropylene (iPP) has been investigated. It has been found that the relative content of the β-crystalline form (k value) of iPP notably increases with the addition of the MA/CaSt mixture, and it attains a maximum value of 0.94 at 0.15% MA/0.30% CaSt. For iPP nucleated with the bicomponent nucleator, the spherulitic size decreases continuously with increasing CaSt dosage. FTIR analysis has shown that an “in situ” reaction may occur between MA and CaSt during melt blending, yielding an effective β-nucleator (calcium malonate, CaMt). The β-nucleation efficiency of an MA/CaSt mixture is higher than that of CaMt itself; this may be ascribed to greater dispersion of the “in situ” produced CaMt in the iPP matrix through the assistance of the CaSt residue and the stearic acid.
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Fabrication of a Nanosize Pattern Embedded Plastic Chip via an Injection Molding Method for Application to an Optical Biosensor

K. H. Kim, W. Kim, J. C. Hong, H. S. Ko, B. K. Kim, C. Huh, G. Y. Sung April 6, 2013 Page range: 341-345
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Abstract

We demonstrate a commercialized injection molding method for nano patterning of polymethyl methacrylate (PMMA) for the purpose of mass production of a label-free optical biosensor chip. Scanning electron microscope (SEM) images clearly show uniform nanopattern transfer on the plastic chip fabricated by an injection molding method. A uniformly deposited silicon nitride layer having a high refractive index by a plasma enhanced chemical vapor deposition (PECVD) technique is also observed. A unique characterization method is described wherein optical resonance reflection is used accurately and quickly to characterize the geometrical sensor structure. The authors anticipate that this robust method will provide an excellent means of producing an optical resonance reflection biosensor (ORRB).
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Structure Development in the Melt Spinning of Polypropylene/Ethylene Butene Copolymer Blends and Birefringence Suppression Effect

J. Yang, Q. Jiang, J. L. White April 6, 2013 Page range: 346-355
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Abstract

Polypropylene (PP)/ethylene butene copolymer (EBM) blends were melt-spun into fibers. The fiber orientation was determined by wide angle diffraction (WAXS) and birefringence. The birefringence of the blend fibers was much lower than that of the pure PP or EBM filaments spun at the same stresses. WAXS study showed that the PP phase had the same orientation versus stress relationship in its blends and in its pure state. However, EBM phase demonstrated much lower birefringence in its blends than in its pure state. The mechanism was explained as following. In melt spinning of the blends, the PP phase crystallized first. Before the PP phase crystallized, both PP and EBM phase had comparable modulus leading uniform stress distribution. After the PP phase crystallized, the modulus of PP phase became much larger than that of the EBM melt. Thus it would take most of the stress if it was the continuous phase leaving the EBM phase crystallizing at much lower stresses. This led to a large birefringence suppression of the EBM phase. In melt spinning of the blends with only 1 to 10 wt.% of PP, the dispersed PP phase could coalesce into a continuous surface layer. Thus small amount of PP could largely decrease the birefringence of EBM fibers.
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Investigation of Polymer Stretching Instabilities: Application to Film Blowing

J. Laffargue, Y. Demay, J.-F. Agassant April 6, 2013 Page range: 356-371
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Abstract

Film blowing, as other elongational polymer forming processes, may present marked drawing instabilities leading to unacceptable products. But in film blowing, these instabilities are much more complex than for example in fibre spinning: there is no stabilizing effect of the polymer cooling, and the symmetry of the process may be broken, leading in some processing conditions to so called helical instabilities. Stability of the process has been investigated using a strategy inspired from shell or homogeneisation theory: as the classical approach uses a frame locally affixed to the membrane, the equations of the problem are now written in the cartesian laboratory frame. Making the equations dimensionless introduces naturally a small parameter defined as an aspect ratio (ratio of the film thickness to the bubble radius). Kinematic and stress variables are expanded as a function of this small parameter and introduced in the equations. It leads classically to a sequence of equations at successive orders. This strategy is used to obtain a time dependent membrane model. The stationary solution is equivalent to the one obtained using the classical approach. This model allows to develop a stability analysis, first in the axisymmetric case and then in the non axisymmetric one. Even a crude Newtonian temperature dependent rheology allows to capture qualitatively the observed instability phenomena.
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Air-coupled Ultrasound for Monitoring the Production of PUR Sandwich Structures

F. Siegmund, D. Döring, M. Rheinfurth, E. Haberstroh, G. Busse April 6, 2013 Page range: 372-378
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Abstract

Polyurethane sandwich structures are very useful in construction because of their excellent thermal insulating properties. Even though the chemicophysical processes occurring inside the production line crucially affect the quality of the final product, up to now, they are not monitored at all. Thus, the aim of this paper is to present a new fundamental approach for non-invasively monitoring these processes online by using air-coupled, low-frequency ultrasonic plate waves (“Lamb waves”). Hereby, a foaming cell incorporating the ultrasonic unit was constructed on a laboratory scale. Then, sandwich structures were fabricated with polyurethane consisting of various ratios of the educts di-isocyanate and polyol. Air, instead of liquid was used as the coupling medium to transport the ultrasonic waves that were subsequently monitored. For comparison, tensile strength and microscopic images were analyzed. Most importantly, various wave amplitudes and phases were recorded depending on the actual chemical properties of the polyurethane and its physical state. Consequently, this technique permits the direct and non-invasive tracking of the foaming process thereby avoiding expensive panel replacements.

PPS-News

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PPS News

April 6, 2013 Page range: 379-379
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Seikei Kakou Abstracts

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Seikei-Kakou Abstracts

April 6, 2013 Page range: 380-380
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About this journal

International Polymer Processing offers original research contributions, invited review papers and recent technological developments in processing thermoplastics, thermosets, elastomers and fibers as well as polymer reaction engineering. For more than 25 years International Polymer Processing, the journal of the Polymer Processing Society, provides strictly peer-reviewed, high-quality articles and rapid communications from the leading experts around the world.
All articles are subject to thorough, independent peer review.
Editor: Polymer Processing Society
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