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Volume 74 Issue 4 - Special Issue: The 9th European Conference on Wood Modification (Arnhem, the Netherlands, September 17–18, 2018) / Issue Editor: Holger Militz

Issue of Holzforschung

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Contents
Journal Overview

Publicly Available March 14, 2020

Editorial

Publicly Available February 28, 2020

Wood modification research in Europe

Holger Militz

Page range: 333-333

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Review

September 21, 2019

Outlook for modified wood use and regulations in circular economy

Henrik Heräjärvi, Janni Kunttu, Elias Hurmekoski, Teppo Hujala

Page range: 334-343

Abstract

Circular economy may play a key role in the future success of modified wood products. The European Union (EU) aims toward a circular economy, i.e. increasing resource efficiency by waste minimization in production processes, cascade uses of materials, elimination of landfill wastes, and maximizing the value of raw materials. The policy has great expected impact across all sectors, and will influence countries with strong wood modification industries, such as Finland, Germany, Norway, and the Netherlands. It also means considerable economic efforts and sets transformation challenges to the societies and industries. Challenges have country-wise differences depending on production structure, environmental circumstances, local policies and regulations, as well as economic resources. This paper is an outlook of the renewed waste legislation in the EU, based on which it assesses the possible impacts of circular economy development on the future of wood modification. One of the key indicators for resource efficiency is € kg −1 , which allows pursuing increased efficiency by minimizing material input (and waste) and/or by maximizing the value. In the case of modified wood, both of these approaches may be considered market opportunities, while the key challenge and the consequent need for action relate to improved waste management.

Original Articles

January 11, 2020

Suitability of a lignin-derived mono-phenol mimic to replace phenol in phenol-formaldehyde resin for use in wood treatment

Vladimirs Biziks, Marco Fleckenstein, Carsten Mai, Holger Militz

Page range: 344-350

Abstract

The goal of this study was to assess the suitability of a single mono-aromatic for substitution of petroleum-based phenol for phenol-formaldehyde (PF) resin synthesis and the usage of a new resin for wood treatment. After proper thermal decomposition of wood-based lignin, pyrolysis oil can be obtained. Due to the heterogeneity of the lignin macromolecule, oil contains large variety of organic-based compounds, mainly mono-aromatics, which are proposed to be used for replacement of phenol during PF resin synthesis. Therefore, for this purpose, nine of the most abundant mono-aromatic compounds in bio-oil were selected: ortho-, meta-, para-cresol, guaiacol, catechol, 4-methylcatechol, resorcinol, syringol, 4-ethylphenol and resol-type resin from each mono-aromatic were synthesized. Relevant features of the resin such as pH, viscosity, average molecular weight and curing behavior of resins using differential scanning calorimetry (DSC) were analyzed. Scots pine ( Pinus sylvestris L.) sapwood samples were used to evaluate the suitability of resin for wood treatment in terms of dimensional stability and were compared with the PF resin-treated wood. From all tested resins, those made of guaiacol or ortho-, or meta-, or para-cresol and/or 4-ethylphenol proved to be suitable for wood treatment, whereas resins made of catechol or 4-methylguaiacol and syringol did not. Suitability of mono-aromatics for synthesis of resol-type resin depends on chemical structure, where the reactivity of the mono-aromatic (derivative of hydroxybenzene) is defined by the type, location and number of substituents.

January 28, 2020

Beech wood treated with polyglycerol succinate: a new effective method for its protection and stabilization

Clément L’Hostis, Emmanuel Fredon, Marie-France Thévenon, Francisco-José Santiago-Medina, Philippe Gérardin

Page range: 351-361

Abstract

This paper deals with an original and non-biocidal chemical treatment consisting of a vacuum/pressure impregnation step of beech wood with a water-borne mixture made from heat-activated condensation of succinic anhydride (SA) and glycerol (G). Chemical structures of adducts were established using matrix-assisted laser desorption ionization time-of-flight mass spectroscopy (MALDI-TOF) investigations. Beech wood was impregnated and cured in order to induce in situ polymerization of glycerol/succinic adducts (GSA) in the cell walls, leading to the formation of polyglycerol succinate (PGS) polyester. Various treatment conditions were investigated depending on the duration (6–72 h) and curing temperature (103–160°C). Weight percent gains (WPGs) ranging between 40 and 60% were obtained. Attenuated total reflectance-middle infrared spectroscopy (ATR-MIR) and carbon-13 nuclear magnetic resonance ( 13 C-NMR) spectroscopy confirmed polyester formation. A curing temperature of 160°C was found to be the best condition to totally avoid polymer leaching, and brought the anti-swelling efficiency (ASE) up to 64%. Decay resistance of PGS-treated wood against Trametes versicolor and Coniophora puteana was also strongly temperature and time dependent: performances fit with the EN113 standard requirements if a curing temperature of 160°C was applied.

February 14, 2020

Study on the impregnation quality of rubberwood (Hevea brasiliensis Müll. Arg.) and English oak (Quercus robur L.) sawn veneers after treatment with 1,3-dimethylol-4,5- dihydroxyethyleneurea (DMDHEU)

Lukas Emmerich, Holger Militz

Page range: 362-371

Abstract

The efficacy of chemical wood modification is closely related to the permeability of the wood species and the cell wall deposition of the reagent, causing a permanent swelling (“bulking effect”). This study aimed to analyze how rubberwood ( Hevea brasiliensis Müll. Arg.) and English oak ( Quercus robur L.) may be affected by chemical wood modification, although they are known to show either variations in permeability or being less permeable. Thin clear veneers were treated with 1,3-dimethylol-4,5- dihydroxyethyleneurea (DMDHEU) which resulted in significantly reduced moisture-induced swelling and increased the resistance to static and dynamic indentation loads. The results evidenced significantly lower liquid uptakes in English oak compared to rubberwood, which directly affected the weight percent gains (WPGs) and restricted the range for potential improvements of the material properties. Surprisingly, rubberwood showed a lower cell wall bulking, which, in comparison with English oak, indicated less DMDHEU monomers entering the cell walls and rather being located in the cell lumens. Atypical for treatments with cell wall penetration chemicals, no further decrease in maximum swelling ( S M ) was detected with increasing bulking in rubberwood specimens. English oak showed higher variations in DMDHEU distribution within treated veneers and between earlywood and latewood areas, effecting a less homogeneous performance.

September 24, 2019

The effect of diammonium phosphate and sodium silicate on the adhesion and fire properties of birch veneer

Saara Hautamäki, Michael Altgen, Daniela Altgen, Erik Larnøy, Tuomas Hänninen, Lauri Rautkari

Page range: 372-381

Abstract

In built environments the combustibility of wood is a great concern, which limits the use of wood as a building material due to legislation. The reaction-to-fire properties of wood can be altered with the use of fire-retardant chemicals, and most of the commonly used fire retardants already have a long history of use. However, only limited information is available on the impact of different fire retardants on the adhesion properties of wood. Additionally, comparative studies between chemicals from different groups of fire retardants is scarce. The objective of this study was to investigate and compare the effects of two commonly used fire retardants, sodium silicate (SS) and diammonium phosphate (DAP), on veneer properties, the focus being especially on thermal behavior and adhesion. Thermal properties and combustibility were studied using thermogravimetric analysis (TGA), flame test and calorimetry. Glue bond strength was analyzed with an automated bonding evaluation system (ABES) and the leaching of chemicals was determined according to EN84. Additionally, the surface characteristics of modified veneers were imaged with scanning electron microscopy (SEM). Results revealed notable differences in the thermal properties of SS and DAP, with DAP having better fire-retardant performance in all thermal testing. SS also affected thermal properties and combustibility of modified veneers, but the effect was only moderate compared to DAP. Neither SS or DAP had any significant resistance against leaching but ABES testing showed a notable increase in the glue bond strength of DAP modified veneers.

October 25, 2019

Enhanced bonding of acetylated wood with an MUF-based adhesive and a resorcinol-formaldehyde-based primer

Andreas Treu, Ronny Bredesen, Ferry Bongers

Page range: 382-390

Abstract

Acetylated wood is a durable and dimensionally stable product with many potential applications in exterior timber structures. Research has shown that acetylated wood can be effectively bonded by various adhesive types. However, one of the most commonly used adhesives for timber constructions, melamine urea formaldehyde (MUF), shows poor performance in combination with acetylated wood in delamination tests based on cyclic wetting and drying. The hydrophobic acetylated wood surface leads to reduced adhesion due to poorer adhesive wetting and fewer chemical bonds between the resin and the wood polymers. The use of a resorcinol-formaldehyde (RF)-based primer on the acetylated wood surface prior to the application of MUF leads to positive gluing results with both acetylated radiata pine and beech, providing significantly improved resistance to delamination. Radial penetration of the primer and MUF in acetylated wood shows higher penetration compared with untreated wood. In addition, a phenol resorcinol-formaldehyde adhesive system showed high resistance against delamination and can be used for gluing of acetylated wood.

February 6, 2020

Brown rot gene expression and regulation in acetylated and furfurylated wood: a complex picture

Rebecka Ringman, Annica Pilgård, Klaus Richter

Page range: 391-399

Abstract

The aim of this study was to investigate Rhodonia placenta expression patterns of genes involved in the depolymerisation during the non-enzymatic phase in acetylated (W Ac ) and furfurylated wood (W FA ). During the 98-day-long exposure, W Ac [22.6% weight per cent gain (WPG) on average] and W FA (69% WPG on average) lost no more than 3% mass while the untreated wood (W Un ) reached 41% mass loss (ML) in 55 days. Expression of six genes putatively involved in the non-enzymatic degradation process were investigated. In conclusion, expression levels of alcohol oxidase Ppl118723 ( AlOx1 ) and laccase Ppl111314 ( Lac ) were significantly higher in the modified wood materials (W Mod ) than in W Un , which is in accordance with previous results and may be explained by the absence of the degradation products that have been proposed to down-regulate the non-enzymatic degradation process. However, copper radical oxidase Ppl156703 ( CRO1 ) and a putative quinate transporter Ppl44553 ( PQT ) were expressed at significantly lower levels in W Mod than in W Un while quinone reductase Ppl124517 ( QRD ) and glucose oxidase Ppl108489 ( GOx ) were expressed at similar levels as in W Un . These results suggest that gene regulation in W Mod is more complex than a general up-regulation of genes involved in the non-enzymatic degradation phase.

November 7, 2019

Investigation of the effect of aging on wood hygroscopicity by 2D ¹H NMR relaxometry

Leila Rostom, Denis Courtier-Murias, Stéphane Rodts, Sabine Care

Page range: 400-411

Abstract

Two-dimensional proton nuclear magnetic resonance (2D 1 H NMR) relaxometry is increasingly used in the field of wood sciences due to its great potential in detecting and quantifying water states at the level of wood constituents. More precisely, in this study, this technique is used to investigate the changes induced by “natural” and “artificial” aging methods on modern and historical oak woods. Two bound water components are detected and present differences in terms of association to the different wood polymers in cell walls: one is more strongly associated with wood polymers than the other. The evolution of the two bound water types is discussed in regard to aging methods and is related to the structure of the cell wall, especially with the S2 layer and the evolution of wood chemical composition (cellulose, hemicelluloses and lignin). The evolution of hydric strains is also discussed taking into account the effect of aging methods on the two bound water components. The obtained results confirm the ability of 2D 1 H NMR relaxometry to evaluate the effect of aging at the molecular level and on hydric deformation. Furthermore, this method shows that it is possible to determine the moisture content of wood without the necessity to oven-dry the wood material.

September 27, 2019

Dynamic vapour sorption protocols for the quantification of accessible hydroxyl groups in wood

Tuuli Uimonen, Saara Hautamäki, Michael Altgen, Maija Kymäläinen, Lauri Rautkari

Page range: 412-419

Abstract

This study investigated several key parameters of deuterium exchange measurements in a dynamic vapour sorption apparatus to optimise the measurement protocol for hydroxyl (OH) group accessibility determination. The impact of changing the sample mass, the deuterium oxide (D 2 O) vapour exposure time and the rate of change in moisture content (dm dt −1 ) during the drying steps on the measured OH group accessibility were analysed. A sample mass of more than 10 mg, an exposure to D 2 O vapour of at least 10 h and a dm dt −1 of 0.0005% min −1 over a 10-min period during the drying steps gave the most reliable results. We also investigated the necessity of adding a method stage that eliminates the effect of inclusion compounds (ICs). The addition of an initial drying and wetting stage enabled the release of entrapped solvents.

Publicly Available August 14, 2019

A molecular model for reversible and irreversible hygroscopicity changes by thermal wood modification

Wim Willems, Michael Altgen, Lauri Rautkari

Page range: 420-425

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Abstract

Heat treatment (HT) is a well-known means to reduce the equilibrium wood moisture content (EMC) at a specified relative humidity (RH). EMC is profoundly decreased by the loss of accessible hydroxyl groups (OH acc ) in the wood matrix by thermochemical reactions. However, the obtained EMC reduction after HT can be partly reversible, depending on the ability of the wood matrix polymers to fully mechanically relax during HT. We discuss the results of our earlier experimental study on the OH acc content and the associated EMC decrease at 93% RH by a relaxation inhibiting dry-HT vs. a relaxation enabling wet-HT. New experimental results, showing that OH acc does not significantly change during reversible EMC changes, are added to the discussion. This study quantitatively supports a molecular explanation of the reversible EMC, in which wood moisture is principally bound at sorption sites, composed of two functional groups, constituting a hydrogen-donor/acceptor pair, involving at least one OH acc group. The irreversible part of EMC reduction is assigned to the thermochemical removal of OH acc from the wood matrix. The reversible part is attributed to a process of wood polymer conformal rearrangements, bringing an isolated OH acc group in proximity of another free hydrogen-bonding functional group, creating a site for water sorption.

September 7, 2019

Effect of service life aspects on carbon footprint: a comparison of wood decking products

Lars G. F. Tellnes, Gry Alfredsen, Per Otto Flæte, Lone Ross Gobakken

Page range: 426-433

Abstract

Carbon footprint over the life cycle is one of the most common environmental performance indicators. In recent years, several wood material producers have published environmental product declarations (EPDs) according to the EN 15804, which makes it possible to compare the carbon footprint of product alternatives. The objective of this study was to investigate the effect of service life aspects by comparing the carbon footprint of treated wood decking products with similar performance expectations. The results showed that the modified wood products had substantially larger carbon footprints during manufacturing than preservative-treated decking materials. Replacement of modified wood during service life creates a huge impact on life cycle carbon footprint, while maintenance with oil provided a large contribution for preservative-treated decking. Hence, service life and maintenance intervals are crucial for the performance ranking between products. The methodological issues to be aware of are: how the functional unit specifies the key performance requirements for the installed product, and whether full replacement is the best modeling option in cases where the decking installation is close to the end of the required service life.

About this journal

Objective
Holzforschung (HF) is an international scholarly journal that publishes cutting-edge research on the biology, chemistry, physics and technology of wood and wood components. High quality papers about biotechnology and tree genetics are also welcome. Rated year after year as one of the top scientific journals in the category of Pulp and Paper (ISI Journal Citation Index), Holzforschung represents innovative, high quality basic and applied research. The German title reflects the journal's origins in a long scientific tradition, but all articles are published in English to stimulate and promote cooperation between experts all over the world. Ahead-of-print publishing ensures fastest possible knowledge transfer.

Topics

Biology, chemistry, physics and technology of wood and wood components
Biotechnology and tree genetics

Article formats
Original articles, Reviews, Short notes

> Information on submission process

Volume 74 Issue 4 - Special Issue: The 9th European Conference on Wood Modification (Arnhem, the Netherlands, September 17–18, 2018) / Issue Editor: Holger Militz

Issue of Holzforschung

Frontmatter

Wood modification research in Europe

Outlook for modified wood use and regulations in circular economy

Abstract

Suitability of a lignin-derived mono-phenol mimic to replace phenol in phenol-formaldehyde resin for use in wood treatment

Abstract

Beech wood treated with polyglycerol succinate: a new effective method for its protection and stabilization

Abstract

Study on the impregnation quality of rubberwood (Hevea brasiliensis Müll. Arg.) and English oak (Quercus robur L.) sawn veneers after treatment with 1,3-dimethylol-4,5- dihydroxyethyleneurea (DMDHEU)

Abstract

The effect of diammonium phosphate and sodium silicate on the adhesion and fire properties of birch veneer

Abstract

Enhanced bonding of acetylated wood with an MUF-based adhesive and a resorcinol-formaldehyde-based primer

Abstract

Brown rot gene expression and regulation in acetylated and furfurylated wood: a complex picture

Abstract

Investigation of the effect of aging on wood hygroscopicity by 2D 1H NMR relaxometry

Abstract

Dynamic vapour sorption protocols for the quantification of accessible hydroxyl groups in wood

Abstract

A molecular model for reversible and irreversible hygroscopicity changes by thermal wood modification

Abstract

Effect of service life aspects on carbon footprint: a comparison of wood decking products

Abstract

Investigation of the effect of aging on wood hygroscopicity by 2D ¹H NMR relaxometry