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October 23, 2021
Abstract
Buffer/backfill materials for radioactive waste disposal sites consist of pure bentonite or bentonite-rock mixtures. In this study, the batch test method was used to obtain the sorption characteristics of important radionuclides such as Cs, Sr and Co on buffer/backfill materials; i. e., mixing Wyoming MX-80 bentonite or local Taiwanese Zhi-Shin bentonite with possible host rock (argillite and granite) in different proportions (0∼100%). The distribution coefficients (K d ) for Cs, Sr and Co were obtained from the experiments. The distribution coefficient for the bentonite-rock mixtures were found, with more than 50% of mixing proportion of bentonite to argillite or granite, to have very similar values to that of pure bentonite. Furthermore, it was clearly found that the sorption of Cs, Sr and Co to bentonite-rock mixtures is decreased as ionic strength of the liquid phase is increased from 0.001M to 1M for NaCl solutions. According to the experimental results, in synthetic groundwater, it is quite convenient and helpful to assess the distribution coefficients (Kd) of Cs, Sr and Co for buffer/backfill materials using batch sorption experiments with bentonite-rock mixtures of fixed mixing proportions.