For a sequence x ∈ l 1\c 00, one can consider the achievement set E(x) of all subsums of series Σn=1∞ x(n). It is known that E(x) has one of the following structures: a finite union of closed intervals, a set homeomorphic to the Cantor set, a set homeomorphic to the set T of subsums of Σn=1∞ x(n) where c(2n − 1) = 3/4n and c(2n) = 2/4n (Cantorval). Based on ideas of Jones and Velleman [Jones R., Achievement sets of sequences, Amer. Math. Monthly, 2011, 118(6), 508–521] and Guthrie and Nymann [Guthrie J.A., Nymann J.E., The topological structure of the set of subsums of an infinite series, Colloq. Math., 1988, 55(2), 323–327] we describe families of sequences which contain, according to our knowledge, all known examples of x with E(x) being Cantorvals.