Published by De Gruyter

Volume 56 Issue 1

Issue of Zeitschrift für Naturforschung B

Contents
Journal Overview

Publicly Available June 2, 2014

Titelei

Page range: I-II

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Publicly Available June 2, 2014

Page range: III-XII

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June 2, 2014

Structure and Properties of the Stannides CeAuSn, Ce₃Rh₄Sn₁₃, and Ce₃Ir₄Sn₁₃

Dirk Niepmann, Rainer Pöttgen, Kristin M. Poduska, Francis J. DiSalvo, Henning Trill, Bernd D. Mosel

Page range: 1-8

Abstract

CeAuSn, Ce 3 Rh 4 Sn 13 , and Ce 3 lr 4 Sn 13 were prepared by reaction of the elements in an arc-melting furnace and subsequent annealing at 970 K for two weeks. The three stannides were investigated by X-ray powder and single crystal techniques. CeAuSn crystallizes with the NdPtSb type, space group P6 3 mc: a = 472.7(2), c = 771.6(3) pm, wR2 = 0.0230,208 F 2 values, 11 variable parameters, and BASF = 0.40(2). The gold and tin atoms form a pronounced two-dimensional [AuSn] polyanion which consists of slightly puckered Au 3 Sn 3 hexagons. , 19 Sn Mössbauer data at 78 K show one signal at an isomer shift of δ = 1.90(7) mm/s subjected to unresolved quadrupole splitting of ΔE Q = 0.55(2) mm/s. Ce 3 Rh 4 Sn 13 and Ce 3 lr 4 Sn 13 adopt the cubic Yb 3 Rh 4 Sn 13 type structure, space group Pm3n: a = 970.51(3) pm, wR2 = 0.0721, 267 F 2 values (Ce 3 Rh 4 Sn 13 ) and a = 972.29(6) pm, wR2 = 0.0850, 267 F 2 values (Ce 3 lr 4 Sn 13 ) with 14 variable parameters for each refinement. Striking structural motifs in Ce 3 Rh 4 Sn 13 are condensed distorted trigonal [RhSn 6 ] prisms with Rh-Sn distances of 266 pm. The polyhedral network leaves two different cages which are occupied by cerium (6c position) and tin (2a position) atoms. The Sn2 atoms show occupancy parameters of only 92% (Ce 3 Rh 4 Sn 13 ) and 76% (Ce 3 Ir 4 Sn 13 ) and an extremely large displacement parameter indicating a rattling of these atoms within the icosahedral Sn 12 cages. Magnetic susceptibility measurements of Ce 3 Rh 4 Sn 13 show paramagnetic behavior down to 2 K with an experimental magnetic moment of 2.45(2) μ B /Ce. No magnetic ordering is observed. Magnetization measurements show a moment of 0.78(2) μ B /Ce at 2 K and 5.5 T. Resistivity data reveal only a very weak temperature dependence. The two crystallographically different tin sites are resolved in the 119 Sn Mössbauer spectrum which shows a signal at δ = 2.12(1) mm/s subject to quadrupole splitting of 1.54(1) mm/s, superimposed by a singlet at δ = 2.47(1) mm/s. The Seebeck coefficient of Ce 3 Rh 4 Sn 13 is within a few μ V/K of zero over the temperature range of 10 - 300 K.

June 2, 2014

Darstellung und spektroskopische Charakterisierung von Natriumpentacyano(phosphan/phosphit)ferraten(III) / Preparation and Spectroscopic Characterization of Sodium Pentacyano(phosphane/phosphite)ferrates(III)

Hidenari Inoue, Satomi Osone, Ekkehard Fluck

Page range: 9-12

Abstract

Sodium pentacyanoferrates(III) of the type Na 2 [Fe(CN) 5 L] (L = phosphane or phosphite) have been prepared from sodium pentacyanoferrates(II), Na 3 [Fe(CN) 5 L], by bromine oxidation and characterized by Mössbauer, IR, and electronic spectroscopy. Isomer shifts and quadrupole splittings lie within the range commonly found in low-spin iron(III) complexes. A linear correlation was found between isomer shifts and CN stretching and Fe-CN bending frequencies, respectively. The spectroscopic parameters show that the d π -d π back bonding of the Fe-P bonds is synergetically strengthened with increasing σ donor capability of the phosphorus ligands.

June 2, 2014

Wechselwirkungen in Molekülkristallen, 166 [1, 2]. Polyiod-Moleküle I₂C=CI₂, (IC)₄S, (IC)₄NH, (IC)₄N-CH₃ und HCI₃: Strukturbestimmung nach Kristallzüchtung oder durch Dichtefunktionaltheorie-Berechnung / Interaction in Molecular Crystals, 166 [1, 2], Polyiodo Molecules I₂C=CI₂, (IC)₄S, (IC)₄ NH, (IC)₄N-CH_{and HCI₃: Structure Determination Following Crystallization or by Density Functional Theory Calculation}

Hans Bock, Sven Holl, Volker Krenzel

Page range: 13-24

Abstract

The structures of tri-and tetraiodo-substituted carbon compounds are determined either experimentally by X-Ray Structure Analysis or, because crystallization of tetraiodothiophene could not be achieved, approximated by Density Functional Theory optimization of structural data from a donor/acceptor complex. The structures show noteworthy details such as a second polymorph of tetraiodoethene crystallized by sublimation or herringbone crystal packing patterns of tetraiodopyrrole derivatives. All molecular geometries are discussed and compared based on relativistic density functional theory calculations with 6 -31G* basis sets including iodine pseudopotentials. They reproduce even finer structural details due to van der Waals repulsion of the bulky iodo substituents. Natural Bond Orbital (NBO) charge distributions suggest positive partial charges at all iodine centers with the strongest polarization Cδ ㊀ → Iδ ㊉ in HCI3, which contains well over 97% iodine.

June 2, 2014

Synthesis and Structure of Chiral Silatranes Derived from Terpenes

Gabriele Wagner, Rudolf Herrmann, BjØrn Pedersen, Wolfgang Scherer

Page range: 25-38

Abstract

Starting with the chiral pool compounds (-)-menthone, (-)-limonene, (-)-β-pinene, and (-)-carvone, new homochiral triethanolamine derivatives were obtained and converted to chiral silatranes. These silatranes were characterized by crystal structure analyses and NMR techniques. Conformational analyses in the solid state and in solution show that the chiral terpene residues determine the direction of the ring puckering of the silatrane moiety.

June 2, 2014

Kristallstruktur von Tetraphenylphosphonium Dichloroiodat(I) [PPh₄][ICl₂] / Crystal Structure of Tetraphenylphosphonium Dichloroiodate(I) [PPh₄][ICl₂]

Rolf Minkwitz, Michael Berkei

Page range: 39-42

Abstract

Dichloroiodate Tetraphenylphosphonium dichloroiodate(I) [PPh 4 ] [ICl 2 ] crystallises in the monoclinic system in the space group P2/n with a = 1025.7(1), b = 770.2(1), c = 1446.4(1) pm, ß = 90.11(1)° and two formula units per unit cell. The ICl 2 - anion is symmetrical (C 2v ) and almost linear with I-Cl bond lengths of 257.1(2) pm and a bond angle of 178.10(6)°.

June 2, 2014

Crystal Structure and Magnetic Properties of a Linear Trinuclear Ni(II) Complex

E. Kavlakoglu, A. Eimali, Y. Elerman, R. Werner, I. Svoboda, H. Fuess

Page range: 43-48

Abstract

Linear Trinuclear Nickel(II) Complex, Super-Exchange Interactions, Antiferromagnetic Coupling [Ni 3 (C 2 H 32 (CH 3 O) 2 L 2 ] [L = 13-bis(5-chlorosalicylideneamino)propan-2-ol dianion, (C 2 H 3 O 2 ) - = acetate, (CH 3 OH) = methanol] was synthesized and its crystal structure was determined. It crystallizes in the monoclinic spaceeroup P2 1 /n with a = 12.694(2), b = 13.281 (4), c = 15.420(3) Å, β = 111.25(2)°, V = 2422.9(9) Å 3 ,Z = 2 . The molecule is a "linear" trinuclear complex with nearly octahedral coordination of each nickel ion. Adjacent nickel(II) ions are bridged by the phenolic oxygen atoms of the ligands and the oxygen atoms of the acetato ligands. The coordination sphere of the terminal nickel(II) ions is completed by the oxygen atom of the methanol. Adjacent nickel(II) centers are separated by 3.043(1) Å and weakly antiferromagnetically coupled (J 1 = -3 .4 cm -1 ). The terminal nickel(II) centers are separated by 6.086(1) Å and very weakly antiferromagnetically coupled (J 2 = -0 .3 cm -1 ) which follows from temperature-dependent magnetic susceptibility measurements in the temperature range 4.5 to 318 K. The magnetic moment rises from 2.99 μ B at 4.5 K to 5.42 μ B at 318 K. In the X (T) curve no characteristic maximum was observed.

June 2, 2014

New Information on the Na-Ti-Se Ternary System

Jennifer A. Aitken, Mercouri G. Kanatzidis

Page range: 49-56

Abstract

Molten Salt Fluxes, Polychalcogenide, Polyselenide Na 2 Ti 2 Se 9 was first discovered in the quaternary system Na/Ti/P/Se, but it can be prepared rationally by dissolving Ti in a Na 2 Se x flux at 375 °C. The silverish dark red crystals are air-and water-stable. A new method for synthesizing Na 4 TiSe 4 is also reported. Na 2 Ti 2 Se 9 crystallizes in space group P2 1 , with a = 12.785(4), b = 14.848(4), c = 13.961(4) Å, ß = 94.556(4)°, R1 = 0.0592 and wR2 = 0.1336. The structure is similar to that of KsNaTi 6 Se 27 . It contains infinite one dimensional chains which run parallel to the c-axis and contain Ti 4+ centers bonded to Se 2 2- and Se 2- species. The l/∞[Ti 2 (Se 2 ) 4 Se] 2- chains pack together in a hexagonal pattern. All of the titanium atoms are surrounded by a pentagonal bipyramid of selenium atoms. The selenium atoms bridge the Ti centers in two different ways. Na 2 Ti 2 Se 9 is a semiconductor with a band gap, E g , of ~ 1.02 eV. The Raman spectra are also reported.

June 2, 2014

Some Organic-Inorganic Hybrid Compounds Based on iso– Thiuronium Cations and Lead Halide Anions

G. C. Papavassiliou, G. A. Mousdis, I. B. Koutselas

Page range: 57-61

Abstract

Using 1-chlorodecane (C 10 H 21 CI), benzyl chloride (C 6 H 5 CH 2 CI), a,a'-dichloro-p-xylene (CICH 2 C 6 H 4 CH 2 CI), 4-phenylbenzyl chloride (C 6 H 5 C 6 H 4 CH 2 CI), 2-bromomethyl-naphthal-ene (C 10 H 7 CH 2 Br), 4-bromomethyl-7-methoxycoumarin (C 10 H 7 O 3 CH 2 Br), 2-bromomethyl-anthraquinone (C 14 H 7 CH 2 Br), 9-chloromethyl-anthracene (C 14 H 9 CH 2 CI), thiourea and halides as starting materials, the organic-inorganic hybrid compounds [C 10 H 21 SC(NH 2 ) 2 ] 2 Pbl 4 , [C 6 H 5 CH 2 SC(NH 2 ) 2 ] 4 Pb 3 l 10 [(H 2 N 2 )CSCH 2 C 6 H 4 CH 2 SC(NH 2 ) 2 ] 0.5 PbI 3 , [C 6 H 5 C 6 H 4 CH 2 S-C(NH 2 ) 2 ]PbI 3 , [C 10 H 7 CH 2 SC(NH 2 ) 2 ]Pbl 3 , [C 14 H 7 O 2 CH 2 SC(NH 2 ) 2 ]Pbl 3 , [C 14 H 9 CH 2 SC(NH 2 ) 2 ]PbI 3 , and [C 14 H 9 CH 2 SC(NH 2 ) 2 ]PbBr 4 , were prepared and characterized analytically and spectroscopically.

June 2, 2014

Metallkomplexe mit biologisch wichtigen Liganden, CXXXI. Pentamethylcyclopentadienyl-Halbsandwich-Komplexe von Rhodium und Iridium mit Glycosyl-«-iminocarboxylaten als Chelat-Liganden / M etal C om plexes of Biologically Im portant Ligands, CXXXI. Pentam ethylcyclopentadienyl Halfsandwich Complexes of Rhodium and Iridium with Glycosyl-a-im inocarboxylates as Chelate Ligands

Stefan Krawielitzki, Wolfgang Beck

Page range: 62-68

Abstract

The N-glycosyl-iminocarboxylate complexes Cp*M(Cl)N(R)=C(R')CO 2 (M = Rh, Ir; R = glycosyl, R ’ = Me, Ph, CH 2 CHMe 2 ) with a chiral metal atom are formed in a template reaction from [Cp*MCl 2 ] 2 (M = Rh, Ir), the 2-keto carboxylic acid and tetra-O-acetyl-β-Dglucosamine, D-glucosamine or D-glucamine as mixtures of two diastereoisomers and were characterized by analytical and spectroscopic methods.

June 2, 2014

Metallkomplexe mit biologisch wichtigen Liganden, CXXXII. N,O-Chelatkomplexe von Palladium(II), Platin(II) und Iridium(III) mit dem Anion von Glucosaminsäure (2-Amino-2-deoxy-D-gluconsäure) / Metal Complexes of Biologically Important Ligands, CXXXII. N ,O -Chelate Complexes of Palladium (II), Platinum (II), and Iridium (III) with the Anion of Glucosaminic Acid (2-Amino-2-deoxy-D-gluconic Acid)

Stefan Krawielitzki, Wolfgang Beck

Page range: 69-72

Abstract

From 2-amino-2-deoxy-D-gluconic acid (LH) and chloro bridged metal complexes the N,O chelates (R 3 P)(Cl)Pd(L) (R = n-C 4 H 9 , Ph), (n-C 4 H 9 ) 3 P(Cl)Pt(L), (C 6 H 4 CH 2 NMe 2 )Pd(L), (Ph-N=N-C 6 H 4 )Pd(L), Cp*(Cl)Ir(L) are formed. They were characterized by analytical and spectroscopic data.

June 2, 2014

Synthese und Struktur von benzylsubstituierten Derivaten des Dinickel-Tripeldeckerkomplexes μ-η⁵,η⁵(2,3–Dihydro–1,3-diborolyl)-(η³–allyl)(η⁴–1,5–hexadien) dinickel / Synthesis and Structure of Benzyl Substituted Derivatives of the Dinickel Triple-Decker Complex μ–η⁵, η⁵–(2 ,3–Dihydro–1,3 -diborolyl)– (η³–allyl)(η⁴– 1,5 -hexadiene)dinickel

Walter Siebert, Stefan Huck, Hans Pritzkow

Page range: 73-78

Abstract

Hydroboration of phenyl- and mesitylethyne with in situ formed HBCl 2 leads to an isomeric mixture of 1,1-bis(dichloroboryl)-2-phenylethane (4a) and l,l-bis(dichloroboryl)-1-phenylethane (4b) (ratio 3 : 1) and regioselectively to 1,1-bis(dichloroboryl)-2-mesitylethane (4c). Treatment of 4a/b and 4c with BI 3 gives the corresponding tetraiodo compounds 5, which undergo redox reactions with butyne-2 to form the 1,3-diiodo-4,5-dimethyl-2,3-dihydro-1,3- diborole derivatives 6a/b and 6c. Reactions of the diiodo-1,3-diboroles with AlMe 3 or LiMe result in the formation of the very air-sensitive pentaorganyl-1,3-diboroles 1a, 1c and the hexaorganyl-1,3-diborole 1b. The mixture of 1a/b as well as 1c react with bis(η 3 -allyl)nickel to give black products, which are chromatographed on silica with hexane as eluent. The brown solids were recrystallized from pentane to give the light-brown crystals of μ-η 5 ,η 5 -[2-benzyl-l,3 ,4 ,5 -tetramethyl-2 ,3-dihydrol, 3-diborolyl](η 3 -allyl)(η 4 -1,5-hexadiene)dinickel (2a, 34%) and μ-η 5 ,η 5 -[2-(2 ,4 ,6-trimethylbenzyl)- 1,3 ,4 ,5-tetramethyl-2 ,3-dihydro-1,3-diborolyl](η 3 -allyl)(η 4 -1,5-hexadiene)dinickel (2c, 43%). lb does not react with Ni(C 3 H 5 ) 2 to form any tripledecker. The compositions of the new compounds follow from spectroscopic and analytical data, and from X-ray structure analyses of 6a and of 2a. The structure of the η 4 -1,5-hexadiene-η 3 -allyl-dinickel triple-decker 2a finally disproved the alternative tris(allyl)dinickel arrangement.

June 2, 2014

Synthesis and Crystal Structure of Mn₂(C₂H₅NH₂)₂Sb₂S₅ Exhibiting a Reversible Phase Transition

Michael Schur, Christian Näther, Wolfgang Bensch

Page range: 79-84

Abstract

Thioantimonates, Solvothermal Synthesis, Chalcogenides The reaction of elemental manganese, antimony and sulfur with ethylamine under mild solvothermal conditions yielded a thioantimonate(III) with composition Mn 2 (EA) 2 Sb 2 S 5 (EA = C 2 H 5 NH 2 ) that is a new member of a series of polymeric manganese thioantimo-nates(III). The structure of the title compound consists of layers of a neutral mesh-like Mn2Sb2S5 framework. The ethylamino ligands coordinated to the Mn centres separate the sheets and fill the voids within the layers formed by the interconnection of Mn 2 Sb 2 S 4 hetero-cubane like building blocks. Below 273 K a reversible phase transition occurs, which is accompanied by a doubling of the crystallographic a-axis.

June 2, 2014

Darstellung, ¹¹B-, ¹³C-NMR- und Schwingungsspektren von Cs₂[B₆Cl₅(p-C₆H₄(NI-I₂))] sowie Kristallstruktur von (Ph₄P)₂[B₆Cl₅(p-C₆H₄(NH₂))]·₂CH₃CN · 0,5 Et₂O / Preparation, ¹¹B, ¹³C NMR and Vibrational Spectra of Cs₂[B₆Cl₅(p-C₆H₄(NH₂))] and Crystal Structure of (Ph₄P)₂[B₆Cl₅(p-C₆H₄(NH₂))]· 2CH₃CN · 0.5 Et₂O

S. Zander, W. Preetz

Page range: 85-89

Abstract

By reduction of [B 6 Cl 5 (p-C 6 H 4 (NO 2 ))] 2- with hydrazine in the presence of Raney nickel in dichlorom ethane solution the amino derivative [B 6 Cl 5 (p-C 6 H 4 (NH 2 )] 2- is formed. X -ray diffraction analysis has been performed on a single crystal of (Ph 4 P) 2 [B 6 Cl 5 (p-C 6 H 4 (NH 2 ] ·2CH 3 CN-0,5Et 2 O(triclinic, space group P1̅, a = 12.870(6), b = 12.9406(5), c = 35,870(7) Å , a = 91,63(4), ß = 93,22(7), γ = 98,04(8)°, Z = 2). The 11 B NMR spectrum is consistent with a monosubstituted B 6 cluster. The IR and R am an spectra exhibit characteristic BB, CH , CC, and NH vibrations, respectively.

June 2, 2014

Dimeres Di(N-lithium–tert–butylamino)bis(dimethylamino)silan - [Si(N(CH₃)₂)₂(NLiC(CH₃)₃)₂]₂ – Darstellung und Kristallstruktur / Dimeric Di(N -lithio-tert-butylamino)bis(dimethylamino)silane - [Si(N(CH₃)₂)₂(NLiC(CH₃)₃)₂]₂ – Synthesis und Crystal Structure

Josef Engering, Eva-Maria Peters, Martin Jansen

Page range: 90-94

Abstract

[Si(N(CH 3 ) 2 ) 2 (NLiC(CH 3 ) 3 ) 2 ] 2 results from the reaction of silicon tetrachloride with excess terf-butylamine, followed by halogen substitution with LiN(CH 3 ) 2 , and treatment with n-butyllithium in hexane. The title compound, found to be dimeric in the solid state, was characterised by single crystal X-ray diffraction (triclinic, Pi , a = 10.208(2), b = 12.140(2), c = 15.658(3) Å , a = 79.02(3), ß = 82.80(3), γ = 67.19(3)°, Z = 2, C 24 H 60 Li 4 N 8 Si 2 ), and by solid state and solution NMR-spectroscopy and mass spectrometry.

June 2, 2014

Über Komplexe des Typs {(PhC=C)₃P}₃M(CO)₃ (M = Cr, Mo, W) / On Complexes of the Type {(PhC=C)₃P}₃M(CO)₃ (M = Cr, Mo, W)

Norbert Kuhn, Martin Göhner, Manfred Steimann

Page range: 95-99

Abstract

The tris(alkinyl)phosphine complexes {(PhC=C) 3 P} 3 M(CO) 3 , M = Cr (3a), Mo (3b), W (3c), are obtained from P(C=CPh) 3 and (C 6 H 15 N 3 )M(CO) 3 (C 6 H 15 N 3 = 1,3,5-trimethyl-1,3,5-triazacyclohexane) as stable yellow solids in good yields. While IR data indicate significant acceptor properties of the phosphane ligands, the X-ray structure analysis of 3c also allows the discussion of weak donor interactions.

June 2, 2014

Crystallographic and Spectroscopic Evidence of O-Bonding in 3d-MetaI Dicyanomethanidonitrite Complexes

M. Hvastijová, J. Kohout, J. W. Buchler, H. W. Katzenmeier, J. Kožíšek, C. Didierjean

Page range: 100-104

Abstract

The coordination of the dicyanomethanidonitrite group through the nitroso oxygen atom in the tetrakis(pyridine) complexes [M{ONC(CN) 2 } 2 (py) 4 ], M = Ni, Co, Cu, and in the bis(pyridine) complex [Cu{ONC(CN) 2 } 2 (py) 2 ] was proved by X-ray crystallography of the Ni 11 complex and re-evaluated infrared spectra. The Ni 11 and Co 11 complexes exhibit almost octahedral structures composed of four pyridine nitrogen atoms and two oxygen atoms of dicyanomethanidonitrite ions. Both copper(II) complexes display a considerable axial distortion of the pseudooctahedral arrangement. In the bis(pyridine) Cu 11 complex the ONC(CN) 2 groups are involved in the bridging function by use of the oxygen and nitrile nitrogen atoms.

June 2, 2014

Orthoamide, LV [1]. C₇H₇N₃O₆ - Tris(diformylamino)methan („Formylaalen“) - ein Orthoameisensäureamid-Derivat mit sechs Formylgruppen / Orthoam ides, LV [1]. C₇H₇N₃O₆ - Tris(diformylamino)methane ( “Formylaalen”) - an Orthoformic Acid Amide Derivative with Six Formyl Groups

Willi Kantlehner, Georg Ziegler, Michael Ciesielski, Oliver Scherr, Markus Vettel

Page range: 105-107

Abstract

The preparation of tris(diformylamino)methane (3), a hitherto unknown derivative of orthoformic acid, is described. In the presence of a Lewis acid the orthoamide 3 formylates activated aromatic compounds.

June 2, 2014

Effekt der Germaniumisotope auf die chemische Verschiebung von ¹⁹F in Difluordimethylgerman und von ¹³C in Tetramethylgerman / Germanium Isotope Effect on the ¹⁹F Chemical Shift in Difluorodimethylgerm ane and the ¹³C Chemical Shift in Tetram ethylgermane

W. Büchner, W. Wolfsberger

Page range: 108-110

Abstract

An isotope effect of about -0.8 Hz at 188 MHz ( - 4 ppb) per two mass units on the 19 F chemical shift in Me 2 GeF 2 due to directly bonded 70 Ge/ 72 Ge/ 74 Ge/ 76 Ge has been observed. The analogous isotope effect on the 13 C chemical shift in Me 4 Ge is about -0.045 Hz at 100.6 MHz (-0.45 ppb).

About this journal

Objective
Zeitschrift fuer Naturforschung B (ZNB) publishes novel research in all areas of inorganic chemistry, organic chemistry, and analytical chemistry. In particular, the journal focuses on solid state chemistry, coordination chemistry, main group element chemistry, synthetic organic chemistry, natural product chemistry and, to a lesser extent, on analytical chemistry. For more than 65 years Zeitschrift fuer Naturforschung B has been open to contributions from all fields of experimental and theoretical chemistry. Zeitschrift fuer Naturforschung B publishes 12 issues per volume/year. Sometimes double issues occur.

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Solid state chemistry
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Volume 56 Issue 1

Issue of Zeitschrift für Naturforschung B

Titelei

Contents

Structure and Properties of the Stannides CeAuSn, Ce3Rh4Sn13, and Ce3Ir4Sn13

Abstract

Darstellung und spektroskopische Charakterisierung von Natriumpentacyano(phosphan/phosphit)ferraten(III) / Preparation and Spectroscopic Characterization of Sodium Pentacyano(phosphane/phosphite)ferrates(III)

Abstract

Abstract

Synthesis and Structure of Chiral Silatranes Derived from Terpenes

Abstract

Kristallstruktur von Tetraphenylphosphonium Dichloroiodat(I) [PPh4][ICl2] / Crystal Structure of Tetraphenylphosphonium Dichloroiodate(I) [PPh4][ICl2]

Abstract

Crystal Structure and Magnetic Properties of a Linear Trinuclear Ni(II) Complex

Abstract

New Information on the Na-Ti-Se Ternary System

Abstract

Some Organic-Inorganic Hybrid Compounds Based on iso– Thiuronium Cations and Lead Halide Anions

Abstract

Abstract

Abstract

Abstract

Synthesis and Crystal Structure of Mn2(C2H5NH2)2Sb2S5 Exhibiting a Reversible Phase Transition

Abstract

Abstract

Dimeres Di(N-lithium–tert–butylamino)bis(dimethylamino)silan - [Si(N(CH3)2)2(NLiC(CH3)3)2]2 – Darstellung und Kristallstruktur / Dimeric Di(N -lithio-tert-butylamino)bis(dimethylamino)silane - [Si(N(CH3)2)2(NLiC(CH3)3)2]2 – Synthesis und Crystal Structure

Abstract

Über Komplexe des Typs {(PhC=C)3P}3M(CO)3 (M = Cr, Mo, W) / On Complexes of the Type {(PhC=C)3P}3M(CO)3 (M = Cr, Mo, W)

Abstract

Crystallographic and Spectroscopic Evidence of O-Bonding in 3d-MetaI Dicyanomethanidonitrite Complexes

Abstract

Orthoamide, LV [1]. C7H7N3O6 - Tris(diformylamino)methan („Formylaalen“) - ein Orthoameisensäureamid-Derivat mit sechs Formylgruppen / Orthoam ides, LV [1]. C7H7N3O6 - Tris(diformylamino)methane ( “Formylaalen”) - an Orthoformic Acid Amide Derivative with Six Formyl Groups

Abstract

Effekt der Germaniumisotope auf die chemische Verschiebung von 19F in Difluordimethylgerman und von 13C in Tetramethylgerman / Germanium Isotope Effect on the 19F Chemical Shift in Difluorodimethylgerm ane and the 13C Chemical Shift in Tetram ethylgermane

Abstract

Structure and Properties of the Stannides CeAuSn, Ce₃Rh₄Sn₁₃, and Ce₃Ir₄Sn₁₃

Kristallstruktur von Tetraphenylphosphonium Dichloroiodat(I) [PPh₄][ICl₂] / Crystal Structure of Tetraphenylphosphonium Dichloroiodate(I) [PPh₄][ICl₂]

Synthesis and Crystal Structure of Mn₂(C₂H₅NH₂)₂Sb₂S₅ Exhibiting a Reversible Phase Transition

Dimeres Di(N-lithium–tert–butylamino)bis(dimethylamino)silan - [Si(N(CH₃)₂)₂(NLiC(CH₃)₃)₂]₂ – Darstellung und Kristallstruktur / Dimeric Di(N -lithio-tert-butylamino)bis(dimethylamino)silane - [Si(N(CH₃)₂)₂(NLiC(CH₃)₃)₂]₂ – Synthesis und Crystal Structure

Über Komplexe des Typs {(PhC=C)₃P}₃M(CO)₃ (M = Cr, Mo, W) / On Complexes of the Type {(PhC=C)₃P}₃M(CO)₃ (M = Cr, Mo, W)

Orthoamide, LV [1]. C₇H₇N₃O₆ - Tris(diformylamino)methan („Formylaalen“) - ein Orthoameisensäureamid-Derivat mit sechs Formylgruppen / Orthoam ides, LV [1]. C₇H₇N₃O₆ - Tris(diformylamino)methane ( “Formylaalen”) - an Orthoformic Acid Amide Derivative with Six Formyl Groups

Effekt der Germaniumisotope auf die chemische Verschiebung von ¹⁹F in Difluordimethylgerman und von ¹³C in Tetramethylgerman / Germanium Isotope Effect on the ¹⁹F Chemical Shift in Difluorodimethylgerm ane and the ¹³C Chemical Shift in Tetram ethylgermane