The structure, the elastic properties, and the Raman frequencies of the zircon and reidite polymorphs of ZrSiO4 were calculated as a function of hydrostatic pressure up to 30 GPa using HF/DFT ab initio calculations at static equilibrium (0 K). The softening of a silent (B1u) mode of zircon leads to a phase transition to a “high-pressure–low-symmetry” (HPLS) ZrSiO4 polymorph with space group I42d and cell parameters a = 6.4512 Å, c = 5.9121 Å, and V = 246.05 Å3 (at 20 GPa). The primary coordination of SiO4 and ZrO8 groups in the structure of zircon is maintained in the high-pressure phase, and the new phase deviates from that of zircon by the rotation of SiO4 tetrahedra and small distortions of the ZrO8 dodecahedra. The new polymorph is stable with respect to zircon at 20 GPa and remains a dynamically stable structure up to at least 30 GPa. On pressure release, the new phase reverts back to the zircon structure and, therefore, cannot be quenched in experiments. In contrast, the transformation from zircon to reidite is reconstructive in nature and results in a first-order transition with a volume and density change of about 9%. The calculated energies from the DFT simulations yield an equilibrium transition pressure of 9.13(1) GPa at 0 K. Simulations of the Raman spectra of the three polymorphs at 20 GPa show how they can be distinguished. In particular, the peak due to the lowest-energy A1 mode with a calculated wavenumber of 94 cm–1 is diagnostic of the HPLS phase because it does not overlap with any of the peaks of zircon or reidite.
The purpose of this investigation was to study the extent to which Portuguese soccer goalkeepers used imagery, and to examine if and how athletes of different ages differed in their use of imagery. Seventy soccer goalkeepers playing in the two major Portuguese soccer leagues completed the translated versions of the Sports Inventory of Mental Strategies, the Imagery Use Questionnaire for Soccer Players, the Sport Imagery Training and the Sport Imagery Questionnaire. The results showed that imagery was most used in competition than in training, preferably in its visual dimension and from an internal perspective. The results also demonstrated that athletes used imagery both for motivational and cognitive purposes, but the motivational function, namely its general-mastery component, was slightly more used and with more vivid images. After competition and when injured, under-21 athletes used imagery significantly less than their older counterparts.