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  • Author: H.-W. Alt x
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Complexes of the type C5H5W(CO)(L)R (L = alkyne; R = CH3, C6H5) are obtained by irradiation of a solution containing both C5H5W(CO)3R and L. The intramolecular mobility of the π-bonded acetylene in the 16-electron complexes C5H5W(CO)(L)R can be demonstrated by temperature-dependent 1H NMR spectroscopy.