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  • Author: Ya-Qin Xu x
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Abstract

C67H49Cl3N6O18, triclinic, P1̄ (no. 2), a = 12.3281(4) Å, b = 15.8887(5) Å, c = 16.9037(6) Å, α = 89.015(2)°, β = 77.885(3)°, γ = 72.021(3)°, V = 3075.20(19) Å3, Z = 2, R gt(F) = 0.0658, wR ref(F 2) = 0.1558, T = 291.2(3) K.

Abstract

Treatment of cis-[RuCl2(phen)2]·2H2O (phen=1,- 10-phenanthroline) with 1-(2,6-diisopropylphenoxy)-4-phenylphthalazine (HL1) or 1-(2,6-dimethylphenoxy)-4-phenylphthalazine (HL2) in the presence of AgPF6 afforded two cyclometalated ruthenium(II) complexes, [Ru(κ 2-C,N-L1)(phen)2](PF6) (1) and [Ru(κ 2-C,N-L2)(phen)2](PF6) (2), respectively. The two complexes have been characterized by UV–vis and luminescence spectroscopy. The structure of 1·1.5H2O has been determined by single-crystal X-ray diffraction.