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Review Solvothermal Synthesis of Multifunctional Coordination Polymers Yonggang Zhao, Kunhao Li, and Jing Li Department of Chemistry and Chemical Biology, Rutgers University, Piscataway, NJ 08854, USA Reprint requests to Prof. Dr. Jing Li. Fax: 732-445-5312. E-mail: Z. Naturforsch. 2010, 65b, 976 – 998; received March 31, 2010 This review focuses primarily on the past 10 years of our development of multifunctional coordi- nation polymers with 1D, 2D and 3D structures employing low-temperature and cost-effective hy- drothermal and solvothermal

,3-benzenedicarboxylic acid; H 2 sba, 2-sulfobenzoic acid; H 2 NICO, 2-hydroxynicotinic acid. Introduction Coordination polymers have been extensively studied during the past two decades due to their attractive structures and topologies as well as their potential applications as multifunctional materials in magnetism (Maspoch et al. 2007, Kurmoo 2009), luminescence (Cui et al. 2012), gas adsorption, separation and purification (Getman et al. 2012, Suh et al. 2012, Sumida et al. 2012), catalysis (Chen and Ma 2012, Yoon et al. 2012), and so on. In recent years, the incorporation of two

supramolecular structures [ 5 ], [ 6 ]. Particularly, the introduction of additional donor functionality to the model nucleobase, for example, as part of the alkyl substituent, has led to numerous reports on metallamacrocycles [ 7 ] and even to coordination polymers [ 8 ]. Most recently, a novel solid organic electrolyte with potential applicability in lithium ion batteries was reported based on N7-(carboxymethyl)guanine [ 9 ]. We recently introduced the purine derivative 6-furylpurine (6FP, Chart 1 ) as an artificial nucleobase for silver(I)-mediated base pairing. Depending

A Pyrazine-Bridged Ni(II) Coordination Polymer Chirantan Roy Choudhurya, Subrata Kumar Deya, Sutapa Sena, Bappaditya Baga, Samiran Mitraa, and Volker Gramlichb a Department of Chemistry, Jadavpur University, Calcutta - 700 032, India b Laboratorium für Kristallographie ETH, Eidgenössische Technische Hochschule Zürich, CH-8092 Zürich, Switzerland Reprint requests to Prof. S. Mitra. E-mail: smitra, Fax: 91-33-414-6266 Z. Naturforsch. 57 b, 1191–1194 (2002); received May 28, 2002 Polymeric Ni(II) Complex, Pyrazine-Bridged Ni(II) Coordination

One-dimensional Coordination Polymers of Cadmium Thiolates with 4,4′-Trimethylenebipyridine Ligands Chao Xua, Fang-Hui Wua, Taike Duana, and Qian-Feng Zhanga,b a Institute of Molecular Engineering and Applied Chemistry, Anhui University of Technology, Ma’anshan, Anhui 243002, P. R. China b State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210009, P. R. China Reprint requests to Dr. Qian-Feng Zhang. Fax: +86-555-2312041. E-mail: Z. Naturforsch. 2009, 64b, 805 – 808; received February 11, 2009 Hydrothermal reactions of

2D and 3D Silver(I)-Ethylenediamine Coordination Polymers with Ag–Ag Argentophilic Interactions Ji-Xiang Daia, Hai-Liang Zhua,b, Alexander Rothenbergerc, and Qian-Feng Zhanga a Department of Applied Chemistry, Anhui University of Technology, Ma’anshan, Anhui 243002, China b Institute of Functional Biomolecules, Nanjing University, Nanjing 210093, China c Institut für Anorganische Chemie, Universität Karlsruhe (TH), 76128 Karlsruhe, Germany Reprint requests to Dr. Qian-Feng Zhang. Fax: +86-555-2311552. E-mail: Z. Naturforsch. 2007, 62b, 1112

843Note A Zinc(II) Coordination Polymer with Tetraiodoterephthalate: Synthesis, Crystal Structure, and Luminescence Le Chena, Sheng-Chun Chena, Zhi-Hui Zhanga, Fu-An Suna, Ai-Jun Cuia, Hai-Bo Gaob, Ming-Yang Hea, and Qun Chena a Key Laboratory of Fine Petro-chemical Technology, Changzhou University, Changzhou 213164, P. R. China b College of Life Science, Linyi University, Linyi 276002, P. R. China Reprint requests to Dr. S.-C. Chen and Prof. Q. Chen. Fax: +8651986330251. E-mail: (S.-C. Chen), (Q. Chen) Z. Naturforsch. 2012

Introduction During recent years, coordination polymers have attracted the interest of many researchers, and examples with a huge diversity of ligand-metal combinations were reported (Hagrman et al., 1999; Khlobystov et al., 2001; Moulton and Zaworotko, 2001; Kitagawa et al., 2004; Robin and Fromm, 2006; Fromm, 2008; Batten et al., 2009; Morsali and Masoomi, 2009; Akhbari and Morsali, 2010; Leong and Vittal, 2011). However, compared with studies on coordination polymers containing transition metals, those containing main group metals in general and bismuth in

6 Transition metal-based coordination polymers Abstract: Inorganic coordination polymer has a demand in the material science re- search world, supplying a distinct method of synthesis, which is developed from various molecular blocks along with the different correlation between them. This chapter gives the outline of future generation coordination polymers and its struc- tural arrangement such as porous, nonporous, and nanospace polymer composites. Keywords: porous structures, nonporous structures, nanoscale transition metal- polymer, synthesis 6.1 Introduction

Synthesis, Crystal Structure and Properties of a New Lanthanide Pyridine-2,4,6-tricarboxylato Coordination Polymer Jian-Li Lin, Wei Xu, Li Zhao, and Yue-Qing Zheng Center of Applied Solid State Chemistry Research, Ningbo University, Ningbo, 315211, P. R. China Reprint requests to Prof. Dr. Yue-Qing Zheng. Fax: Int. +574/87600747. E-mail: Z. Naturforsch. 2011, 66b, 570 – 576; received March 3, 2011 A new lanthanide pyridine-2,4,6-tricarboxylato coordination polymer, [Dy2(H2O)5(ptc)2]·H2O (H3ptc = pyridine-2,4,6-tricarboxylic acid), was