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Acta Chemica Iasi

The Journal of "Alexandru Ioan Cuza" University from Iasi

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2067-2446
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Study of Archeometric Characteristics of a Panel Painted Icon Form XIXth Century

Raluca A. Cristache
  • Corresponding author
  • „Al. I. Cuza” University of Iasi, ARHEOINVEST Platform, Blvd. Carol I 11, 700506, Iasi, Romania
  • Email
  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
/ Ion Sandu
  • „Al. I. Cuza” University of Iasi, ARHEOINVEST Platform, Blvd. Carol I 11, 700506, Iasi, Romania
  • Romanian Inventors Forum, Str Sf. Petru Movila 3, L11, III/3, 700089, Iasi, Romania
  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
/ Viorica Vasilache
  • „Al. I. Cuza” University of Iasi, ARHEOINVEST Platform, Blvd. Carol I 11, 700506, Iasi, Romania
  • Romanian Inventors Forum, Str Sf. Petru Movila 3, L11, III/3, 700089, Iasi, Romania
  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
/ Oana Cristache
  • „Al. I. Cuza” University of Iasi, ARHEOINVEST Platform, Blvd. Carol I 11, 700506, Iasi, Romania
  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
Published Online: 2013-12-31 | DOI: https://doi.org/10.2478/achi-2013-0007

Abstract

This study presents a physicochemical analysis on the orthodox icon “The grieving Mother” from XIXth century. The icon is made by an anonymus painter, in tempera pigments, on a lime wood support, Tillia cordata. God’s Mother is represented from one side, only the bust, with the head down, framed by a white border. The predominant colors of the icon are ultramarine blue, ocher, red-brown, with silver leaf. The edges of the panel were painted with tempera pigments as the border. On the right edge an inscription in blue ink, can be seen, but is unreadable. The painting layer has gaps, fissures, detachments, dirt, degraded and scaly varnish. The panel is made from a single board, transversally cut, without crossbeams. The study is based on the identification of some archeometric characteristics of the wood panel and of the pigment layer. To determin painting materials and the conservation state, Fourier Transform Infrared Spectroscopy (Micro-FTIR) and Scanning Electron Microscope coupled with Energy Dispersive X-ray spectroscopy (SEM-EDX) were employed. Using this methods we identify the pigments used and the state of degradation of the panel. The FTIR spectrum analysis showed that the pigment layer contains schellac varnish, ultramarine blue and dust, a conclusion supported by SEM-EDX analysis.

Keywords: icon; pigments; Optical Microscopy; Micro-FTIR; SEM-EDX

  • 1. Kouloumpi, E.; Vandenabeele, P.; Lawson, G. Analysis of post- Byzantine icons from the Church of the Assumption in Cephalonia, Ionian Islands, Greece: A multi-method approach. Anal. Chim. Acta, 2007, 598, 169-179.Web of ScienceGoogle Scholar

  • 2. Zieba-Paulus, J.; Ligeza, M. Application of micro-fourier transform infrared spectroscopy to examination of easel paintings. Problems of Forensic Sciences, 2001, vol. XLVII, 418-425.Google Scholar

  • 3. Higgitt, C.; White, R.; Analyses Of Paint Media: New Studies Of Italian Paintings Of The Fiftheenth And Sixtheenth Centuries. National Gallery Technical Bulletin, 2005, 26, 86-97.Google Scholar

  • 4. Sandu, C. A.; Helena de S´ab M.; Costa Pereirac, M. Ancient ‘gilded’ art objects from European cultural heritage: a review on different scales of characterization. Surface and Interface Analysus, Wiley Online Library, 2010, 43, (8), 1134-1151.Google Scholar

  • 5. Baciu, A.; Moldovan, Z.; Bratu, I.; Marutoiu, O.F.; Kacsó, I.; Glajar , I.; Hernanz, A.; Marutoiu, C. Comparative Study of the Painting Materials of a Series of Orthodox Icons on Wooden and Glass Support from Transylvania. Current Analytical Chemistry, 2010, 6, 53-59.Google Scholar

  • 6. Derrick, M.R.; Stulik, D.; Landry, J.M. Scientific tools for Conservation, The Getty Conservation Institute, Los Angeles, 1999, pp. 236.Google Scholar

  • 7. Sandu, I.C.A.; Bracci, S.; Sandu, I.; Lobefaro, M. Integrated Analytical Study for the Authentication of Five Russian Icons (XVI-XVII centuries), Microscopy Research And Technique, 2009, 72, 755-765.Web of ScienceGoogle Scholar

  • 8. Darwish, S.S.; Scientific Investigation Of The Materials And Techniques Used In A 19th Century Egyptian Cemetery Wall Painting (Hawsh Al-Basha), International Journal of Conservation Science, 2013, 4, 145-152.Google Scholar

  • 9. Săndulescu-Verna, C. Materiale şi tehnica picturii, Ed. Marineasa, Timişoara; 2000, pp.547.Google Scholar

  • 10. Kaszowskaa, Z.; Malekb, K.; Pan´ czykc, M.; Mikołajskaa, A. A joint application of ATR-FTIR and SEM imaging with high spatial resolution: Identification and distribution of painting materials and their degradation products in paint cross sections. Vib. Spectrosc. 2013, 65, 1- 11.Web of ScienceGoogle Scholar

  • 11. Vahur, S.; Teearu, A.; Leito, Ivo. ATR-FT-IR spectroscopy in the region of 550-230cm−1 for identification of inorganic pigments. Spectrochim. Acta Part A. 2010, 75, 1061-1072.Google Scholar

  • 12. Favaro, M.; Guastoni, A.; Marini, F.; Bianchin, S.; Gambirasi, A. Characterization of lapis lazuli and corresponding purified pigments for a provenance study of ultramarine pigments used in works of art. Anal. Bioanal. Chem. 2012, 402, 2195-2208. Web of ScienceGoogle Scholar

  • 13. Van der Weerd J.; Van Loon A.;. Boon J.J. FTIR Studies of the Effects of Pigments on the Aging of Oil. Stud. Conserv. 2005, 1, 3-22.Google Scholar

  • 14. http://tera.chem.ut.ee/IR_spectra/index.php?option=com_content&view=article&id=75:-ultramarine-blue-deep-linseed-oil&catid=11:blue-pigments-linseed-oil&Itemid=43 Google Scholar

About the article

Published Online: 2013-12-31

Published in Print: 2013-12-01


Citation Information: Acta Chemica Iasi, Volume 21, Issue 2, Pages 71–82, ISSN (Online) 2067-2446, DOI: https://doi.org/10.2478/achi-2013-0007.

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