Jump to ContentJump to Main Navigation
Show Summary Details
More options …

Acta Chimica Slovaca

The Journal of Slovak University of Technology in Bratislava

2 Issues per year

Open Access
Online
ISSN
1337-978X
See all formats and pricing
More options …

Phase diagram of the system CaSO4—K2SO4—KNO3—Ca(NO3)2—H2O

Jana Jurišová
  • Corresponding author
  • Institute of Inorganic Chemistry, Technology and Materials, Faculty of Chemical and Food Technology STU in Bratislava, Radlinského 9, 812 37 Bratislava, Slovak Republic
  • Email
  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
/ Vladimír Danielik
  • Institute of Inorganic Chemistry, Technology and Materials, Faculty of Chemical and Food Technology STU in Bratislava, Radlinského 9, 812 37 Bratislava, Slovak Republic
  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
/ Pavel Fellner
  • Institute of Inorganic Chemistry, Technology and Materials, Faculty of Chemical and Food Technology STU in Bratislava, Radlinského 9, 812 37 Bratislava, Slovak Republic
  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
/ Marek Lencsés / Milan Králik
Published Online: 2014-05-27 | DOI: https://doi.org/10.2478/acs-2014-0004

Abstract

Potassium nitrate as a fertilizer suitable for greenhouse and hydroponic applications can be prepared by the reaction of potassium sulphate with calcium nitrate. However, it may happen that simultaneously with the precipitation of gypsum (CaSO4·2H2O) also two other binary salts, viz. syngenite (K2SO4·CaSO4·H2O) and görgeyite (K2SO4·5CaSO4·H2O) can crystallize. This would lower the yield of KNO3. For minimization of potassium loss we have to determine the conditions under which syngenite and görgeyite crystallize. As a useful tool for the quantitative determination of specific hydrates, simultaneous DTA/TG technique appeared. Each hydrate decomposes at a certain temperature. The loss of water at dehydration can be used for a quantitative determination of the amount of the hydrate in the precipitating solid phase. Based on the experimental data several conclusions can be drawn: (i) excess of calcium cations lowers the concentration of sulphate ions in the liquid phase together with lowering of contents of syngenite and görgeyite in the solid phase; (ii) higher content of water results in a higher solubility of sulphate ions; (iii) joint crystallization of syngenite and gypsum occurs in the composition area interesting from the point of KNO3 production; (iv) area of the primary crystallization of görgeyite does not exist in the phase diagram at 80 °C. However, görgeyite crystallizes at the molar ratio Ca(NO3)2:K2SO4 = 1:1 by ternary crystallization; (v) area of crystallization of pure gypsum is shifted to lower ratio Ca(NO3)2:K2SO4 by the addition of water to the system.

Keywords: görgeyite; phase diagram; potassium nitrate; syngenite

References

About the article

Published Online: 2014-05-27

Published in Print: 2014-04-01


Citation Information: Acta Chimica Slovaca, ISSN (Online) 1337-978X, DOI: https://doi.org/10.2478/acs-2014-0004.

Export Citation

© Faculty of Chemical and Food Technology, Slovak University of Technology in Bratislava . This article is distributed under the terms of the Creative Commons Attribution Non-Commercial License, which permits unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited. BY-NC-ND 3.0

Comments (0)

Please log in or register to comment.
Log in