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The Journal of Institute of Environmental Engineering and Committee of Environmental Engineering of Polish Academy of Sciences

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Physico-Chemical Parameters Determining the Variability of Actually and Potentially Available Fractions of Heavy Metals in Fluvial Sediments of the Middle Odra River

Aleksandra Ibragimow
  • Corresponding author
  • Adam Mickiewicz University, Polish-German Research Institute in Collegium Polonicum, Kościuszki 1, 69-100 Słubice, Poland
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  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
/ Barbara Walna / Marcin Siepak
  • Adam Mickiewicz University, Institute of Geology, Department of Hydrogeology and Water Protection, Maków Polnych 16, 61-606 Poznań, Poland
  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
Published Online: 2013-07-06 | DOI: https://doi.org/10.2478/aep-2013-0012


The occurrence of heavy metals (Cd, Cr, Cu, Ni, Pb, Zn) has been determined in the fluvial sediment samples collected along three transects in the Middle Odra River (western Poland) with a width of 360 m. The total concentrations of the metals were obtained after HNO3 microwave digestion and the available fractions of heavy metals were determined by single extraction procedures using two extractants: 0.01M CaCl2 and 0.05M EDTA. The measurement of physico-chemical parameters was also performed. The determination of total and available fractions of heavy metals, except potential available fractions of Cr, revealed high concentrations of studied elements detected in the sediment samples characterized by high content of coarse and very coarse-grained sand fraction and high content of organic matter. It was found that the concentrations of total and available fractions of metals could increase along with the content of organic matter, Eh values and concentrations of H+. Apart from the above, those concentrations become the lowest, the higher the content of medium grain size fractions is. Furthermore, the amounts of CaCl2 and EDTA extractable metals increase in the sediments samples characterized by the lowest total and available concentrations of heavy metals.

Keywords : Heavy metals; available fractions; single extraction; the Odra River

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About the article

Published Online: 2013-07-06

Published in Print: 2013-06-01

Citation Information: Archives of Environmental Protection, Volume 39, Issue 2, Pages 3–16, ISSN (Online) 2083-4810, ISSN (Print) 2083-4772, DOI: https://doi.org/10.2478/aep-2013-0012.

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