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Archives of Metallurgy and Materials

The Journal of Institute of Metallurgy and Materials Science and Commitee on Metallurgy of Polish Academy of Sciences

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Extraction Factor Of Tungsten Sources From Tungsten Scraps By Zinc Decomposition Process


J.-H. Pee / G.H. Kim / H.Y. Lee / Y.J. Kim
Published Online: 2015-08-03 | DOI: https://doi.org/10.1515/amm-2015-0120


Decomposition promoting factors and extraction process of tungsten carbide and tungstic acid powders in the zinc decomposition process of tungsten scraps which are composed mostly of tungsten carbide and cobalt were evaluated. Zinc volatility was suppressed by the enclosed graphite crucible and zinc volatilization pressure was produced in the reaction graphite crucible inside an electric furnace for ZDP (Zinc Decomposition Process). Decomposition reaction was done for 2hours at 650°, which 100% decomposed the tungsten scraps that were over 30 mm thick. Decomposed scraps were pulverized under 75μm and were composed of tungsten carbide and cobalt identified by the XRD (X-ray Diffraction). To produce the WC(Tungsten Carbide) powder directly from decomposed scraps, pulverized powders were reacted with hydrochloric acid to remove the cobalt binder. Also to produce the tungstic acid, pulverized powders were reacted with aqua regia to remove the cobalt binder and oxidize the tungsten carbide. Tungsten carbide and tungstic acid powders were identified by XRD and chemical composition analysis.

Keywords: Raw material; Recycling; Zinc decomposition process; Tungsten carbide; Tungstic acid


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About the article

Received: 2014-11-20

Published Online: 2015-08-03

Published in Print: 2015-06-01

Citation Information: Archives of Metallurgy and Materials, Volume 60, Issue 2, Pages 1311–1314, ISSN (Online) 2300-1909, DOI: https://doi.org/10.1515/amm-2015-0120.

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© Polish Academy of Sciences. This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License. BY-NC-ND 3.0

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