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American Mineralogist

Journal of Earth and Planetary Materials

Ed. by Baker, Don / Xu, Hongwu / Swainson, Ian


IMPACT FACTOR 2018: 2.631

CiteScore 2018: 2.55

SCImago Journal Rank (SJR) 2018: 1.355
Source Normalized Impact per Paper (SNIP) 2018: 1.103

Online
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1945-3027
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Volume 86, Issue 10

Issues

Geochemical modeling of bacterially induced mineralization of schwertmannite and jarosite in sulfuric acid spring water

Motoharu Kawano
  • Department of Biochemical Sciences and Technology, Faculty of Agriculture, Kagoshima University, 1-21-24 Korimoto, Kagoshima 890-0065, Japan
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/ Katsutoshi Tomita
  • Department of Earth and Environmental Sciences, Faculty of Science, Kagoshima University, 1-21-35 Korimoto, Kagoshima 890-0065, Japan
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Published Online: 2015-03-26 | DOI: https://doi.org/10.2138/am-2001-1005

Abstract

Mineralogy and geochemistry of a sulfuric acid spring water with a pH of 3.37 to 2.89 were investigated to verify the formation processes of iron minerals and the effects of bacteria on their formation. To estimate the solubility of schwertmannite, experimental dissolution in 10.0 mM H2SO4 was conducted and this solubility data was used for geochemical modeling. Experimental incubation of the spring water containing bacteria was also performed and compared with a simulated abiotic system to evaluate the role of bacteria in the mineral formation. The spring water seeps through cracks of hydrothermally altered andesitic rocks containing pyrite, and precipitates schwertmannite and jarosite. Schwertmannite appears as a film-like thin layer floating on the water surface and composed of aggregates of spherical particles with diameters of 1 to 5 µm. Jarosite is produced as a precipitate on submerged rock surfaces. The precipitate contains well crystallized jarosite spheres 5 to 10 µm in diameter. Some ellipsoidal to rod shaped bacteria covered or decorated by poorly ordered iron minerals are also present in close association with the schwertmannite spheres. Results of the experimental incubation demonstrate that the oxidation rates of Fe2+ are 5.3 × 103 to 7.2 × 103 times greater than those of the simulated abiotic system, suggesting that the formation of the iron minerals is promoted by bacterial oxidation of Fe2+. The dissolution experiment indicates that the solubility product of the schwertmannite having an average chemical composition of Fe8O8(OH)5.9(SO4)1.05 is approximately log KS = 7.06 ± 0.09. Using this data, geochemical modeling reveals that the spring water is supersaturated with respect to schwertmannite and also goethite and jarosite, but undersaturated with respect to ferrihydrite. Additionally, it is confirmed that the bulk solution chemistry deviates slightly into the stability field of goethite rather than jarosite. This suggests that the aquatic environments in contact with the rock surfaces may be more acidic and/or enriched in SO42- relative to the bulk solution, which may eventually lead to the formation of jarosite instead of goethite.

About the article

Received: 2001-02-02

Accepted: 2001-06-15

Published Online: 2015-03-26

Published in Print: 2001-10-01


Citation Information: American Mineralogist, Volume 86, Issue 10, Pages 1156–1165, ISSN (Online) 1945-3027, ISSN (Print) 0003-004X, DOI: https://doi.org/10.2138/am-2001-1005.

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© 2015 by Walter de Gruyter Berlin/Boston.

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