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American Mineralogist

Journal of Earth and Planetary Materials

Ed. by Baker, Don / Xu, Hongwu / Swainson, Ian


IMPACT FACTOR 2018: 2.631

CiteScore 2018: 2.55

SCImago Journal Rank (SJR) 2018: 1.355
Source Normalized Impact per Paper (SNIP) 2018: 1.103

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1945-3027
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Volume 92, Issue 5-6

Issues

The pearceite-polybasite group of minerals: Crystal chemistry and new nomenclature rules

Luca Bindi / Michel Evain
  • Laboratoire de Chimie des Solides, IMN, UMR C6502 CNRS, Université de Nantes, 2 rue de la Houssinière, BP32229, 44322 Nantes CEDEX 3, France
  • Other articles by this author:
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/ Paul G. Spry
  • Department of Geological and Atmospheric Sciences, 253 Science I, Iowa State University, Ames, Iowa 50011.3210, U.S.A.
  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
/ Silvio Menchetti
  • Dipartimento di Scienze della Terra, Università di Firenze, Via La Pira 4, I-50121 Firenze, Italy
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Published Online: 2015-04-01 | DOI: https://doi.org/10.2138/am.2007.2440

Abstract

The present paper reports changes to the existing nomenclature for minerals belonging to the pearceite-polybasite group. Thirty-one samples of minerals in this group from different localities, with variable chemical composition, and showing the 111, 221, and 222 unit-cell types, were studied by means of X-ray single-crystal diffraction and electron microprobe. The unit-cell parameters were modeled using a multiple regression method as a function of the Ag, Sb, and Se contents. The determination of the crystal structures for all the members of the group permits them to be considered as a family of polytypes and for all members to be named pearceite or polybasite. The main reason for doubling the unit-cell parameters is linked to the ordering of silver. The distinction between pearceite and polybasite is easily done with an electron microprobe analysis (As/Sb ratio). A hyphenated italic suffix indicating the crystal system and the cell-type symbol should be added, if crystallographic data are available. Given this designation, the old names antimonpearceite and arsenpolybasite are abandoned here and the old names pearceite and polybasite, previously defined on a structural basis (i.e., 111 and 222), are redefined on a chemical basis. The old name pearceite will be replaced by pearceite-Tac, antimonpearceite by polybasite-Tac, arsenpolybasite-221 by pearceite-T2ac, arsenpolybasite-222 by pearceite-M2a2b2c, polybasite-221 by polybasite-T2ac, and polybasite-222 by polybasite-M2a2b2c. Since all polytypes are composed of two different layers stacked along [001]: layer A, with general composition [(Ag,Cu)6(As,Sb)2S7]2-, and layer B, with general composition [Ag9CuS4]2+, the chemical formulae of pearceite and polybasite should be written as [Ag9CuS4][(Ag,Cu)6(As,Sb)2S7] and [Ag9CuS4][(Ag,Cu)6(Sb,As)2S7], respectively, instead of (Ag,Cu)16(As,Sb)2S11 and (Ag,Cu)16(Sb,As)2S11, as is currently accepted. The new nomenclature rules were approved by the Commission on New Minerals and Mineral Names of the International Mineralogical Association.

Keywords: Pearceite-polybasite; nomenclature rules; crystal chemistry; X-ray data; chemical composition

About the article

Received: 2006-08-30

Accepted: 2006-12-25

Published Online: 2015-04-01

Published in Print: 2007-05-01


Citation Information: American Mineralogist, Volume 92, Issue 5-6, Pages 918–925, ISSN (Online) 1945-3027, ISSN (Print) 0003-004X, DOI: https://doi.org/10.2138/am.2007.2440.

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© 2015 by Walter de Gruyter Berlin/Boston.Get Permission

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